Showing papers on "Corrosion published in 2009"

Welding Metallurgy and Weldability of Nickel-Base Alloys

Abstract: Preface. 1. Introduction. 1.1 Ni-base Alloy Classification. 1.2 History of Nickel and Ni-base Alloys. 1.3 Corrosion Resistance. 1.4 Nickel Alloy Production. 2. Alloying Additions, Phase Diagrams, and Phase Stability. 2.1 Introduction. 2.2 General Influence of Alloying Additions. 2.3 Phase Diagrams for Solid-Solution Alloys. 2.4 Phase Diagrams for Precipitation Hardened Alloys--gamma' Formers. 2.5 Phase Diagrams for Precipitation-Hardened Alloys--gamma" Formers. 2.6 Calculated Phase Stability Diagrams. 2.7 PHACOMP Phase Stability Calculations. 3. Solid-Solution Strengthened Ni-base Alloys. 3.1 Standard Alloys and Consumables. 3.2 Physical Metallurgy and Mechanical Properties. 3.3 Welding Metallurgy. 3.4 Mechanical Properties of Weldments. 3.5 Weldability. 3.6 Corrosion Resistance. 3.7 Case Studies. 4. Precipitation Strengthened Ni-base Alloys. 4.1 Standard Alloys and Consumables. 4.2 Physical Metallurgy and Mechanical Properties. 4.3 Welding Metallurgy. 4.4 Mechanical Properties of Weldments. 4.5 Weldability. 5. Oxide Dispersion Strengthened Alloys and Nickel Aluminides. 5.1 Oxide Dispersion Strengthened Alloys. 5.2 Nickel Aluminide Alloys. 6. Repair Welding of Ni-base Alloys. 6.1 Solid-Solution Strengthened Alloys. 6.2 Precipitation Strengthened Alloys. 6.3 Single Crystal Superalloys. 7. Dissimilar Welding. 7.1 Application of Dissimilar Welds. 7.2 Influence of Process Parameters on Fusion Zone Composition. 7.3 Carbon, Low Alloys and Stainless Steels. 7.4 Postweld Heat Treatment Cracking in Stainless Steels Welded with Ni-base Filler Metals. 7.5 Super Austenitic Stainless Steels. 7.6 Dissimilar Welds in Ni-base Alloys - Effect on Corrosion Resistance. 7.7 9%Ni Steels. 7.8 Super Duplex Stainless Steels. 7.9 Case Studies. 8. Weldability Testing. 8.1 Introduction. 8.2 The Varestraint Test. 8.3 Modified Cast Pin Tear Test. 8.4 The Sigmajig Test. 8.5 The Hot Ductility Test. 8.6 The Strain-to-Fracture Test. 8.7 Other Weldability Tests. Appendix A Composition of Wrought and Cast Nickel-Base Alloys. Appendix B Composition of Nickel and Nickel Alloy Consumables. Appendix C Corrosion Acceptance Testing Methods. Appendix D Etching Techniques for Ni-base Alloys and Welds. Author Index. Subject Index.

Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating

Abstract: Homogeneous epoxy coatings containing nanoparticles of SiO 2 , Zn, Fe 2 O 3 and halloysite clay were successfully synthesized on steel substrates by room-temperature curing of a fully mixed epoxy slurry diluted by acetone. The surface morphology and mechanical properties of these coatings were characterized by scanning electron microscopy and atomic force microscopy, respectively. The effect of incorporating various nanoparticles on the corrosion resistance of epoxy-coated steel was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy. The electrochemical monitoring of the coated steel over 28 days of immersion in both 0.3 wt.% and 3 wt.% NaCl solutions suggested the beneficial role of nanoparticles in significantly improving the corrosion resistance of the coated steel, with the Fe 2 O 3 and halloysite clay nanoparticles being the best. The SiO 2 nanoparticles were found to significantly improve the microstructure of the coating matrix and thus enhanced both the anticorrosive performance and Young's modulus of the epoxy coating. In addition to enhancing the coating barrier performance, at least another mechanism was at work to account for the role of the nanoparticles in improving the anticorrosive performance of these epoxy coatings.

Halloysite tubes as nanocontainers for anticorrosion coating with benzotriazole.

Abstract: Halloysite clay nanotubes were investigated as a tubular container for the corrosion inhibitor benzotriazole. Halloysite is a naturally occurring cylindrical clay mineral with an internal diameter in the nanometer range and a length up to several micrometers, yielding a high-aspect-ratio hollow tube structure. Halloysite may be used as an additive in paints to produce a functional composite coating material. A maximum benzotriazole loading of 5% by weight was achieved for clay tubes of 50 nm external diameters and lumen of 15 nm. Variable release rates of the corrosion inhibitor were possible in a range between 5 and 100 h, as was demonstrated by formation of stoppers at tube openings. The anticorrosive performance of the sol-gel coating and paint loaded with 2-5% of halloysite-entrapped benzotriazole was tested on copper and on 2024-aluminum alloy by direct exposure of the metal plates to corrosive media. Kinetics of the corrosion spot formation at the coating defects was analyzed by the scanning vibrating electrode technique, and an essential damping of corrosion development was demonstrated for halloysite-loaded samples.

Microbiologically Influenced Corrosion

Abstract: The term microbiologically influenced corrosion (MIC) is used to designate corrosion due to the presence and activities of microorganisms, ie, those organisms that cannot be seen individually with the unaided human eye, including microalgae, archaea, bacteria, and fungi. Microorganisms can accelerate rates of partial reactions in corrosion processes or shift the mechanism for corrosion. Microorganisms can influence pitting, dealloying, enhanced erosion corrosion, enhanced galvanic corrosion, stress corrosion cracking, and hydrogen embrittlement. Microbiologically influenced corrosion has been reported for all engineering metals and alloys with the exception of predominantly titanium and high chromium–nickel alloys. It has been documented for metals and nonmetals exposed to seawater, freshwater, distilled/demineralized water, crude and distillate hydrocarbon fuels, process chemicals, foodstuffs, soils, human plasma, saliva, and sewage. The following sections describe the estimated costs of MIC, mechanisms, and causative microorganisms contributing to MIC; techniques for diagnosing, measuring, and monitoring; engineering practices that influence MIC and strategies to prevent or mitigate MIC. Keywords: corrosion; MIC; microbiologically influenced corrosion; alloys

Preparation of superhydrophobic coatings on zinc as effective corrosion barriers.

Abstract: Stable superhydrophobic films with a contact angle of 151 ± 2° were prepared on zinc substrates by a simple immersion technique into a methanol solution of hydrolyzed 1H,1H,2H,2H-perfluorooctyltrichlorosilane [CF3(CF2)5(CH2)2SiCl3, PFTS] for 5 days at room temperature followed by a short annealing at 130 °C in air for 1 h. The superhydrophobic film provides an effective corrosion-resistant coating for the zinc interface when immersed in an aqueous solution of sodium chloride (3% NaCl) for up to 29 days. The corrosion process was investigated by following the change of the water contact angle over time and by electrochemical means. The results are compared to those of unprotected zinc interfaces.

Plasma electrolytic oxidation (PEO) for production of anodised coatings on lightweight metal (Al, Mg, Ti) alloys

Abstract: The introduction of plasma electrolytic oxidation (PEO) as a surface finishing technique has enabled a range of hard, dense oxide coatings to be produced on aluminium, magnesium, titanium and other lightweight alloy substrates. As with all surface coating technologies, successful development of PEO coatings requires adequate attention to substrate pretreatment together with careful control of electrolyte conditions and process variables. The principles and applications of the PEO coating process are considered, including the fundamentals of oxide deposition, the technology involved and the typical characteristics of the coatings. Industrial applications are considered together with their coating requirements. Plasma electrolytic oxidation coating is a specialised but well developed process. Suitable control of electrolyte and process conditions can realise a novel range of coatings having technologically attractive physical and chemical properties. The development of PEO technology over the last decade has provided coatings having controlled appearance, hardness, corrosion resistance and other tribological properties across an extending range of industrial sectors. Continuing developments are concisely reviewed and the PEO process is illustrated by the characterisation of anodised coatings on an AZ91 magnesium alloy surface.

The use of Al–Al2O3 cold spray coatings to improve the surface properties of magnesium alloys

Abstract: Pure Al and 6061 aluminium alloy based Al2O3 particle-reinforced composite coatings were produced on AZ91E substrates using cold spray. The strength of the coating/substrate interface in tension was found to be stronger than the coating itself The coatings have corrosion resistance similar to that of bulk pure aluminium in both salt spray and electrochemical tests. The wear resistance of the coatings is significantly better than that of the AZ91 Mg substrate, but the significant result is that the wear rate of the coatings is several decades lower than that of various bulk Al alloys tested for comparison. The effect of post-spray heat treatment, the volume fraction of Al2O3 within the coating and of the type of Al powder used in the coatings on the corrosion and wear resistance was also discussed.

Nanoporous Metals by Alloy Corrosion: Formation and Mechanical Properties

Abstract: Nanoporous metals prepared by the corrosion of an alloy can take the form of monolithic, millimeter-sized bodies containing approximately 1015 nanoscale ligaments per cubic millimeter. The ligament size can reach down to the very limits of stability of nanoscale objects. The processes by which nanoporous metals are formed have continued to be fascinating, even though their study in relation to surface treatment, metal refinement, and failure mechanisms can be traced back to ancient times. In fact, the prospect of using alloy corrosion as a means of making nanomaterials for fundamental studies and functional applications has led to a revived interest in the process. The quite distinct mechanical properties of nanoporous metals are one of the focus points of this interest, as relevant studies probe the deformation behavior of crystals at the lower end of the size scale. Furthermore, the coupling of bulk stress and strain to the forces acting along the surface of nanoporous metals provide unique opportunities for controlling the mechanical behavior through external variables such as the electrical or chemical potentials.