Showing papers on "Dichlorophenylphosphine published in 1989"
TL;DR: A general methodology for the preparation of sterically hindered hydroxyaryl derivatives of both phosphorus and silicon is described in this paper, where a trisadduct tris(3,5-di-t-butyl-4-trimethylsilyloxyphenyl(diphenyl)phosphine) is described.
9 citations
TL;DR: In this paper, the reaction of the dichlorophenylphosphine with 2 equivalents of diphenyl-1,3 propanedione-1.3 a −30°C in presence of triethylamine conduisant au ([diphenyl]-1, 3 oxo-3] propenyl "O" phenyl] phosphinate
Abstract: Mecanisme de la reaction de la dichlorophenylphosphine avec 2 equivalents de diphenyl-1,3 propanedione-1,3 a −30°C en presence de triethylamine conduisant au ([diphenyl-1,3 oxo-3] propenyl «O»-[diphenyl-1,3 oxo-3 propenyl] phenyl) phosphinate
4 citations
Patent•
29 May 1989
TL;DR: In this paper, a mixture of a metathesis polymerizable monomer (e.g., dicyclopentadiene) reactive solution containing a polymerization catalyst series (PCS) component was used to polymerize a crosslinked polymer molded product in the presence of halogenated phosphorus compounds.
Abstract: PURPOSE:To provide the subject molded product containing a small amount of residual monomers, by mixing a metathesis polymerization catalyst component-containing monomer solution with a polymerization catalyst activating agent-containing monomer solution, pouring the mixture into a mold and polymerizing the poured mixture in the presence of a halogenated phosphorus compound. CONSTITUTION:A combination of (A) a metathesis polymerizable monomer (e.g., dicyclopentadiene) reactive solution containing a metathesis polymerization catalyst series catalyst component (e.g., tungsten hexachloride) and (B) a metathesis polymerizable monomer reactive solution containing a metathesis polymerization catalyst series activating agent component (e.g., trioctyl aluminum) is mixed. The produced mixture is poured into a mold in the coexistence of >=one kind of halogenated phosphorus compounds having at least one halogen-phosphorus bond (e.g., dichlorophenylphosphine) and subsequently polymerized to provide the objective crosslinked polymer molded product.
3 citations
TL;DR: In this paper, the reaction of the dichlorophenylphosphine with 2 equivalents of diphenyl-1,3 propanedione-1.3 a −30°C in presence of triethylamine conduisant au ([diphenyl]-1, 3 oxo-3] propenyl "O" phenyl] phosphinate
Abstract: Mecanisme de la reaction de la dichlorophenylphosphine avec 2 equivalents de diphenyl-1,3 propanedione-1,3 a −30°C en presence de triethylamine conduisant au ([diphenyl-1,3 oxo-3] propenyl «O»-[diphenyl-1,3 oxo-3 propenyl] phenyl) phosphinate