Showing papers on "Electric potential published in 2011"

A finite strain model of stress, diffusion, plastic flow, and electrochemical reactions in a lithium-ion half-cell

Abstract: We formulate the continuum field equations and constitutive equations that govern deformation, stress, and electric current flow in a Li-ion half-cell. The model considers mass transport through the system, deformation and stress in the anode and cathode, electrostatic fields, as well as the electrochemical reactions at the electrode/electrolyte interfaces. It extends existing analyses by accounting for the effects of finite strains and plastic flow in the electrodes, and by exploring in detail the role of stress in the electrochemical reactions at the electrode–electrolyte interfaces. In particular, we find that that stress directly influences the rest potential at the interface, so that a term involving stress must be added to the Nernst equation if the stress in the solid is significant. The model is used to predict the variation of stress and electric potential in a model 1-D half-cell, consisting of a thin film of Si on a rigid substrate, a fluid electrolyte layer, and a solid Li cathode. The predicted cycles of stress and potential are shown to be in good agreement with experimental observations.

Electric-field-induced wetting and dewetting in single hydrophobic nanopores.

Abstract: Single hydrophobic nanopores can undergo reversible wetting and dewetting by applying an electric potential across the nanopore membrane.

A synthetic electric force acting on neutral atoms

Abstract: In electromagnetism, the vector potential generates magnetic fields through its spatial variation and electric fields through its time dependence. Now, it is demonstrated that, by engineering a time-varying vector potential acting on an atomic Bose–Einstein condensate, a synthetic gauge field can be generated that has the effect of an electric field on the atoms, even if these are neutral.

Understanding the surface potential of water.

Abstract: We have resolved the inconsistency in quantifying the surface potential at the liquid−vapor interface when using explicit ab initio electronic charge density and effective atomic partial charge models of liquid water. This is related, in part, to the fact that the resulting electric potentials from partial-charge models and ab initio charge distributions are quite different except for those regions of space between the molecules. We show that the electrostatic surface potential from a quantum mechanical charge distribution compares well to high-energy electron diffraction and electron holography measurements, as opposed to the comparison with electrochemical measurements. We suggest that certain regions of space be excluded when comparing computed surface potentials with electrochemical measurements. This work describes a novel interpretation of ab initio computed surface potentials through high-energy electron holography measurements as useful benchmarks toward a better understanding of electrochemistry.

A Comparison of Emissive Probe Techniques for Electric Potential Measurements in a Complex Plasma

Abstract: Accurate measurements of the plasma potential is a critical challenge especially for complex plasmas such as magnetized and flowing. We compare various emissive probe techniques for measurements of the plasma potential. The measurements were conducted in a low-pressure magnetized discharge of the Hall thruster. The thruster was operated with xenon gas in subkilowatt power range and the discharge voltage range of 200–450 V. The probe was placed at the channel exit where, the electron temperature is in the range of 10 to 60 eV and the plasma potential is in the range of 50 to 250 V. The floating point method is expected to give a value ∼Te/e below the plasma potential. The experimental results are consistent with these expectations. Specifically, it is shown that the floating potential of the emissive probe is ∼2Te/e below the plasma potential. It is observed that the separation technique varies wildly and does not give a good measure of the plasma potential

A comparison of emissive probe techniques for electric potential measurements in a complex plasma

Abstract: The major emissive probe techniques are compared to better understand the floating potential of an electron emitting surface in a plasma. An overview of the separation point technique, floating point technique, and inflection point in the limit of zero emission technique is given, addressing how each method works as well as the theoretical basis and limitations of each. It is shown that while the floating point method is the most popular, it is expected to yield a value ∼1.5Te/e below the plasma potential due to a virtual cathode forming around the probe. The theoretical predictions were checked with experiments performed in a 2 kW annular Hall thruster plasma (ne ∼ 109−1010 cm−3and Te ∼ 10−50 eV). The authors find that the floating point method gives a value around 2Te/e below the inflection point method, which is shown to be a more accurate emissive probe technique than other techniques used in this work for measurements of the plasma potential.

Optimal Time Decay of the Vlasov–Poisson–Boltzmann System in $${\mathbb R^3}$$

Abstract: The Vlasov–Poisson–Boltzmann System governs the time evolution of the distribution function for dilute charged particles in the presence of a self-consistent electric potential force through the Poisson equation. In this paper, we are concerned with the rate of convergence of solutions to equilibrium for this system over \({\mathbb R^3}\). It is shown that the electric field, which is indeed responsible for the lowest-order part in the energy space, reduces the speed of convergence, hence the dispersion of this system over the full space is slower than that of the Boltzmann equation without forces; the exact L2-rate for the former is (1 + t)−1/4 while it is (1 + t)−3/4 for the latter. For the proof, in the linearized case with a given non-homogeneous source, Fourier analysis is employed to obtain time-decay properties of the solution operator. In the nonlinear case, the combination of the linearized results and the nonlinear energy estimates with the help of the proper Lyapunov-type inequalities leads to the optimal time-decay rate of perturbed solutions under some conditions on initial data.

Surface charge accumulation on cylindrical polymeric model insulators in air: simulation and measurement

Abstract: The time characteristics of the surface charge accumulation process on cylindrical polymeric model insulators under dc stress were investigated in a partial discharge free, dry air environment. In order to simulate the influence of different dielectric and electric material properties on surface charge accumulation, a tool was developed which considers also the nonlinear behavior of the electric conduction mechanism within the gas volume. The results of simulation have been verified by measurements of the surface potential distribution along the samples at different ambient temperatures.

Effect of Secondary Electron Emission on Electron Cross-Field Current in $E \times B$ Discharges

Abstract: This paper reviews and discusses recent experimental, theoretical, and numerical studies of plasma-wall interaction in a weakly collisional magnetized plasma bounded with channel walls made from different materials. A low-pressure E ×B plasma discharge of the Hall thruster was used to characterize the electron current across the magnetic field and its dependence on the applied voltage and the electron-induced secondary electron emission (SEE) from the channel wall. The presence of a depleted anisotropic electron energy distribution function with beams of secondary electrons was predicted to explain the enhancement of the electron cross-field current observed in experiments. Without the SEE, the electron cross-field transport can be reduced from anomalously high to nearly classical collisional level. The suppression of the SEE was achieved using an engineered carbon-velvet material for the channel walls. Both theoretically and experimentally, it is shown that the electron emission from the walls can limit the maximum achievable electric field in the magnetized plasma. With nonemitting walls, the maximum electric field in the thruster can approach a fundamental limit for a quasi-neutral plasma.

Fourier transform ion cyclotron resonance cell with dynamic harmonization of the electric field in the whole volume by shaping of the excitation and detection electrode assembly

Abstract: A new principle of formation of the effective electric field distribution in a Penning trap is presented. It is based on the concept of electric potential space averaging via charged particle cyclotron motion. The method of making hyperbolic-type field distribution in the whole volume of a cylindrical Penning trap is developed on the basis of this new principal. The method is based on subdividing the cell cylindrical surface into segments with shapes producing quadratic dependence on axial coordinate of an averaged (along cyclotron motion orbit) electric potential at any radius of cyclotron motion. The cell performance is compared in digital experiments with the performance of a Gabrielse-type cylindrical cell with four compensation electrodes and is shown to be more effective in ion motion harmonization at higher cyclotron radii and axial oscillation amplitude.

Surface charge decay on polymeric materials under different neutralization modes in air

Abstract: Surface charge decay on thick flat samples of HTV silicone rubbers charged by impulse corona is studied. In the experiments, surfaces of the materials exposed to corona were kept open to ambient air whereas the opposite surfaces were in contact with a grounded copper plate and surface potential distributions on the samples were measured using Kelvin type electrostatic probe. The developed procedure allowed for implementation of three study cases when (i) neutralization of pre-deposited charges by free ions present in air was prevented and surface potential decay occurred mainly due to bulk neutralization; (ii) gas neutralization took place under natural conditions and (iii) gas neutralization was enhanced due to increased amount of free ions in ambient air provided by nearby corona. Potential decay observed only due to bulk neutralization was used to evaluate voltage dependent conductivity of the materials and allowed for comparing them with those measured by the standard method. Comparison of decay characteristics observed for different test conditions were used to evaluate the relative importance of each mechanism on the total process of charge decay.

Dust accumulation effect on efficiency of Si photovoltaic modules

Abstract: We experimentally studied the electrical efficiency effects of naturally forming atmospheric dust deposits on commercial photovoltaic panels. The variable considered for measurements was the electric potential for three commercial silicon modules: monocrystalline, polycrystalline, and amorphous. A mathematical model was developed to determine maximum potential as a function of temperature and of total incident radiation. The study presents two essential parts: the naturally deposited dust particles and the variation in maximum electric potential between clean and dirty modules. The results indicate that the maximum reduction in potential is around of 6% for monocrystalline and polycrystalline modules and of 12% for the amorphous silicon.

Electrokinetic particle translocation through a nanopore

Abstract: Nanoparticle electrophoretic translocation through a single nanopore induces a detectable change in the ionic current, which enables the nanopore-based sensing for various bio-analytical applications In this study, a transient continuum-based model is developed for the first time to investigate the electrokinetic particle translocation through a nanopore by solving the Nernst–Planck equations for the ionic concentrations, the Poisson equation for the electric potential and the Navier–Stokes equations for the flow field using an arbitrary Lagrangian–Eulerian (ALE) method When the applied electric field is relatively low, a current blockade is expected In addition, the particle could be trapped at the entrance of the nanopore when the electrical double layer (EDL) adjacent to the charged particle is relatively thick When the electric field imposed is relatively high, the particle can always pass through the nanopore by electrophoresis However, a current enhancement is predicted if the EDL of the particle is relatively thick The obtained numerical results qualitatively agree with the existing experimental results It is also found that the initial orientation of the particle could significantly affect the particle translocation and the ionic current through a nanopore Furthermore, a relatively high electric field tends to align the particle with its longest axis parallel to the local electric field However, the particle's initial lateral offset from the centerline of the nanopore acts as a minor effect

Externally applied electric fields up to 1.6 × 10(5) V/m do not affect the homogeneous nucleation of ice in supercooled water.

Abstract: The freezing of water can initiate at electrically conducting electrodes kept at a high electric potential or at charged electrically insulating surfaces. The microscopic mechanisms of these phenomena are unknown, but they must involve interactions between water molecules and electric fields. This paper investigates the effect of uniform electric fields on the homogeneous nucleation of ice in supercooled water. Electric fields were applied across drops of water immersed in a perfluorinated liquid using a parallel-plate capacitor; the drops traveled in a microchannel and were supercooled until they froze due to the homogeneous nucleation of ice. The distribution of freezing temperatures of drops depended on the rate of nucleation of ice, and the sensitivity of measurements allowed detection of changes by a factor of 1.5 in the rate of nucleation. Sinusoidal alternation of the electric field at frequencies from 3 to 100 kHz prevented free ions present in water from screening the electric field in the bulk o...

Single-dielectric barrier discharge plasma actuator modelling and validation

Abstract: Single-dielectric barrier discharge (SDBD) plasma actuators have gained a great deal of world-wide interest for flow-control applications. With this has come the need for flow-interaction models of plasma actuators that can be used in computational flow simulations. SDBD plasma actuators consist of two electrodes: one uncovered and exposed to the air and the other encapsulated by a dielectric material. An AC electric potential is supplied to the electrodes. When the AC potential is large enough, the air in the region over the encapsulated electrode ionizes. The ionized air in the presence of the electric field results in a space–time dependent body force vector field. The body force is the mechanism for flow control. This study describes a semi-empirical model that has been developed to capture the dynamic nature of the local air ionization and time-dependent body force vector distribution. Validation of the model includes comparisons to experimentally measured space–time charge distribution and the time-resolved and time-averaged body force. Two flow simulations are then used to further validate the SDBD plasma actuator model. These involved an impulsively started plasma actuator in still air, and the flow around a circular cylinder in which plasma actuators were used to suppress the Karman vortex street. In both cases, the simulations agreed well with the experiments.

Controlling Electric Dipoles in Nanodielectrics and Its Applications for Enabling Air-Stable n-Channel Organic Transistors

Abstract: We present a new method to manipulate the channel charge density of field-effect transistors using dipole-generating self-assembled monolayers (SAMs) with different anchor groups. Our approach maintains an ideal interface between the dipole layers and the semiconductor while changing the built-in electric potential by 0.41−0.50 V. This potential difference can be used to change effectively the electrical properties of nanoelectronic devices. We further demonstrate the application of the SAM dipoles to enable air-stable operation of n-channel organic transistors.

Electric field compensation and sensing with a single ion in a planar trap

Abstract: We use a single ion as a movable electric field sensor with accuracies on the order of a few V/m. For this, we compensate undesired static electric fields in a planar radio frequency trap and characterize the static field and its curvature over an extended region along the trap axis. We observe a strong buildup of stray charges around the loading region on the trap resulting in an electric field of up to 1.3 kV/m at the ion position. We also find that the profile of the stray field remains constant over a time span of a few months.

Dynamical polarization of graphene in a magnetic field

Abstract: The one-loop dynamical polarization function of graphene in an external magnetic field is calculated as a function of wave vector and frequency at finite chemical potential, temperature, band gap, and width of Landau levels. The exact analytic result is given in terms of digamma functions and generalized Laguerre polynomials and has the form of a double sum over Landau levels. Various limits (static, clean, etc.) are discussed. The Thomas-Fermi inverse length ${q}_{F}$ of screening of the Coulomb potential is found to be an oscillating function of a magnetic field and a chemical potential. At zero temperature and scattering rate, it vanishes when the Fermi level lies between the Landau levels.

Electrokinetic transport through nanochannels.

Abstract: This article presents a numerical study of the electrokinetic transport phenomena (electroosmosis and electrophoresis) in a three-dimensional nanochannel with a circular cross-section. Due to the nanometer dimensions, the Boltzmann distribution of the ions is not valid in the nanochannels. Therefore, the conventional theories of electrokinetic flow through the microchannels such as Poisson-Boltzmann equation and Helmholtz-Smoluchowski slip velocity approach are no longer applicable. In the current study, a set of coupled partial differential equations including Poisson-Nernst-Plank equation, Navier-Stokes, and continuity equations is solved to find the electric potential field, ionic concentration field, and the velocity field in the three-dimensional nanochannel. The effects of surface electric charge and the radius of nanochannel on the electric potential, liquid flow, and ionic transport are investigated. Unlike the microchannels, the electric potential field, ionic concentration field, and velocity field are strongly size-dependent in nanochannels. The electric potential gradient along the nanochannel also depends on the surface electric charge of the nanochannel. More counter ions than the coions are transported through the nanochannel. The ionic concentration enrichment at the entrance and the exit of the nanochannel is completely evident from the simulation results. The study also shows that the flow velocity in the nanochannel is higher when the surface electric charge is stronger or the radius of the nanochannel is larger.

An Interactive Simulation Tool for Complex Multilayer Dielectric Devices

Abstract: Novel devices incorporating multiple layers of new materials increase the complexity of device structures, particularly in field-effect transistors, capacitors, and nonvolatile memory (NVM). The mounting complexity of these devices increases the difficulty of generating energy band diagrams and performing device parameter calculations whether these calculations are done by hand, using spreadsheets, or via mathematical programs. Although finite-element Poisson-Schrodinger equation solvers are available to perform the calculations, the cost and time spent learning them can be a hindrance. A straightforward GUI interactive simulation tool is presented that quickly calculates and displays energy bands, electric fields, potentials, and charge distributions for 1-D metal-multilayered-dielectrics-semiconductor stacks. Fixed charge can be inserted into dielectric layers. The freeware program calculates device parameters, (e.g., effective oxide thickness, flat-band voltage (VFB), threshold voltage (Vt), stack capacitance) and layer parameters (e.g., capacitance, potential, electric field, tunneling distance). Calculated data can be exported. Using the simulation tool, trap-based flash NVM is examined. Device performance characteristics such as the Vt and VFB shifts of three different stacks are examined. Comparisons between the program and a finite-element Poisson-Schrodinger equation solver are performed to validate the program's accuracy.

Drive system for synchronous motor

Abstract: Provided is a position-sensorless drive method, wherein control of the rotational speed and torque of a permanent-magnet motor is executed by driving the motor with an ideal sinusoidal-wave current generated by a minimum necessary number of switching, using an inverter, and wherein driving from an extremely low speed range in the vicinity of zero is possible. A neutral point electric potential of a permanent-magnet motor (4) is detected by synchronizing with the PWM waveform of an inverter. The position of a rotor of the permanent-magnet motor (4) is surmised from changes in the neutral point electric potential. The rotor position of a three-phase synchronous motor is surmised by making, upon detecting the neutral point electric potential, three or four types of switching states wherein the output voltage of the inverter is not a zero vector, by shifting the timings of each of the phases of the PWM waveform, and sampling the neutral point electric potential in at least two types of switching states among those switching states.

Direct current driven by ac electric field in quantum wells

Abstract: It is shown that the excitation of charge carriers by ac electric field with zero average driving leads to a direct electric current in quantum well structures. The current emerges for both linear and circular polarization of the ac electric field and depends on the field polarization and frequency. We present a microscopic model and an analytical theory of such a nonlinear electron transport in quantum wells with structure inversion asymmetry. In such systems, the dc current is induced by ac electric field that has both the in-plane and out-of-plane components. The ac field polarized in the interface plane gives rise to a direct current if the quantum well is subjected to an in-plane static magnetic field.

Practical solutions for reliable triple probe measurements in magnetized plasmas

Abstract: The triple probe method to obtain local, time-resolved measurements of density, electron temperature and plasma potential is investigated in detail. The difficulties in obtaining reliable measurements with this technique are discussed and overcome. These include phase delay errors, ion sheath expansion and limited bandwidth due to stray capacitance to ground. In particular, a relatively simple electronic circuit is described to strongly reduce stray capacitance. Measurements with the triple probe are presented in a plasma characterized by interchange-driven turbulence in the TORPEX device. The measured time-averaged and time-dependent, conditionally averaged parameters are cross-checked with other Langmuir probe based techniques, and show good agreement. Triple probe measurements show that electron temperature fluctuations are sufficiently large, such that the identification of plasma potential fluctuations with fluctuations of the floating potential is not a good approximation. Over a large radial region, the time-averaged fluctuation-induced particle flux can, however, be deduced from floating potential only. This is because the phase shift between density and electron temperature is close to zero there and temperature fluctuations do not give rise to a net radial particle transport.

Plasma potential and turbulence dynamics in toroidal devices (survey of T-10 and TJ-II experiments)

Abstract: A direct comparison of the electric potential and its fluctuations in the T-10 tokamak and the TJ-II stellarator is presented for similar plasma conditions in the two machines, using the heavy ion beam probe diagnostic. We observed the following similarities: (i) plasma potentials of several hundred volts, resulting in a radial electric field Er of several tens of V?cm?1; (ii) a negative sign for the plasma potential at central line-averaged electron densities larger than 1\times 10^{19}\,{\rm m}^{-3} SRC=http://ej.iop.org/images/0029-5515/51/8/083043/nf381326in001.gif/>, with comparable values in both machines, even when using different heating methods; (iii) with increasing electron density ne or energy confinement time ?E, the potential evolves in the negative direction; (iv) with electron cyclotron resonance heating and associated increase in the electron temperature Te, ?E degrades and the plasma potential evolves in the positive direction. We generally find that the more negative potential and Er values correspond to higher values of ?E. Modelling indicates that basic neoclassical mechanisms contribute significantly to the formation of the electric potential in the core. Broadband turbulence is suppressed at spontaneous and biased transitions to improved confinement regimes and is always accompanied by characteristic changes in plasma potential profiles. Various types of quasi-coherent potential oscillations are observed, among them geodesic acoustic modes in T-10 and Alfv?n eigenmodes in TJ-II.

Separation of mixtures of particles in a multipart microdevice employing insulator‐based dielectrophoresis

Abstract: Dielectrophoresis is the electrokinetic movement of particles due to polarization effects in the presence of non-uniform electric fields. In insulator-based dielectrophoresis (iDEP) regions of low and high electric field intensity, i.e. non-uniformity of electric field, are produced when the cross-sectional area of a microchannel is decreased by the presence of electrical insulating structures between two electrodes. This technique is increasingly being studied for the manipulation of a wide variety of particles, and novel designs are continuously developed. Despite significant advances in the area, complex mixture separation and sample fractionation continue to be the most important challenges. In this work, a microchannel design is presented for carrying out direct current (DC)-iDEP for the separation of a mixture of particles. The device comprises a main channel, two side channels and two sections of cylindrical posts with different diameters, which will generate different non-uniformities in the electric field on the main channel, designed for the discrimination and separation of particles of two different sizes. By applying an electric potential of 1000 V, a mixture of 1 and 4 μm polystyrene microspheres were dielectrophoretically separated and concentrated at the same time and then redirected to different outlets. The results obtained here demonstrate that, by carefully designing the device geometry and selecting operating conditions, effective sorting of particle mixtures can be achieved in this type of multi-section DC-iDEP devices.

Using the charge-stabilization technique in the double ionization potential equation-of-motion calculations with dianion references

Abstract: The charge-stabilization method is applied to double ionization potential equation-of-motion (EOM-DIP) calculations to stabilize unstable dianion reference functions. The auto-ionizing character of the dianionic reference states spoils the numeric performance of EOM-DIP limiting applications of this method. We demonstrate that reliable excitation energies can be computed by EOM-DIP using a stabilized resonance wave function instead of the lowest energy solution corresponding to the neutral + free electron(s) state of the system. The details of charge-stabilization procedure are discussed and illustrated by examples. The choice of optimal stabilizing Coulomb potential, which is strong enough to stabilize the dianion reference, yet, minimally perturbs the target states of the neutral, is the crux of the approach. Two algorithms of choosing optimal parameters of the stabilization potential are presented. One is based on the orbital energies, and another – on the basis set dependence of the total Hartree-Fock energy of the reference. Our benchmark calculations of the singlet-triplet energy gaps in several diradicals show a remarkable improvement of the EOM-DIP accuracy in problematic cases. Overall, the excitation energies in diradicals computed using the stabilized EOM-DIP are within 0.2 eV from the reference EOM spin-flip values.