Showing papers on "Ferrier carbocyclization published in 2006"
TL;DR: In this paper, a three-component coupling reaction of functionalized cyclohexenone (+)- 6 derived from d-glucose by way of Ferrier's carbocyclization reaction, with vinyl cuprate and 2-alkoxypropanal 7 effectively constructed the carbon framework of 3 in a highly stereoselective manner.
21 citations
TL;DR: The Ferrier reaction of O-1,3-dienyl acetals promoted by organoaluminum complexes such as methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is shown to proceed with a high degree of regio- and stereoselectivity to afford the corresponding alpha-alkenyl-substituted beta-alkoxy aldehydes in good yields.
15 citations
TL;DR: A variety of 2,3-unsaturated O-glycosides have been prepared by the Ferrier rearrangement of acetyl protected glycals under microwave irradiation using silica gel as an acid catalyst as discussed by the authors.
12 citations
TL;DR: Er(OTf) 3 is a useful catalyst for the Ferrier rearrangement furnishing 2',3'-dideoxy pyranosyl nucleosides easily by means of cleaner reaction profiles, short reaction times, mild reaction conditions, good stereoselectivity, and good recoverability of the commercially available catalyst as mentioned in this paper.
Abstract: Er(OTf) 3 is a useful catalyst for the Ferrier rearrangement furnishing 2',3'-dideoxy pyranosyl nucleosides easily by means of cleaner reaction profiles, short reaction times, mild reaction conditions, good stereoselectivity, and good recoverability of the commercially available catalyst.
1 citations