Showing papers on "Energy source published in 2013"

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

Abstract: Two major energy-related problems confront the world in the next 50 years. First, increased worldwide competition for gradually depleting fossil fuel reserves (derived from past photosynthesis) will lead to higher costs, both monetarily and politically. Second, atmospheric CO_2 levels are at their highest recorded level since records began. Further increases are predicted to produce large and uncontrollable impacts on the world climate. These projected impacts extend beyond climate to ocean acidification, because the ocean is a major sink for atmospheric CO2.1 Providing a future energy supply that is secure and CO_2-neutral will require switching to nonfossil energy sources such as wind, solar, nuclear, and geothermal energy and developing methods for transforming the energy produced by these new sources into forms that can be stored, transported, and used upon demand.

Throughput Maximization in Wireless Powered Communication Networks

Abstract: This paper studies the newly emerging wireless powered communication network in which one hybrid access point (H-AP) with constant power supply coordinates the wireless energy/information transmissions to/from a set of distributed users that do not have other energy sources. A "harvest-then-transmit" protocol is proposed where all users first harvest the wireless energy broadcast by the H-AP in the downlink (DL) and then send their independent information to the H-AP in the uplink (UL) by time-division-multiple-access (TDMA). First, we study the sum-throughput maximization of all users by jointly optimizing the time allocation for the DL wireless power transfer versus the users' UL information transmissions given a total time constraint based on the users' DL and UL channels as well as their average harvested energy values. By applying convex optimization techniques, we obtain the closed-form expressions for the optimal time allocations to maximize the sum-throughput. Our solution reveals an interesting "doubly near-far" phenomenon due to both the DL and UL distance-dependent signal attenuation, where a far user from the H-AP, which receives less wireless energy than a nearer user in the DL, has to transmit with more power in the UL for reliable information transmission. As a result, the maximum sum-throughput is shown to be achieved by allocating substantially more time to the near users than the far users, thus resulting in unfair rate allocation among different users. To overcome this problem, we furthermore propose a new performance metric so-called common-throughput with the additional constraint that all users should be allocated with an equal rate regardless of their distances to the H-AP. We present an efficient algorithm to solve the common-throughput maximization problem. Simulation results demonstrate the effectiveness of the common-throughput approach for solving the new doubly near-far problem in wireless powered communication networks.

A review of energy sources and energy management system in electric vehicles

Abstract: The issues of global warming and depletion of fossil fuels have paved opportunities to electric vehicle (EV). Moreover, the rapid development of power electronics technologies has even realized high energy-efficient vehicles. EV could be the alternative to decrease the global green house gases emission as the energy consumption in the world transportation is high. However, EV faces huge challenges in battery cost since one-third of the EV cost lies on battery. This paper reviews state-of-the-art of the energy sources, storage devices, power converters, low-level control energy management strategies and high supervisor control algorithms used in EV. The comparison on advantages and disadvantages of vehicle technology is highlighted. In addition, the standards and patterns of drive cycles for EV are also outlined. The advancement of power electronics and power processors has enabled sophisticated controls (low-level and high supervisory algorithms) to be implemented in EV to achieve optimum performance as well as the realization of fast-charging stations. The rapid growth of EV has led to the integration of alternative resources to the utility grid and hence smart grid control plays an important role in managing the demand. The awareness of environmental issue and fuel crisis has brought up the sales of EV worldwide.

Throughput Maximization in Wireless Powered Communication Networks

Abstract: This paper studies the newly emerging wireless powered communication network (WPCN) in which one hybrid access point (H-AP) with constant power supply coordinates the wireless energy/information transmissions to/from distributed users that do not have energy sources. A "harvest-then-transmit" protocol is proposed where all users first harvest the wireless energy broadcast by the H-AP in the downlink (DL) and then send their independent information to the H-AP in the uplink (UL) by time-division-multiple-access (TDMA). First, we study the sum-throughput maximization of all users by jointly optimizing the time allocation for the DL wireless power transfer versus the users' UL information transmissions given a total time constraint based on the users' DL and UL channels as well as their average harvested energy values. By applying convex optimization techniques, we obtain the closed-form expressions for the optimal time allocations to maximize the sum-throughput. Our solution reveals "doubly near-far" phenomenon due to both the DL and UL distance-dependent signal attenuation, where a far user from the H-AP, which receives less wireless energy than a nearer user in the DL, has to transmit with more power in the UL for reliable information transmission. Consequently, the maximum sum-throughput is achieved by allocating substantially more time to the near users than the far users, thus resulting in unfair rate allocation among different users. To overcome this problem, we furthermore propose a new performance metric so-called common-throughput with the additional constraint that all users should be allocated with an equal rate regardless of their distances to the H-AP. We present an efficient algorithm to solve the common-throughput maximization problem. Simulation results demonstrate the effectiveness of the common-throughput approach for solving the new doubly near-far problem in WPCNs.

The gut microbiota suppresses insulin-mediated fat accumulation via the short-chain fatty acid receptor GPR43

Abstract: The gut microbiota affects nutrient acquisition and energy regulation of the host, and can influence the development of obesity, insulin resistance, and diabetes. During feeding, gut microbes produce short-chain fatty acids, which are important energy sources for the host. Here we show that the short-chain fatty acid receptor GPR43 links the metabolic activity of the gut microbiota with host body energy homoeostasis. We demonstrate that GPR43-deficient mice are obese on a normal diet, whereas mice overexpressing GPR43 specifically in adipose tissue remain lean even when fed a high-fat diet. Raised under germ-free conditions or after treatment with antibiotics, both types of mice have a normal phenotype. We further show that short-chain fatty acid-mediated activation of GPR43 suppresses insulin signalling in adipocytes, which inhibits fat accumulation in adipose tissue and promotes the metabolism of unincorporated lipids and glucose in other tissues. These findings establish GPR43 as a sensor for excessive dietary energy, thereby controlling body energy utilization while maintaining metabolic homoeostasis.

Common envelope evolution: where we stand and how we can move forward

Abstract: This work aims to present our current best physical understanding of common-envelope evolution (CEE). We highlight areas of consensus and disagreement, and stress ideas which should point the way forward for progress in this important but long-standing and largely unconquered problem. Unusually for CEE-related work, we mostly try to avoid relying on results from population synthesis or observations, in order to avoid potentially being misled by previous misunderstandings. As far as possible we debate all the relevant issues starting from physics alone, all the way from the evolution of the binary system immediately before CEE begins to the processes which might occur just after the ejection of the envelope. In particular, we include extensive discussion about the energy sources and sinks operating in CEE, and hence examine the foundations of the standard energy formalism. Special attention is also given to comparing the results of hydrodynamic simulations from different groups and to discussing the potential effect of initial conditions on the differences in the outcomes. We compare current numerical techniques for the problem of CEE and also whether more appropriate tools could and should be produced (including new formulations of computational hydrodynamics, and attempts to include 3D processes within 1D codes). Finally we explore new ways to link CEE with observations. We compare previous simulations of CEE to the recent outburst from V1309 Sco, and discuss to what extent post-common-envelope binaries and nebulae can provide information, e.g. from binary eccentricities, which is not currently being fully exploited.

Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption

Abstract: The development of hydrogen-based energy sources as viable alternatives to fossil-fuel technologies has revolutionized clean energy production using fuel cells However, to date, the slow rate of the hydrogen oxidation reaction (HOR) in alkaline environments has hindered advances in alkaline fuel cell systems Here, we address this by studying the trends in the activity of the HOR in alkaline environments We demonstrate that it can be enhanced more than fivefold compared to state-of-the-art platinum catalysts The maximum activity is found for materials (Ir and Pt₀₁Ru₀₉) with an optimal balance between the active sites that are required for the adsorption/dissociation of H₂ and for the adsorption of hydroxyl species (OHad) We propose that the more oxophilic sites on Ir (defects) and PtRu material (Ru atoms) electrodes facilitate the adsorption of OHad species Those then react with the hydrogen intermediates (Had) that are adsorbed on more noble surface sites

Targeting lactate metabolism for cancer therapeutics

Abstract: Lactate, once considered a waste product of glycolysis, has emerged as a critical regulator of cancer development, maintenance, and metastasis. Indeed, tumor lactate levels correlate with increased metastasis, tumor recurrence, and poor outcome. Lactate mediates cancer cell intrinsic effects on metabolism and has additional non–tumor cell autonomous effects that drive tumorigenesis. Tumor cells can metabolize lactate as an energy source and shuttle lactate to neighboring cancer cells, adjacent stroma, and vascular endothelial cells, which induces metabolic reprogramming. Lactate also plays roles in promoting tumor inflammation and in functioning as a signaling molecule that stimulates tumor angiogenesis. Here we review the mechanisms of lactate production and transport and highlight emerging evidence indicating that targeting lactate metabolism is a promising approach for cancer therapeutics.

X-ray-Computed Tomography Contrast Agents

Abstract: X-ray computed tomography (CT) is a well-established tissue imaging technique employed in a variety of research and clinical settings.1 Specifically, CT is a non-invasive clinical diagnostic tool that allows for 3D visual reconstruction and segmentation of tissues of interest. High resolution CT systems can be used to perform non-destructive 3D imaging of a variety of tissue types and organ systems, such as: the gastrointestinal tract, cardiovascular system, renal tract, liver, lungs, bone, cartilage, tumorous tissue, etc. CT is one of the most prevalent diagnostic tools in terms of frequency-of-use and hospital availability.2 The use of CT is on the rise and the number of clinical CT scanners in operation worldwide is estimated at over 45,000.1b Today, over 70 million clinical CT scans are performed yearly in the U.S. alone. For a recent detailed analysis of the use of clinical CT imaging and data regarding the number of regular and contrast-enhanced CT scans performed annually in the U.S. we refer the reader to the “Nationwide Evaluation of X-ray Trends” survey published by the Conference for Radiation Control Program Directors (CRCPD).3 The idea of using tomography (Greek: tomos = slice, graphein = draw) as a diagnostic tool in medicine was adopted soon after the discovery of X-rays by W. C. Roentgen in 1895. However, several more decades passed before the technology advanced sufficiently to bring those ideas to fruition. The first successful CT imaging device was built in 1972 by G. N. Hounsfield, at Electric and Musical Industries Ltd. In 1979, G. N. Hounsfield and South African physicist A. M. Cormack shared a Nobel Prize in medicine for their contributions to the field of X-ray CT imaging and diagnostics.4 X-rays are a form of electromagnetic radiation with wavelengths roughly between 0.01 nm and 10 nm. Traditionally, X-rays are generated by a vacuum tube using high voltage to accelerate electrons from a cathode to a (usually) tungsten-alloy anode. In the process, the accelerated electrons release electromagnetic radiation in the form of X-rays and the maximum energy of the radiation is limited by the energy of the incident electron. Operating voltages of modern clinical CT scanners differ among instrument models and manufacturers, but generally fall between 80 kVp to 150 kVp. As a rule, materials possessing higher density (ρ) or high atomic number (Z) tend to better absorb X-rays. The relationship is best expressed in the formula for X-ray absorption coefficient (μ): μ≈ρZ4AE3 (1) where “A” is the atomic mass and “E” is the X-ray energy. The strong relationship between absorption and atomic number is of significant importance in clinical applications. The Z4 factor allows for contrast levels of several orders of magnitude between different tissues and types of contrast agents. When an incident X-ray has energy equal or slightly greater than the binding energy of the K-shell electron of the atom, a large sudden increase in absorption coefficient is observed. This energy value is known as absorption edge (k), and the k value increases with atomic number of the element. Consequently, X-ray attenuating contrast media containing atoms of high atomic number (most commonly iodine or barium), are frequently used in clinical settings to obtain images of soft tissues. To generate images with the highest contrast to the surrounding tissue, the energy of the X-ray source can be adjusted to closely match the absorption edge value (k) of the relevant imaging-agent atoms (i.e., iodine, barium, gold, etc.). Thus, it is also possible to do selective X-ray imaging and to differentiate between attenuating materials by fine tuning the energy source to the appropriate absorption edge value. A CT image is obtained by rotating an X-ray source around an object, with a detector positioned directly opposite the radiation source. Alternatively, in many preclinical CT scanners the object sometimes is rotated around its own axis. Such preclinical scanners are often being used for small animal in vivo imaging. Generally, X-ray scans are taken at small angular increments during rotation around the object over 360°. A series of attenuation profiles or projections is thus obtained. The projections are then processed mathematically to create a 3D rendition of the scanned object. An in depth description of the engineering principles underlying modern CT imaging instruments is beyond the scope of this manuscript, and the reader is referred to other published works.1c,5 A diagnostic imaging method related to CT is X-ray fluoroscopy. Fluoroscopy allows for the acquisition of real-time, continuous images of the internal organs. Like in CT, imaging agents are often used in fluoroscopy for better contrast resolution. Small iodinated agents are commonly injected into blood vessels for use in fluoroscopic angiography, allowing for the evaluation of blood flow and visualization of the vasculature system, while barium contrast media are introduced orally or with an enema to investigate the anatomy (and pathology) of the gastrointestinal tract. The introduction of magnetic resonance imaging (MRI) resulted in a loss of interest and reduction in CT contrast agent development throughout the 1980s. However, advances in computer technology, and the introduction and widespread adoption of spiral-CT in the mid-1990s have sparked a revival of interest in CT imaging and CT contrast media. Current clinical CT scanners are capable of acquiring high resolution 3D isotropic images of the body within several minutes. CT imaging today is less time consuming, less expensive, and more readily available than other medical imaging technologies such as MRI and positron emission tomography (PET). In the last several years, the emergence of novel technologies such as dual-source CT, and multi-detector CT has advanced the field of CT imaging even further. As a comparison to X-ray imaging diagnostic methods, PET imaging employs gamma-ray emitting radioactive nuclei “tracers” as contrast agents while MRI takes advantage of nuclear magnetic resonance principles by applying high magnetic fields to align magnetization of certain atomic nuclei. In contrast to CT and PET imaging, MRI uses no ionizing radiation and it is therefore often deemed safer than the other two.

High performance photovoltaic applications using solution-processed small molecules.

Abstract: Energy remains a critical issue for the survival and prosperity of humancivilization. Many experts believe that the eventual solution for sustainable energy is the use of direct solar energy as the main energy source. Among the options for renewable energy, photovoltaic technologies that harness solar energy offer a way to harness an unlimited resource and minimum environment impact in contrast with other alternatives such as water, nuclear, and wind energy.Currently, almost all commercial photovoltaic technologies use Si-based technology, which has a number of disadvantages including high cost, lack of flexibility, and the serious environmental impact of the Si industry. Other technologies, such as organic photovoltaic (OPV) cells, can overcome some of these issues. Today, polymer-based OPV (P-OPV) devices have achieved power conversion efficiencies (PCEs) that exceed 9%. Compared with P-OPV, small molecules based OPV (SM-OPV) offers further advantages, including a defined structure for more reproducible...

Hydrothermal liquefaction (HTL) of microalgae for biofuel production: State of the art review and future prospects

Abstract: Among the various types of biomass, microalgae have the potential of becoming a significant energy source for biofuel production in the coming years. Currently, research is mainly focusing on optimization of the cultivation methods and the conversion of just a single microalgae fraction (lipids for biodiesel production). Hydrothermal liquefaction is a method for thermochemical conversion of wet microalgae, producing a liquid energy carrier called ‘bio-oil’ or ‘biocrude’, next to gaseous, aqueous and solid by-products. A review of the available literature is presented here, analyzing the influence of parameters such as temperature, holding time and catalyst dosage on the yield and properties of the different product fractions. Also, the strain selection and the status of the technology for hydrothermal processes are analyzed. Finally, based on the findings obtained from the literature review, directions for future research are suggested.

Meshworm: A Peristaltic Soft Robot With Antagonistic Nickel Titanium Coil Actuators

Abstract: This paper presents the complete development and analysis of a soft robotic platform that exhibits peristaltic locomotion. The design principle is based on the antagonistic arrangement of circular and longitudinal muscle groups of Oligochaetes. Sequential antagonistic motion is achieved in a flexible braided mesh-tube structure using a nickel titanium (NiTi) coil actuators wrapped in a spiral pattern around the circumference. An enhanced theoretical model of the NiTi coil spring describes the combination of martensite deformation and spring elasticity as a function of geometry. A numerical model of the mesh structures reveals how peristaltic actuation induces robust locomotion and details the deformation by the contraction of circumferential NiTi actuators. Several peristaltic locomotion modes are modeled, tested, and compared on the basis of speed. Utilizing additional NiTi coils placed longitudinally, steering capabilities are incorporated. Proprioceptive potentiometers sense segment contraction, which enables the development of closed-loop controllers. Several appropriate control algorithms are designed and experimentally compared based on locomotion speed and energy consumption. The entire mechanical structure is made of flexible mesh materials and can withstand significant external impact during operation. This approach allows a completely soft robotic platform by employing a flexible control unit and energy sources.

High Energy Density Metal-Air Batteries: A Review

Abstract: In the last few decades, there are some exciting developments in the field of lithium (Li)-ion batteries from small portable devices to large power system such as electric vehicles (EVs). However, the maximum energy density of lithium-ion batteries is insufficient for the extended range of EVs propulsion. On the other hand, metal-air batteries have a greater power storage capacity, a few times more than the best performing lithium-ion batteries. Mechanically rechargeable zinc (Zn)-, magnesium (Mg)-, and aluminum (Al)-air batteries are receiving increasing attention, due to the advantages of using safe, low cost and abundant materials. If successfully developed, these batteries could provide an energy source for EVs comparing that of gasoline in terms of usable energy density. Nevertheless, there are still numerous scientific and technical challenges that must be overcome, if this alluring promise can be turned into reality. This paper provides a comprehensive overview of recent advances and challenges of metal air batteries from various elements, including air cathode, electrolyte, and anode. In addition, this review outlines the fundamental principles and understanding of the electrochemical reactions in the areas of lithium-air batteries. Finally, a summary of future research directions in the field of the metal-air batteries is provided.

The last decade of global anthropogenic sulfur dioxide: 2000-2011 emissions

Abstract: The evolution of global and regional anthropogenic SO2 emissions in the last decade has been estimated through a bottom-up calculation. After increasing until about 2006, we estimate a declining trend continuing until 2011. However, there is strong spatial variability, with North America and Europe continuing to reduce emissions, with an increasing role of Asia and international shipping. China remains a key contributor, but the introduction of stricter emission limits followed by an ambitious program of installing flue gas desulfurization on power plants resulted in a significant decline in emissions from the energy sector and stabilization of total Chinese SO2 emissions. Comparable mitigation strategies are not yet present in several other Asian countries and industrial sectors in general, while emissions from international shipping are expected to start declining soon following an international agreement to reduce the sulfur content of fuel oil. The estimated trends in global SO2 emissions are within the range of representative concentration pathway (RCP) projections and the uncertainty previously estimated for the year 2005.

The case for organic photovoltaics

Abstract: Increasing demand for energy worldwide, driven largely by the developing world, coupled with the tremendous hidden costs associated with traditional energy sources necessitates an unprecedented fraction of the future global energy mix come from sustainable, renewable sources. The potential solar energy resource dwarfs that of all other renewable sources combined, yet only two photovoltaic technologies are known to have the potential to be scaled up to make dramatic impact on the overall energy mix: silicon and organic photovoltaics. In this paper, we present the long-term sustainability advantages of organics when compared to silicon and other photovoltaic technologies in terms of energy payback time and global warming potential while also discussing the outlook for transitional applications of organic solar cells.

Throughput Maximization for the Gaussian Relay Channel with Energy Harvesting Constraints

Abstract: This paper considers the use of energy harvesters, instead of conventional time-invariant energy sources, in wireless cooperative communication. For the purpose of exposition, we study the classic three-node Gaussian relay channel with decode-and-forward (DF) relaying, in which the source and relay nodes transmit with power drawn from energy-harvesting (EH) sources. Assuming a deterministic EH model under which the energy arrival time and the harvested amount are known prior to transmission, the throughput maximization problem over a finite horizon of N transmission blocks is investigated. In particular, two types of data traffic with different delay constraints are considered: delay-constrained (DC) traffic (for which only one-block decoding delay is allowed at the destination) and no-delay-constrained (NDC) traffic (for which arbitrary decoding delay up to N blocks is allowed). For the DC case, we show that the joint source and relay power allocation over time is necessary to achieve the maximum throughput, and propose an efficient algorithm to compute the optimal power profiles. For the NDC case, although the throughput maximization problem is non-convex, we prove the optimality of a separation principle for the source and relay power allocation problems, based upon which a two-stage power allocation algorithm is developed to obtain the optimal source and relay power profiles separately. Furthermore, we compare the DC and NDC cases, and obtain the sufficient and necessary conditions under which the NDC case performs strictly better than the DC case. It is shown that NDC transmission is able to exploit a new form of diversity arising from the independent source and relay energy availability over time in cooperative communication, termed "energy diversity", even with time-invariant channels.

Energetic cost of brain functional connectivity.

Abstract: The brain's functional connectivity is complex, has high energetic cost, and requires efficient use of glucose, the brain's main energy source. It has been proposed that regions with a high degree of functional connectivity are energy efficient and can minimize consumption of glucose. However, the relationship between functional connectivity and energy consumption in the brain is poorly understood. To address this neglect, here we propose a simple model for the energy demands of brain functional connectivity, which we tested with positron emission tomography and MRI in 54 healthy volunteers at rest. Higher glucose metabolism was associated with proportionally larger MRI signal amplitudes, and a higher degree of connectivity was associated with nonlinear increases in metabolism, supporting our hypothesis for the energy efficiency of the connectivity hubs. Basal metabolism (in the absence of connectivity) accounted for 30% of brain glucose utilization, which suggests that the spontaneous brain activity accounts for 70% of the energy consumed by the brain. The energy efficiency of the connectivity hubs was higher for ventral precuneus, cerebellum, and subcortical hubs than for cortical hubs. The higher energy demands of brain communication that hinges upon higher connectivity could render brain hubs more vulnerable to deficits in energy delivery or utilization and help explain their sensitivity to neurodegenerative conditions, such as Alzheimer's disease.

System for performing surgical procedures with a reusable instrument module

Abstract: A surgical instrument is provided including an outer housing shell defining a cavity, the outer housing shell defining an upper outer housing half and a lower outer housing half, wherein the upper outer housing half defines a longitudinal axis and an instrument module selectively insertable into the cavity of the outer housing shell. The instrument module includes an inner housing shell, at least one motor disposed within the inner housing shell, a control board being in electrical communication with the at least one motor and an energy source being in electrical communication with the at least one motor and the control board. The instrument module is inserted into the cavity of the outer housing shell in such a manner that the operative axis of the at least one motor is substantially parallel to the longitudinal axis of the upper outer housing half.

GIS-based solar farms site selection using analytic hierarchy process (AHP) in Karapinar region, Konya/Turkey

Abstract: Renewable energy is clean sources and has a much lower environmental impact than other energy sources. In Turkey, solar energy investments have been developed rapidly in recent years. Site selection for solar farms is a critical issue for large investments because of quality of terrain, local weathering factors, proximity to high transmission capacity lines, agricultural facilities and environmental conservation issues. Multi criteria evaluation methods are often used for different site selection studies. The purpose of this study was to determine suitable site selection for solar farms by using GIS and AHP in the study area. The final index model was grouped into four categories as “low suitable”, “moderate”, “suitable” and “best suitable” with an equal interval classification method. As a result, 15.38% (928.18 km 2 ) of the study area has low suitable, 14.38% (867.83 km 2 ) has moderate suitable, 15.98% (964.39 km 2 ) has suitable and 13.92% (840.07 km 2 ) has best suitable for solar farms area. 40.34% (2434.52 km 2 ) of the study area is not suitable for solar farm areas.

Design and preparation of materials for advanced electrochemical storage

Abstract: To meet the growing global demand for energy while preserving the environment, it is necessary to drastically reduce the world's dependence on non-renewable energy sources. At the core of this effort will be the ability to efficiently convert, store, transport and access energy in a variety of ways. Batteries for use in small consumer devices have saturated society; however, if they are ever to be useful in large-scale applications such as automotive transportation or grid-storage, they will require new materials with dramatically improved performance. Efforts must also focus on using Earth-abundant and nontoxic compounds so that whatever developments are made will not create new environmental problems. In this Account, we describe a general strategy for the design and development of new insertion electrode materials for Li(Na)-ion batteries that meet these requirements. We begin by reviewing the current state of the art of insertion electrodes and highlighting the intrinsic material properties of electrodes that must be re-engineered for extension to larger-scale applications. We then present a detailed discussion of the relevant criteria for the conceptual design and appropriate selection of new electrode chemical compositions. We describe how the open-circuit voltage of Li-ion batteries can be manipulated and optimized through structural and compositional tuning by exploiting differences in the electronegativity among possible electrode materials. We then discuss which modern synthetic techniques are most sustainable, allowing the creation of new materials via environmentally responsible reactions that minimize the use of energy and toxic solvents. Finally, we present a case study showing how we successfully employed these approaches to develop a large number of new, useful electrode materials within the recently discovered family of transition metal fluorosulfates. This family has attracted interest as a possible source of improved Li-ion batteries in larger scale applications and benefits from a relatively "green" synthesis.

The changing paradigm in CO2 utilization

Abstract: CO2 is today at the centre of the attention of scientists and technologists for its potential as source of carbon in the synthesis of chemicals and fuels. The actual utilization of CO2 although significant for the chemical industry (ca. 200 Mt/y) represents a minor fraction of the anthropogenic emission (32,000 Mt/y). So far, only thermal routes were exploited, based on the use of fossil carbon as source of energy. This has brought to the exploitation of low-energy reactions, making a few chemicals. The changing paradigm in the use of perennial energy sources such as solar-, wind- and geothermal-energy, makes possible the exploitation of reactions that are more energy intensive and bring to products such as fuels that have a large market. This paper makes an analysis of the potential of several applications, highlighting barriers to a large scale conversion and identifying technologies that can make possible and economically acceptable the conversion of CO2 into fuels. Cycling large volumes of CO2 represents a way to control both its immission into the atmosphere and the extraction of fossil fuels.

Bistable vibration energy harvesters: A review

Abstract: Powering electronics without depending on batteries is an open research field. Mechanical vibrations prove to be a reliable energy source, but low-frequency broadband vibrations cannot be harvested effectively using linear oscillators. This article discusses an alternative for harvesting such vibrations, with energy harvesters with two stable configurations. The challenges related to nonlinear dynamics are briefly discussed. Different existing designs of bistable energy harvesters are presented and classified, according to their feasibility for miniaturization. A general dynamic model for those designs is described. Finally, an extensive discussion on quantitative measures of evaluating the effectiveness of energy harvesters is accomplished, resulting in the proposition of a new dimensionless metric suited for a broadband analysis.

Solar energy: Trends and enabling technologies

Abstract: The global demand for energy is currently growing beyond the limits of installable generation capacity. To meet future energy demands efficiently, energy security and reliability must be improved and alternative energy sources must be investigated aggressively. An effective energy solution should be able to address long-term issues by utilizing alternative and renewable energy sources. Of the many available renewable sources of energy, solar energy is clearly a promising option as it is extensively available. Solar power, especially as it reaches more competitive levels with other energy sources in terms of cost, may serve to sustain the lives of millions of underprivileged people in developing countries. Furthermore, solar energy devices can benefit the environment and economy of developing countries. This paper illustrates the need for the utilization of alternative energy sources, evaluates the global scenario of installed generation systems, reviews technologies underlying various solar powered devices, and discusses several applications and challenges in this area. In addition, this paper addresses the costs of deployment, maintenance, and operation, as well as economic policies that promote installation of solar energy systems.

A light-driven sodium ion pump in marine bacteria

Abstract: Light-driven proton-pumping rhodopsins are widely distributed in many microorganisms. They convert sunlight energy into proton gradients that serve as energy source of the cell. Here we report a new functional class of a microbial rhodopsin, a light-driven sodium ion pump. We discover that the marine flavobacterium Krokinobacter eikastus possesses two rhodopsins, the first, KR1, being a prototypical proton pump, while the second, KR2, pumps sodium ions outward. Rhodopsin KR2 can also pump lithium ions, but converts to a proton pump when presented with potassium chloride or salts of larger cations. These data indicate that KR2 is a compatible sodium ion-proton pump, and spectroscopic analysis showed it binds sodium ions in its extracellular domain. These findings suggest that light-driven sodium pumps may be as important in situ as their proton-pumping counterparts.