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Fly ash

About: Fly ash is a(n) research topic. Over the lifetime, 47676 publication(s) have been published within this topic receiving 675644 citation(s). The topic is also known as: pulverised fuel ash.

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Abstract: Fly ash, generated during the combustion of coal for energy production, is an industrial by-product which is recognized as an environmental pollutant. Because of the environmental problems presented by the fly ash, considerable research has been undertaken on the subject worldwide. In this paper, the utilization of fly ash in construction, as a low-cost adsorbent for the removal of organic compounds, flue gas and metals, light weight aggregate, mine back fill, road sub-base, and zeolite synthesis is discussed. A considerable amount of research has been conducted using fly ash for adsorption of NOx, SOx, organic compounds, and mercury in air, dyes and other organic compounds in waters. It is found that fly ash is a promising adsorbent for the removal of various pollutants. The adsorption capacity of fly ash may be increased after chemical and physical activation. It was also found that fly ash has good potential for use in the construction industry. The conversion of fly ash into zeolites has many applications such as ion exchange, molecular sieves, and adsorbents. Converting fly ash into zeolites not only alleviates the disposal problem but also converts a waste material into a marketable commodity. Investigations also revealed that the unburned carbon component in fly ash plays an important role in its adsorption capacity. Future research in these areas is also discussed.

1,772 citations

Journal ArticleDOI
Abstract: The alkali activation of waste materials (especially those coming from industrial and mining activities) has become an important area of research in many laboratories because it is possible to use these materials to synthesize inexpensive and ecologically sound cementlike construction materials. In the present paper, the mechanism of activation of a fly ash (no other solid material was used) with highly alkaline solutions is described. These solutions, made with NaOH, KOH, water glass, etc., have the common characteristic of having a very high OH 2 concentration. The product of the reaction is an amorphous aluminosilicate gel having a structure similar to that of zeolitic precursors. Temperature and time of curing of specimens together with the solution/fly ash ratio are some of the variables that were studied. These variables have been shown to notably influence the development of the mechanical strength of the final product. Mechanical strengths with values in the 60 MPa range were obtained after curing the fly ash at 85 8 C for only 5 h. © 1999 Elsevier Science Ltd. All rights reserved.

1,493 citations

Journal ArticleDOI
Abstract: Coal fly ash, an industrial by-product, is derived from coal combustion in thermal power plants. It is one of the most complex anthropogenic materials, and its improper disposal has become an environmental concern and resulted in a waste of recoverable resources. There is a pressing and ongoing need to develop new recycling methods for coal fly ash. The present review first describes the generation, physicochemical properties and hazards of coal fly ash at the global level, and then focuses on its current and potential applications, including use in the soil amelioration, construction industry, ceramic industry, catalysis, depth separation, zeolite synthesis, etc. Finally, the advantages and disadvantages of these applications, the mode of fly ash utilization worldwide and directions for future research are considered.

849 citations

Journal ArticleDOI
Abstract: This paper presents an overview of research related to mercury control technology for coal-fired power plants and identifies areas requiring additional research and development. It critically reviews measured mercury emissions; the chemistry of mercury transformation and control; progress in the development of promising control technologies: sorbent injection, control in wet scrubbers, and coal cleaning; and projects costs for mercury control. Currently, there is no single best technology that can be broadly applied. Combinations of available control methods may be able to provide up to 90% control for some plants but not others. In August 2000, the National Research Council completed a study that determined that the U.S. Environmental Protection Agency's (EPA) conservative exposure reference dose of 0.1 μg mercury/kg body weight/day was scientifically justified to protect against harmful neurological effects during fetal development and early childhood. Subsequently, in December 2000, EPA made its regulatory decision that mercury emissions from coal-fired electric generating plants will need to be controlled on a schedule that calls for a proposed rule by December 2003, a final rule by December 2004, and full compliance by the end of 2007. Coal-fired utility boilers are currently the largest single-known source of mercury emissions in the United States. EPA's Information Collection Request (ICR) to coal-burning utilities indicated that there were 75 tons of mercury in the 900 million tons of coal used in U.S. power plants during 1999. Estimates of total mercury emissions from coal-fired plants based on ICR data range from 40 to 52 tons. On average, about 40% of the mercury entering a coal-fired power plant is captured and 60% emitted. Percentage emissions of mercury for individual plants tested under the ICR varied widely depending on coal type and emission control equipment. Western subbituminous coals on average contain only about half as much mercury as Appalachian bituminous coals, but the higher chlorine content of the latter promotes mercury oxidation and results in a higher percentage of mercury capture. Some iron minerals found in coal also catalyze mercury oxidation, whereas calcium and sulfur tend to impede oxidation. Review of ICR data on mercury capture in boilers and existing control devices indicates very little mercury removal within a pulverized coal-fired boiler, and the level of mercury oxidation at the exit of the boiler was increased for higher coal chlorine contents and lower exit temperatures. Mercury removals across cold-side electrostatic precipitators (ESPs) averaged 27%, compared to 4% for hot-side ESPs. Removals for fabric filters (FFs) were higher, averaging 58%, owing to additional gas–solid contact time for oxidation. Both wet and dry flue gas desulfurization (FGD) systems removed 80% to 90% of the gaseous mercury(II), but elemental mercury (Hg0) was not affected. High mercury removals, averaging 86%, in fluidized-bed combustors with FFs were attributed to mercury capture on high-carbon fly ash. Tests on the two coal-fired integrated gasification combined-cycle plants in the United States suggest that about half of the coal mercury was emitted predominantly in elemental form. ICR tests on selective catalytic reduction and selective noncatalytic reduction used for NOx control were inconclusive, and additional full-scale tests are in progress. The mechanisms responsible for varied levels of mercury oxidation and capture are beginning to be understood. Mercury in coal occurs in association with pyrite and other sulfide minerals and may also be organically bound. Coal mercury is converted to gaseous Hg0 in the combustion flame and is subsequently partially oxidized (35% to 95%) as the combustion gases cool. Mercury oxidation in boiler systems is kinetically controlled; homogeneous oxidation reactions are promoted by chlorine and atomic chlorine, and heterogeneous oxidation is promoted by fly ash and sorbents. Acid gases critically influence the heterogeneous oxidation of mercury, particularly as it affects capture on sorbents. HCl, NO, and NO2 all promote oxidation and capture both individually and in combination. However, the combination of SO2 with NO2 greatly reduces capture of Hg0 on activated carbon, whereas oxidation continues on the solid surface. Mass transfer of gaseous mercury by diffusion from the bulk gas to the solid surface can also limit heterogeneous oxidation and capture of mercury, but diffusion within a porous sorbent is not believed to be rate-limiting. Reducing the size of the sorbent particles and increasing their dispersion can greatly enhance control where mass transfer is limiting. To achieve 90% control of a mercury concentration of 10 μg/scm in 2-s residence time by activated carbon injection requires a minimum carbon-to-mercury (C/Hg) mass ratio of about 3000:1 for 4-μm particles compared to 18,000:1 for 10-μm particles. Mercury removals in some tests performed to characterize sorbents have been mass transfer-limited by the large particle size of the sorbents used. Mercury sorption capacities between about 200 and 5000 μg Hg/g C have been reported for conditions applying to coal combustion. However, higher measured capacities do not always correlate with higher removal levels in practice because of the effect of other variables. What is important is that several of the activated carbons tested have sufficient capacity to capture mercury at carbon injection rates below a C/Hg mass ratio of 10,000, based on both laboratory and field sorption tests. Since capacity is defined in reference to an assumed sorption equilibrium, the equilibrium capacity of a sorbent determined over a period of hours in the laboratory may have limited relevance to the amount of mercury captured in a few seconds' time of flight or in minutes of contact time on an FF. Laboratory tests that are more representative of the conditions in an actual control device are needed to determine more useful capacity factors. Injection of activated carbon upstream of either an ESP or an FF baghouse is a retrofit control technology that has potential application to 75% of all coal-fired power plants in the United States that are not equipped with FGD scrubbers. Field and pilot-scale tests on activated carbon injection for mercury control have resulted in mercury removals between about 25% and 95% over the range of 2000–15,000 C/Hg mass ratio. The mercury removal data from some tests could be correlated with carbon injection rates by assuming that the removal was mass transfer-limited, whereas in tests on other coals, removals appeared to be controlled by catalytic oxidation and capture on fly ash. Mercury capture on sorbents, therefore, depends on the properties of the coal being burned, and pilot-scale tests on particular coals should be performed before a full-scale sorbent injection system is designed. Development of low-cost, ultrafine sorbents with high effective sorption capacities and rapid reaction kinetics would revolutionize injection technology. Engineering development is also needed to improve sorbent dispersion and to optimize gas–solid contact time. Wet FGD units currently installed on about 25% of the U.S. coal-fired utility boilers remove nearly 90% of the mercury(II) entering but essentially none of the Hg0. Research to enhance mercury removal in scrubbers focuses on converting Hg0 to an oxidized form in or ahead of the scrubber using proprietary reagents. Palladium and carbon-based catalysts have shown the most promise for oxidizing Hg0. Mercury removals from near 0% to about 60% are reported for the physical washing methods of the type that are widely used to remove pyritic sulfur and ash from 77% of all bituminous coal used in the United States. Advanced cleaning methods and hydrothermal treatment offer higher removals, but no coal-cleaning method is likely to reliably meet a 70% or greater removal requirement. Coal cleaning could, however, contribute to overall mercury control under a cap-and-trade form of mercury regulation. Concerns over the release of mercury from coal combustion by-products by leaching or atmospheric reemission will be heightened with the installation of mercury control technologies. Concentrations of mercury in leachates from fly ashes, FGD materials, and activated carbon saturated with mercury are very low and usually below detection limits. Essentially, no mercury emission from these materials into air has been measured at ambient temperature. However, mercury is released from saturated sorbents upon heating above 135 °C. Preliminary results on the stability of mercury on fly ash, FGD materials, and saturated carbons are encouraging, but more testing is needed before the concerns are fully resolved.

828 citations

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