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Showing papers on "Dichlorophenylphosphine published in 1978"


Journal ArticleDOI
TL;DR: Treatment of PhPCl2 with o-HOC6H4COMe in the presence of NEt3 affords Ph[graphic omitted], the structure of which has been determined by means of 13C n.m.r. spectroscopy and X-ray crystallography as discussed by the authors.
Abstract: Treatment of PhPCl2 with o-HOC6H4COMe in the presence of NEt3 affords Ph[graphic omitted], the structure of which has been determined by means of 13C n.m.r. spectroscopy and X-ray crystallography.

5 citations


Journal ArticleDOI
TL;DR: In this article, the chiral tertiary phosphines are obtained by direct treatment of the intermediate with another organometallic complex, i.e., by using a pyridine from the intermediate complex.

4 citations


Journal ArticleDOI
TL;DR: In this paper, the effect of chlorophosphines (phosphorus trichloride, dichlorophenylphosphine, chlorodiphenylphophosphine) on the radical polymerization of methyl methacrylate was investigated in benzene solution.
Abstract: The effect of chlorophosphines (phosphorus trichloride, dichlorophenylphosphine, chlorodiphenylphosphine) on the radical polymerization of methyl methacrylate was investigated in benzene solution. The polymerization was carried out at 50°C by the standard solution method, α,α′-azobisisobutyronitrile being used as an initiator. These chlorophosphines accelerated the polymerization of methyl methacrylate but did not affect the rate of decomposition of α,α′-azobisisobutyronitrile. Ultraviolet and infrared spectral data suggested that the acceleration effect was due to the complex formation of methyl methacrylate with each chlorophosphine. From the result of a copolymerization with styrene, it was found that the reactivity of methyl methacrylate monomer increased in the presence of dichlorophenylphosphine.

2 citations