Topic
Ferrier rearrangement
About: Ferrier rearrangement is a research topic. Over the lifetime, 321 publications have been published within this topic receiving 5524 citations.
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TL;DR: In this paper, a method to prepare 3-alkoxyindanones efficiently by gold-catalyzed tandem cycloisomerization/Petasis-Ferrier rearrangement from ortho-ethynylarylaldehydes with alcohols is described.
Abstract: A method to prepare 3-alkoxyindanones efficiently by gold-catalyzed tandem cycloisomerization/Petasis–Ferrier rearrangement from ortho-ethynylarylaldehydes with alcohols is described. The reaction was accomplished in moderate to excellent yields under mild reaction conditions and also offers a convenient synthetic route to 3-alkoxycyclopentenones.
20 citations
TL;DR: In this paper, a Ferrier rearrangement and β-hydroxyketone transposition are key steps in a route to a pancratistatin C-ring precursor.
19 citations
TL;DR: In this article, the synthesis of five new 2,3-unsaturated O-glycosides (3a-e) employing Ferrier's rearrangement with different catalysts, was reported.
19 citations
TL;DR: This protocol surpasses the existing methods for the synthesis of 2-C-methylene glycosides as it obviates the need for functionalizing the allylic hydroxy group of glycals.
19 citations
TL;DR: InCl3 as discussed by the authors catalyzes a facile stereoselective 1,3-migration of allylic ethers of glycals to afford 2-C-methylene- and 2-3-unsaturated-α-O-glycosides in high yields.
19 citations