Showing papers on "Ferrier carbocyclization published in 2003"

TL;DR: In this paper, the total synthesis of (−)-actinobolin 2, an antipode of the natural product starting from d -glucose, was described, and a three-component coupling reaction of a functionalized cyclohexenone (+)-6, derived from d-glucoses by way of Ferrier's carbocyclization, with vinyl cuprate and an aldehyde (R)-5 effectively constructed the carbon framework of 2 in a highly stereoselective manner.

TL;DR: Paulsen as discussed by the authors converted triacetyl-acetyl−d−glucal to 2,3−unsaturated methyl glycosides using ferric chloride as the catalyst.