Topic
Countercurrent exchange
About: Countercurrent exchange is a research topic. Over the lifetime, 2255 publications have been published within this topic receiving 28687 citations. The topic is also known as: Countercurrent exchange.
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TL;DR: In this paper , the results showed that when using a D2EHPA-TOA mixture, the overall extraction of scandium tends to rise from 37 to 68% as the concentration of sulphuric acid rises.
Abstract: Equimolar mixtures of di-2-ethylhexylphosphoric acid (D2EHPA) with trin-butylphosphate (TBP) or trioctylamine (TOA) in kerosene were used for extracting scandium from sulphuric acid-based red mud leach liquor. The results showed that when using a D2EHPA-TOA mixture, the overall extraction of scandium (ЕSc) tends to rise from 37 to 68% as the concentration of sulphuric acid rises. At the same time, the extraction of concomitant elements tends to decrease and remains way below the Е Sc . When using a D2EHPATBP mixture, the rising acidity of the solution does not lead to any significant increase in scandium extraction so that the latter remains quite high (i.e. 82–85%) while the extraction of the concomitant elements is significantly lower. A five-stage countercurrent extraction process was performed using a mixture of 0.1 mol/L D2EHPA and 0.1 mol/L TBP with 2 mol/L sulphuric acid to recover scandium from the liquor with minimized amounts of concomitant metals. The results showed that a 96.8% of scandium can be recovered after a three-stage countercurrent extraction process with 97% aluminium, 95% iron, 87% titanium and 54% zirconium removed from the liquor. A 4.7 mol/L sulphuric acid solution with an organic to aqueous ratio of 1:1 was used to wash the organic phase after a three-stage extraction process. For reextraction, a solution containing 2.5% NaOH and 6.5% Na2CO3 was used at a 2:1 aqueous to organic phase ratio. The solution was filtered to separate the solid phase. The precipitate was washed and dried and a primary 3.42% concentrate was obtained. Based on the obtained data, the authors describe a scandium extraction process using sulphuric acid-based red mud leach liquor. The new scandium concentration by extraction process parameters were tested on an enlarged scale at the Intermix MET site. A 100 g experimental batch of primary scandium concentrate containing, %: 2.2 Sc; 21.8 Тi; 4.3 Na; 0.6 Al; 1.7 Fe; 5.0 Zr; 0.0056 Y, was obtained from a 260-litre red mud leach liquor. For this, a cascade of five centrifugal extractors was used at the extractant saturation stage. An 8-litre mixture of 0.1 mol/L D2EHPA and 0.1 mol/L TBP in Exxsol D100 was used. The organic phase was in recycle, and due to that its saturation was 340 mg of scandium per litre of extractant.
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01 Jan 2022••
TL;DR: In this article, the mass effect, 1 + e, based on the differences in ionic mobilities was determined for the isotope mixture 22Na23Na in 1 N acetic acid as the countercurrent solution as a function of the ionic concentration.
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TL;DR: In this paper, a new kind of centrifugal countercurrent partition chromatographic column has been developed, which looks like the chain of a bicycle and has been successfully demonstrated in the separation of dinitrophenyl (DNP) amino acids.
Abstract: A new kind of centrifugal countercurrent partition chromatographic column has been developed. The shape of the column looks like the chain of a bicycle. Using the column, retention ratio of the stationary phase was measured with three kinds of solvent systems under various experimental conditions. The chloroform solvent systems showed retention from 52 to 66% when the upper phase was used as the stationary phase. The performance of the column has been successfully demonstrated in the separation of dinitrophenyl (DNP) amino acids, Weimeisu and an extract of branch-leaves of Taxus cuspidate.