Ferrier carbocyclization

About: Ferrier carbocyclization is a research topic. Over the lifetime, 66 publications have been published within this topic receiving 947 citations.

Gold(III) Chloride and Phenylacetylene: A Catalyst System for the Ferrier Rearrangement, and O-Glycosylation of 1-O-Acetyl Sugars as Glycosyl Donors.

Abstract: A new catalyst system AuCl3/phenylacetylene is developed to promote the Ferrier rearrangement of glycals and the O-glycosylation of 1-O-acetyl sugars.

Total Synthesis of (-)-Tetrodotoxin from D-Glucose: A New Route to Multi-Functionalized Cyclitol Employing the Ferrier(II) Reaction Toward (-)-Tetrodotoxin.

Abstract: Total synthesis of (−)-tetrodotoxin (TTX) from D-glucose is described. As a critical transformation step for synthesizing TTX, a key multi-functionalized cyclitol was prepared from D-glucose employ...