Topic
Ferrier rearrangement
About: Ferrier rearrangement is a research topic. Over the lifetime, 321 publications have been published within this topic receiving 5524 citations.
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TL;DR: In this article, an improved method for the synthesis of 2,3-unsaturated-glycosides has been established by using RuCl 3 ·3H 2 O as a catalyst.
13 citations
TL;DR: In this article, the sigma-Ferrier ring expansion of carbohydrate derived vinylcyclopropanes (VCPs) under electrophilic conditions mediated by chloramine-T and a phase-transfer catalyst was investigated.
13 citations
TL;DR: The reaction of 1,2-dihydropyranyl acetates with dimethylzinc, diethylZinc and diphenylzinc in the presence of CF3COOH gave the corresponding alky and aryl C-pyranosides via a Ferrier rearrangement in excellent yields.
13 citations
TL;DR: In this article, Lichtenthaler et al. used ferric chloride as the catalyst to convert triacetylglucal (1) to the corresponding 2,3-unsaturated allyl and benzyl glycosides (2 and 3) using a catalytic catalyst.
13 citations
TL;DR: The attempted intermolecular addition of malonyl radicals to 1′,2′-unsaturated nucleosides has led to the unexpected formation of furanones as mentioned in this paper.
12 citations