Showing papers on "Energy source published in 2014"

Photocatalytic Conversion of CO 2 into Renewable Hydrocarbon Fuels: State‐of‐the‐Art Accomplishment, Challenges, and Prospects

Abstract: Photocatalytic reduction of CO2 into hydrocarbon fuels, an artificial photosynthesis, is based on the simulation of natural photosynthesis in green plants, whereby O2 and carbohydrates are produced from H2 O and CO2 using sunlight as an energy source. It couples the reductive half-reaction of CO2 fixation with a matched oxidative half-reaction such as water oxidation, to achieve a carbon neutral cycle, which is like killing two birds with one stone in terms of saving the environment and supplying future energy. The present review provides an overview and highlights recent state-of-the-art accomplishments of overcoming the drawback of low photoconversion efficiency and selectivity through the design of highly active photocatalysts from the point of adsorption of reactants, charge separation and transport, light harvesting, and CO2 activation. It specifically includes: i) band-structure engineering, ii) nanostructuralization, iii) surface oxygen vacancy engineering, iv) macro-/meso-/microporous structuralization, v) exposed facet engineering, vi) co-catalysts, vii) the development of a Z-scheme system. The challenges and prospects for future development of this field are also present.

Quantitative flux analysis reveals folate-dependent NADPH production

Abstract: ATP is the dominant energy source in animals for mechanical and electrical work (for example, muscle contraction or neuronal firing). For chemical work, there is an equally important role for NADPH, which powers redox defence and reductive biosynthesis1. The most direct route to produce NADPH from glucose is the oxidative pentose phosphate pathway, with malic enzyme sometimes also important2, 3. Although the relative contribution of glycolysis and oxidative phosphorylation to ATP production has been extensively analysed, similar analysis of NADPH metabolism has been lacking. Here we demonstrate the ability to directly track, by liquid chromatography–mass spectrometry, the passage of deuterium from labelled substrates into NADPH, and combine this approach with carbon labelling and mathematical modelling to measure NADPH fluxes. In proliferating cells, the largest contributor to cytosolic NADPH is the oxidative pentose phosphate pathway. Surprisingly, a nearly comparable contribution comes from serine-driven one-carbon metabolism, in which oxidation of methylene tetrahydrofolate to 10-formyl-tetrahydrofolate is coupled to reduction of NADP+ to NADPH. Moreover, tracing of mitochondrial one-carbon metabolism revealed complete oxidation of 10-formyl-tetrahydrofolate to make NADPH. As folate metabolism has not previously been considered an NADPH producer, confirmation of its functional significance was undertaken through knockdown of methylenetetrahydrofolate dehydrogenase (MTHFD) genes. Depletion of either the cytosolic or mitochondrial MTHFD isozyme resulted in decreased cellular NADPH/NADP+ and reduced/oxidized glutathione ratios (GSH/GSSG) and increased cell sensitivity to oxidative stress. Thus, although the importance of folate metabolism for proliferating cells has been long recognized and attributed to its function of producing one-carbon units for nucleic acid synthesis, another crucial function of this pathway is generating reducing power.

Revealing the Bacterial Butyrate Synthesis Pathways by Analyzing (Meta)genomic Data

Abstract: Butyrate-producing bacteria have recently gained attention, since they are important for a healthy colon and when altered contribute to emerging diseases, such as ulcerative colitis and type II diabetes. This guild is polyphyletic and cannot be accurately detected by 16S rRNA gene sequencing. Consequently, approaches targeting the terminal genes of the main butyrate- producing pathway have been developed. However, since additional pathways exist and alternative, newly recognized enzymes catalyzing the terminal reaction have been described, previous investigations are often incomplete. We undertook a broad analy- sis of butyrate-producing pathways and individual genes by screening 3,184 sequenced bacterial genomes from the Integrated Microbial Genome database. Genomes of 225 bacteria with a potential to produce butyrate were identified, including many pre- viously unknown candidates. The majority of candidates belong to distinct families within the Firmicutes, but members of nine other phyla, especially from Actinobacteria,Bacteroidetes,Fusobacteria,Proteobacteria,Spirochaetes, andThermotogae, were also identified as potential butyrate producers. The established gene catalogue (3,055 entries) was used to screen for butyrate synthesis pathways in 15 metagenomes derived from stool samples of healthy individuals provided by the HMP (Human Micro- biome Project) consortium. A high percentage of total genomes exhibited a butyrate-producing pathway (mean, 19.1%; range, 3.2% to 39.4%), where the acetyl-coenzyme A (CoA) pathway was the most prevalent (mean, 79.7% of all pathways), followed by the lysine pathway (mean, 11.2%). Diversity analysis for the acetyl-CoA pathway showed that the same fewfirmicute groups as- sociated with several Lachnospiraceae andRuminococcaceae were dominating in most individuals, whereas the other pathways were associated primarily with Bacteroidetes. IMPORTANCE Microbiome research has revealed new, important roles of our gut microbiota for maintaining health, but an un- derstanding of effects of specific microbial functions on the host is in its infancy, partly because in-depth functional microbial analyses are rare and publicly available databases are often incomplete/misannotated. In this study, we focused on production of butyrate, the main energy source for colonocytes, which plays a critical role in health and disease. We have provided a complete database of genes from major known butyrate-producing pathways, using in-depth genomic analysis of publicly available ge- nomes,filling an important gap to accurately assess the butyrate-producing potential of complex microbial communities from "-omics"-derived data. Furthermore, a reference data set containing the abundance and diversity of butyrate synthesis pathways from the healthy gut microbiota was established through a metagenomics-based assessment. This study will help in understand- ing the role of butyrate producers in health and disease and may assist the development of treatments for functional dysbiosis.

Sharp increase in central Oklahoma seismicity since 2008 induced by massive wastewater injection

Abstract: Unconventional oil and gas production provides a rapidly growing energy source; however, high-production states in the United States, such as Oklahoma, face sharply rising numbers of earthquakes. Subsurface pressure data required to unequivocally link earthquakes to wastewater injection are rarely accessible. Here we use seismicity and hydrogeological models to show that fluid migration from high-rate disposal wells in Oklahoma is potentially responsible for the largest swarm. Earthquake hypocenters occur within disposal formations and upper basement, between 2- and 5-kilometer depth. The modeled fluid pressure perturbation propagates throughout the same depth range and tracks earthquakes to distances of 35 kilometers, with a triggering threshold of ~0.07 megapascals. Although thousands of disposal wells operate aseismically, four of the highest-rate wells are capable of inducing 20% of 2008 to 2013 central U.S. seismicity.

Review of Advanced Materials for Proton Exchange Membrane Fuel Cells

Abstract: The scientific community is focused on the development of inexpensive and high-performing membrane materials for proton exchange membrane (PEM) fuel cells (FCs). The major approach to reducing the cost of FCs, which is crucial for the widespread acceptance of FCs as energy sources for various practical applications, is reducing the cost of the membrane. Efforts are being made in the development of advanced polymeric materials, which will satisfy the technical and economic demands of the consumers. Because most alternative membranes are outperformed by Nafion membranes over an entire set of important properties, it may be worthwhile to compromise on certain parameters to develop alternative specialized membranes. This review presents the properties (mainly conductivity and chemical and mechanical stability) of modern solid polymer electrolytes (SPEs) for PEM FCs.

Nonstructural carbon in woody plants.

Abstract: Nonstructural carbon (NSC) provides the carbon and energy for plant growth and survival. In woody plants, fundamental questions about NSC remain unresolved: Is NSC storage an active or passive process? Do older NSC reserves remain accessible to the plant? How is NSC depletion related to mortality risk? Herein we review conceptual and mathematical models of NSC dynamics, recent observations and experiments at the organismal scale, and advances in plant physiology that have provided a better understanding of the dynamics of woody plant NSC. Plants preferentially use new carbon but can access decade-old carbon when the plant is stressed or physically damaged. In addition to serving as a carbon and energy source, NSC plays important roles in phloem transport, osmoregulation, and cold tolerance, but how plants regulate these competing roles and NSC depletion remains elusive. Moving forward requires greater synthesis of models and data and integration across scales from -omics to ecology.

A review of hydrothermal biomass processing

Abstract: Hydrothermal processing is an important thermochemical conversion process that is used to convert biomass into valuable products or biofuel. The process is usually performed in water at 250–374 °C under pressures of 4–22 MPa. The biomass is degraded into small components in water. Based on the target products, i.e., bio-oil, bio-gas or bio-carbon, the process conditions (temperature, pressure and time) are chosen. There has been significant effort in evaluating various biomass resources for hydrothermal processing because the process is suitable for any type of biomass including the co-utilization of biomass with waste materials. Additionally, because most biomass resources have high moisture contents, the most efficient way to process them is through hydrothermal processing. To understand hydrothermal biomass processing and the degradation pathway of biomass, it is necessary to understand the properties of water under hydrothermal conditions (i.e., subcritical and supercritical). In this respect, the physicochemical properties of water under subcritical and supercritical conditions and the interactions of water with biomass are discussed in the present paper. This review focuses on the hydrothermal processing of biomass and identifies the characteristics of various types of hydrothermal processing products. Additionally, this review provides an overview of the available biomass, the use of biomass as an energy source and related conversion technologies.

Zeolites as catalysts in oil refining

Abstract: Oil is nowadays the main energy source and this prevalent position most probably will continue in the next decades. This situation is largely due to the degree of maturity that has been achieved in oil refining and petrochemistry as a consequence of the large effort in research and innovation. The remarkable efficiency of oil refining is largely based on the use of zeolites as catalysts. The use of zeolites as catalysts in refining and petrochemistry has been considered as one of the major accomplishments in the chemistry of the XXth century. In this tutorial review, the introductory part describes the main features of zeolites in connection with their use as solid acids. The main body of the review describes important refining processes in which zeolites are used including light naphtha isomerization, olefin alkylation, reforming, cracking and hydrocracking. The final section contains our view on future developments in the field such as the increase in the quality of the transportation fuels and the coprocessing of increasing percentage of biofuels together with oil streams. This review is intended to provide the rudiments of zeolite science applied to refining catalysis.

A Comparative Study of Energy Management Schemes for a Fuel-Cell Hybrid Emergency Power System of More-Electric Aircraft

Abstract: This paper presents a comparative analysis of different energy management schemes for a fuel-cell-based emergency power system of a more-electric aircraft. The fuel-cell hybrid system considered in this paper consists of fuel cells, lithium-ion batteries, and supercapacitors, along with associated dc/dc and dc/ac converters. The energy management schemes addressed are state of the art and are most commonly used energy management techniques in fuel-cell vehicle applications, and they include the following: the state machine control strategy, the rule-based fuzzy logic strategy, the classical proportional-integral control strategy, the frequency decoupling/fuzzy logic control strategy, and the equivalent consumption minimization strategy. The main criteria for performance comparison are the hydrogen consumption, the state of charges of the batteries/supercapacitors, and the overall system efficiency. Moreover, the stresses on each energy source, which impact their life cycle, are measured using a new approach based on the wavelet transform of their instantaneous power. A simulation model and an experimental test bench are developed to validate all analysis and performances.

Optimal Taxes on Fossil Fuel in General Equilibrium

Abstract: We analyze a dynamic stochastic general-equilibrium (DSGE) model with an externality—through climate change—from using fossil energy. Our central result is a simple formula for the marginal externality damage of emissions (or, equivalently, for the optimal carbon tax). This formula, which holds under quite plausible assumptions, reveals that the damage is proportional to current GDP, with the proportion depending only on three factors: (i) discounting, (ii) the expected damage elasticity (how many percent of the output flow is lost from an extra unit of carbon in the atmosphere), and (iii) the structure of carbon depreciation in the atmosphere. Thus, the stochastic values of future output, consumption, and the atmospheric CO2 concentration, as well as the paths of technology (whether endogenous or exogenous) and population, and so on, all disappear from the formula. We find that the optimal tax should be a bit higher than the median, or most well-known, estimates in the literature. We also formulate a parsimonious yet comprehensive and easily solved model allowing us to compute the optimal and market paths for the use of different sources of energy and the corresponding climate change. We find coal—rather than oil—to be the main threat to economic welfare, largely due to its abundance. We also find that the costs of inaction are particularly sensitive to the assumptions regarding the substitutability of different energy sources and technological progress.

Comprehensive Review of Stability Criteria for DC Power Distribution Systems

Abstract: Power-electronics-based dc power distribution systems, consisting of several interconnected feedback-controlled switching converters, suffer from potential degradation of stability and dynamic performance caused by negative incremental impedances due to the presence of constant power loads. For this reason, the stability analysis of these systems is a significant design consideration. This paper reviews all the major stability criteria for dc distribution systems that have been developed so far: the Middlebrook Criterion, the Gain Margin and Phase Margin Criterion, the Opposing Argument Criterion, the Energy Source Analysis Consortium (ESAC) Criterion, and the Three-Step Impedance Criterion. In particular, the paper discusses, for each criterion, the artificial conservativeness characteristics in the design of dc distribution systems, and the formulation of design specifications that ensure system stability. Moreover, the Passivity-Based Stability Criterion is discussed, which has been recently proposed as an alternative stability criterion. While all prior stability criteria are based on forbidden regions for the polar plot of the so-called minor loop gain, which is an impedance ratio, the proposed criterion is based on imposing passivity of the overall bus impedance. A meaningful simulation example is presented to illustrate the main characteristics of the reviewed stability criteria.

Nanochemistry-derived Bi2WO6 nanostructures: towards production of sustainable chemicals and fuels induced by visible light

Abstract: Low cost and easily made bismuth tungstate (Bi2WO6) could be one of the key technologies to make chemicals and fuels from biomass, atmospheric carbon dioxide and water at low cost using solar radiation as an energy source. Its narrow band gap (2.8 eV) enables ideal visible light (λ > 400 nm) absorption. Yet, it is the material's shape, namely the superstructure morphology wisely created via a nanochemistry approach, which leads to better electron–hole separation and much higher photoactivity. Recent results coupled to the versatile photochemistry of this readily available semiconductor suggest that the practical application of nanochemistry-derived Bi2WO6 nanostructures for the synthesis of value-added fine chemicals and fuel production is possible. We describe progress in this important field of chemical research from a nanochemistry viewpoint, and identify opportunities for further progress.

Mitochondrial trafficking and anchoring in neurons: New insight and implications

Abstract: Mitochondria are essential organelles for neuronal growth, survival, and function. Neurons use specialized mechanisms to drive mitochondria transport and to anchor them in axons and at synapses. Stationary mitochondria buffer intracellular Ca2+ and serve as a local energy source by supplying ATP. The balance between motile and stationary mitochondria responds quickly to changes in axonal and synaptic physiology. Defects in mitochondrial transport are implicated in the pathogenesis of several major neurological disorders. Recent work has provided new insight in the regulation of microtubule-based mitochondrial trafficking and anchoring, and on how mitochondrial motility influences neuron growth, synaptic function, and mitophagy.

Design of high-efficiency visible-light photocatalysts for water splitting: MoS2/AlN(GaN) heterostructures

Abstract: Hydrogen fuel produced from water splitting using solar energy and a catalyst is a clean and renewable future energy source. Great efforts in searching for photocatalysts that are highly efficient, inexpensive, and capable of harvesting sunlight have been made for the last decade, which, however, have not yet been achieved in a single material system so far. Here, we predict that MoS2/AlN(GaN) van der Waals (vdW) heterostructures are sufficiently efficient photocatalysts for water splitting under visible-light irradiation based on ab initio calculations. Contrary to other investigated photocatalysts, MoS2/AlN(GaN) vdW heterostructures can separately produce hydrogen and oxygen at the opposite surfaces, where the photoexcited electrons transfer from AlN(GaN) to MoS2 during the photocatalysis process. Meanwhile, these vdW heterostructures exhibit significantly improved photocatalytic properties under visible-light irradiation by the calculated optical absorption spectra. Our findings pave a new way to facil...

HyMeX-SOP1: The Field Campaign Dedicated to Heavy Precipitation and Flash Flooding in the Northwestern Mediterranean

Abstract: The Mediterranean region is frequently affected by heavy precipitation events associated with flash floods, landslides, and mudslides that cause hundreds of millions of euros in damages per year and often, casualties. A major field campaign was devoted to heavy precipitation and flash floods from 5 September to 6 November 2012 within the framework of the 10-year international HyMeX (Hydrological cycle in the Mediterranean Experiment) dedicated to the hydrological cycle and related high-impact events. The 2- month field campaign took place over the Northwestern Mediterranean Sea and its surrounding coastal regions in France, Italy, and Spain. The observation strategy of the field experiment was devised to improve our knowledge on the following key components leading to heavy precipitation and flash flooding in the region: i) the marine atmospheric flows that transport moist and conditionally unstable air towards the coasts; ii) the Mediterranean Sea acting as a moisture and energy source; iii) the dynamics and microphysics of the convective systems producing heavy precipitation; iv) the hydrological processes during flash floods. This article provides the rationale for developing this first HyMeX field experiment and an overview of its design and execution. Highlights of some Intense Observation Periods illustrate the potential of the unique datasets collected for process understanding, model improvement and data assimilation.

Distributed Control Systems for Small-Scale Power Networks: Using Multiagent Cooperative Control Theory

Abstract: Existing electric power distribution networks are operating near full capacity and facing rapid changes to address environmental concerns and improve their reliability and sustainability. These concerns are satisfied through the effective integration and coordination of distributed generators (DGs), which facilitate the exploitation of renewable energy resources, including wind power, photovoltaics, and fuel cells [1]. Although DGs can be of rotating machinery type, more recently, DGs have been designed to support renewable energy resources by electronic interfacing through voltage source inverters (VSI). Each DG corresponds to one energy source, and its control inputs are given to the interface VSI [1]-[5]. The successful coordination of DGs can be realized through microgrids, which are small-scale power systems consisting of local generation, local loads, and energy storage systems. Microgrids are autonomous subsystems with dedicated control systems that provide guaranteed power quality for local loads such as hospitals, economic centers, apartments, and universities. The microgrid concept, with its local control and power quality support, allows for the scalable integration of local power resources and loads into the existing power grid and enables a high penetration of distributed generation [5]-[10].

Triplet–triplet annihilation photon-upconversion: towards solar energy applications

Abstract: Solar power production and solar energy storage are important research areas for development of technologies that can facilitate a transition to a future society independent of fossil fuel based energy sources. Devices for direct conversion of solar photons suffer from poor efficiencies due to spectrum losses, which are caused by energy mismatch between the optical absorption of the devices and the broadband irradiation provided by the sun. In this context, photon-upconversion technologies are becoming increasingly interesting since they might offer an efficient way of converting low energy solar energy photons into higher energy photons, ideal for solar power production and solar energy storage. This perspective discusses recent progress in triplet-triplet annihilation (TTA) photon-upconversion systems and devices for solar energy applications. Furthermore, challenges with evaluation of the efficiency of TTA-photon-upconversion systems are discussed and a general approach for evaluation and comparison of existing systems is suggested.

Review of the application of energy harvesting in buildings

Abstract: This review presents the state of the art of the application of energy harvesting in commercial and residential buildings. Electromagnetic (optical and radio frequency), kinetic, thermal and airflow-based energy sources are identified as potential energy sources within buildings and the available energy is measured in a range of buildings. Suitable energy harvesters are discussed and the available and the potential harvested energy calculated. Calculations based on these measurements, and the technical specifications of state-of-the-art harvesters, show that typical harvested powers are: (1) indoor solar cell (active area of 9 cm2, volume of 2.88 cm3): ~300 µW from a light intensity of 1000 lx; (2) thermoelectric harvester (volume of 1.4 cm3): 6 mW from a thermal gradient of 25 °C; (3) periodic kinetic energy harvester (volume of 0.15 cm3): 2 µW from a vibration acceleration of 0.25 m s−2 at 45 Hz; (4) electromagnetic wave harvester (13 cm antenna length and conversion efficiency of 0.7): 1 µW with an RF source power of −25 dBm; and (5) airflow harvester (wind turbine blade of 6 cm diameter and generator efficiency of 0.41): 140 mW from an airflow of 8 m s−1. These results highlight the high potential of energy harvesting technology in buildings and the relative attractions of various harvester technologies. The harvested power could either be used to replace batteries or to prolong the life of rechargeable batteries for low-power (~1 mW) electronic devices.