Electrochromism

About: Electrochromism is a research topic. Over the lifetime, 13097 publications have been published within this topic receiving 294637 citations.

Electrochromic device and method for manufacturing the same

Abstract: An electrochromic device and a method for manufacturing same, which device has at least a pair of opposed transparent electroconductive layers, a first transparent ion conductive layer provided between the pair of opposed electroconductive layers, a second transparent ion conductive layer adjacent to the first ion conductive layer, a reductive coloring electrochromic layer adjacent to the second ion conductive layer, wherein the first transparent ion conductive layer is formed in an atmosphere containing water vapor and the second transparent ion conductive layer is formed in an atmosphere containing oxygen. Thereby an electrochromic device can be provided, which device exhibits excellent durability when being driven at a high contrast ratio and high resistance to such environments as high temperature and humidity.

Synthesis, Electronic, and Emission Spectroscopy, and Electrochromic Characterization of Azulene−Fluorene Conjugated Oligomers and Polymers

Abstract: Two model compounds, 1,3-bis(9,9-dihexylfluoren-2-yl)azulene (M1), and 1,3-bis[7-(9,9,9′,9′-tetrahexyl-2,2′-bifluoren-7-yl)azulene (M2), and polymers, poly[2,7-(9,9-dialkylfluorenyl)-alt-(1′,3′-azulenyl)] (P1−P4) and poly{[1,3-bis(9′,9′-dihexylfluoren-2′-yl)azulenyl]-alt-[2′′,7′′-(9′′,9′′-dialkylfluorenyl]} (P5, P6) were synthesized by reacting 1,3-dibromoazulene or 1,3-bis(7-bromo-9,9-dihexylfluoren-2-yl)azulene with a suitable 9,9-dialkylflourenyl-2-borate or 2,7-diborate via Suzuki cross-coupling reactions. The thermal and optical properties of the polymers were characterized by thermogravimetric analysis, differential scanning calorimetry, and UV−vis and fluorescence spectroscopy. M1, M2, and P1−P6 are nonfluorescent in the neutral state in different organic solvents. However, M1, M2, P5, and P6 become fluorescent upon the addition of trifluoroacetic acid in THF, with relative quantum efficiencies of 0.004−0.06. The “switching on” of the fluorescence for the azulene−fluorene copolymers and model compo...

Parasitic Absorption Reduction in Metal Oxide-Based Transparent Electrodes: Application in Perovskite Solar Cells

Abstract: Transition metal oxides (TMOs) are commonly used in a wide spectrum of device applications, thanks to their interesting electronic, photochromic, and electrochromic properties. Their environmental sensitivity, exploited for gas and chemical sensors, is however undesirable for application in optoelectronic devices, where TMOs are used as charge injection or extraction layers. In this work, we first study the coloration of molybdenum and tungsten oxide layers, induced by thermal annealing, Ar plasma exposure, or transparent conducting oxide overlayer deposition, typically used in solar cell fabrication. We then propose a discoloration method based on an oxidizing CO2 plasma treatment, which allows for a complete bleaching of colored TMO films and prevents any subsequent recoloration during following cell processing steps. Then, we show that tungsten oxide is intrinsically more resilient to damage induced by Ar plasma exposure as compared to the commonly used molybdenum oxide. Finally, we show that parasitic...