Topic
Dichlorophenylphosphine
About: Dichlorophenylphosphine is a research topic. Over the lifetime, 127 publications have been published within this topic receiving 1267 citations.
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TL;DR: In this paper, measurements of the infrared spectrum (650-200 cm−1) and Raman spectra of dichlorophenylphosphine (DPH) were reported, and the interpretation of these spectra and those for some related compounds were discussed.
10 citations
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TL;DR: The benzophosphole-fused indoles, such as phosphine oxide, phospholium salt, and borane complex, exhibited strong photoluminescence in dichloromethane (Φ = 67–75%).
Abstract: The parent benzophospholo[3,2-b]indole was prepared by the reaction of dichlorophenylphosphine with a dilithium intermediate, which was prepared in two steps from 2-ethynyl-N,N-dimethylaniline. Using the obtained benzophosphole-fused indole as a common starting material, simple modifications were carried out at the phosphorus center of the phosphole, synthesizing various functionalized analogs. The X-ray structure analysis of trivalent phosphole and phosphine oxide showed that the fused tetracyclic moieties are planar. The benzophosphole-fused indoles, such as phosphine oxide, phospholium salt, and borane complex, exhibited strong photoluminescence in dichloromethane (Φ = 67–75%).
10 citations
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TL;DR: A general methodology for the preparation of sterically hindered hydroxyaryl derivatives of both phosphorus and silicon is described in this paper, where a trisadduct tris(3,5-di-t-butyl-4-trimethylsilyloxyphenyl(diphenyl)phosphine) is described.
9 citations
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TL;DR: In this article, the conversion of enantiomerically enriched 2α-hydroxypinan-3-one and its oxime into a range of derivatives with potential application in asymmetric synthesis was attempted.
Abstract: The conversion of enantiomerically enriched (ee >99%) 2α-hydroxypinan-3-one and its oxime (obtained in previously described procedures∗ from α-pinene of 65% ee) into a range of derivatives with potential application in asymmetric synthesis was attempted C2-Symmetrical compounds, ligands for potential catalysts, were synthesized from 2α-hydroxypinan-3-one and either aliphatic or aromatic diamines Reduction or etherification/reduction of selected diiminodiols afforded respective diaminodiols and diaminoethers, which were further transformed into azolium salts Reactions of dipinanediaminoethers with dichlorophenylphosphine and subsequent in situ oxidation of the products afford the respective stable phosphinediamide oxides Four selected compounds were crystallographically studied
9 citations
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TL;DR: In this paper, 1,2-dihydro 1, 2- λ3-azaphosphorines were prepared by reaction of dichlorophenylphosphine with two equivalents of imines derived from propanal.
9 citations