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Differential scanning calorimetry

About: Differential scanning calorimetry is a research topic. Over the lifetime, 50315 publications have been published within this topic receiving 1152335 citations. The topic is also known as: DSC.


Papers
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Journal ArticleDOI
01 May 2012-Carbon
TL;DR: In this article, the copper shell/core nanoparticles were found to be formed by a novel coalescence mechanism that is quite different from the well-known dissolution-precipitation mechanism for some other graphene/metal (such as nickel, iron or cobalt) shell or core nanoparticles.

185 citations

Journal ArticleDOI
TL;DR: The thermal degradation behavior of cellulose fibers and some fibrous cellulose esters with partial degree of substitution has been studied by thermogravimetry analysis (TG) and differential scanning calorimetry (DSC) as discussed by the authors.

185 citations

Journal ArticleDOI
Defeng Wu1, Liang Wu1, Lanfeng Wu1, Bin Xu1, Yisheng Zhang1, Ming Zhang1 
TL;DR: In this paper, the nonisothermal cold crystallization behavior of intercalated polylactide (PLA)/clay nanocomposites (PLACNs) was studied using differential scanning calorimetry, polarized optical microscope, X-ray diffractometer, dynamic mechanical thermal analysis, and Fourier transform infrared spectrometer.
Abstract: The nonisothermal cold crystallization behavior of intercalated polylactide (PLA)/clay nanocomposites (PLACNs) was studied using differential scanning calorimetry, polarized optical microscope, X-ray diffractometer, dynamic mechanical thermal analysis, and Fourier transform infrared spectrometer. The results show that both the cold crystallization temperature (Tcc) and melting point (Tm) of PLA matrix decreases monotonously with increasing of clay loadings, accompanied by the decreasing degree of crystallinity (Xc%) at the low heating rates (≤5 °C/min). However, the Xc% of PLACNs presents a remarkable increase at the high heating rate of 10 °C/min in contrast to that of neat PLA. The crystallization kinetics was then analyzed by the Avrami, Jezioney, Ozawa, Mo, Kissinger and Lauritzen–Hoffman kinetic models. It can be concluded that at the low heating rate, the cold crystallization of both the neat PLA and nanocomposites proceeds by regime III kinetics. The nucleation effect of clay promote the crystallization to some extent, while the impeding effect of clay results in the decrease of crystallization rate with increasing of clay loadings. At the high heating rate of 10 °C/min, crystallization proceeds mainly by regime II kinetics. Thus, the formation of much more incomplete crystals in the PLACNs with high clay loadings due to the dominant multiple nucleations mechanism in regime II, may have primary contribution to the lower crystallization kinetics, also as a result to the higher degree of crystallinity and lower melting point in contrast to that of neat PLA. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1100–1113, 2007

185 citations

Journal ArticleDOI
TL;DR: It is shown that enzyme stabilization by ionic liquids seems to be related to the associated structural changes of the protein that can be observed by differential scanning calorimetry (DSC) and fluorescence and circular dichroism (CD).
Abstract: The stability of alpha-chymotrypsin in the ionic liquid, 1-ethyl-3-methyl-imidizolium bis[(trifluoromethyl)sulfonyl]amide ([emim][NTf2]), was studied at 30 and 50 degrees C and compared with the stability in other liquid media, such as water, 3 M sorbitol, and 1-propanol. The kinetic analysis of the enzyme stability pointed to the clear denaturative effect of 1-propanol, while both 3M sorbitol and [emim][NTf2] displayed a strong stabilizing power. For the first time, it is shown that enzyme stabilization by ionic liquids seems to be related to the associated structural changes of the protein that can be observed by differential scanning calorimetry (DSC) and fluorescence and circular dichroism (CD). The [emim][NTf2] enhanced both the melting temperature and heat capacity of the enzyme compared to the other media assayed. The fluorescence spectra clearly showed the ability of [emim][NTf2] to compact the native structural conformation of alpha-chymotrypsin, preventing the usual thermal unfolding which occurs in other media. Changes in the secondary structure of this beta/beta protein, as quantified by the CD spectra, pointed to the great enhancement (up 40% with respect to that in water) of beta-strands in the presence of the ionic liquid, which reflects its stabilization power.

185 citations

Journal ArticleDOI
TL;DR: In this article, a practical guide to studying the thermal behavior of maize starches using differential scanning calorimetry (DSC) is introduced. But it is difficult to study the thermal behaviour of starch materials using DSC.

185 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
20231,992
20224,368
20211,646
20201,696
20191,799
20181,990