Fourier transform infrared spectroscopy

About: Fourier transform infrared spectroscopy is a research topic. Over the lifetime, 48250 publications have been published within this topic receiving 1134369 citations.

Preparation and characterization of NiO nanoparticles by anodic arc plasma method

Abstract: NiO nanoparticles with average particle size of 25 nm were successfully prepared by anodic arc plasma method. The composition, morphology, crystal microstructure, specific surface area, infrared spectra, and particle size distribution of product were analyzed by using X-ray diffraction (XRD), transmission electron microscopy (TEM) and the corresponding selected area electron diffraction (SAED), Fourier transform infrared (FTIR) spectrum, and Brunauer-Emmett-Teller (BET) N2 adsorption. The experiment results show that the NiO nanoparticles are bcc structure with spherical shape and well dispersed, the particle size distribution ranging from 15 to 45nm with the average particle size is about 25 nm, and the specific surface area is 33m2/g. The infrared absorption band of NiO nanoparticles shows blue shifts compared with that of bulk NiO.

Carboxymethyl Cellulose/Silver Nanoparticles Composite: Synthesis, Characterization and Application as a Benign Corrosion Inhibitor for St37 Steel in 15% H2SO4 Medium.

Abstract: This study has been designed to boost the inhibition efficiency and stability of carboxymethyl cellulose (CMC) and this objective has been achieved by incorporating silver nanoparticles (AgNPs) generated in situ by reduction of AgNO3 using natural honey into CMC matrix. Characterization of CMC/AgNPs composite was done using transmission electron microscope (TEM), Fourier transform infrared (FTIR) spectroscopy, ultraviolet–visible spectroscopy (UV–vis), scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS). Weight loss, electrochemical (dynamic electrochemical impedance spectroscopy, electrochemical impedance spectroscopy, and potentiodynamic polarization) supported by surface assessment (SEM, atomic force microscope, and FTIR) techniques are deployed for the anticorrosion studies of CMC/AgNPs on St37 specimen in 15% H2SO4 medium. CMC/AgNPs performs better than CMC. At 25 °C, optimum inhibition efficiency of 93.94% is afforded by 1000 ppm of CMC/AgNPs from DEIS method. Inhibiti...

Surface modification of Fe3O4@SiO2 microsphere by silane coupling agent

Abstract: In the present study, Fe3O4@SiO2 core–shell microspheres were prepared via two steps. First, Fe3O4 nanoparticles were synthesized by co-precipitation of Fe+3 and Fe+2 as reaction substrates and NaOH as precipitant. Second, the surface of Fe3O4 was coated with silica by hydrolysis of tetraethylorthosilicate as the silica source. Subsequently, in order to reduce the amount of interaction and the agglomeration of Fe3O4@SiO2 microspheres, the silica shell of these particles was modified by vinyltriethoxysilane as the silane coupling agent. The structural properties of the samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared spectroscopy analyses. The results indicated that the average sizes of Fe3O4 and Fe3O4@SiO2 particles were about 50 and 500 nm, respectively. Also, the surface characterization of Fe3O4@SiO2 microspheres showed that the silane coupling agent was covalently coupled with the silica surface.

Thin Molecularly Imprinted Polymer Films via Reversible Addition−Fragmentation Chain Transfer Polymerization

Abstract: Mesoporous silica beads modified with an azo initiator were used for grafting of cross-linked molecularly imprinted polymers through reversible addition−fragmentation chain transfer (RAFT) mediated polymerization. The RAFT mediation allowed an efficient control of the grafting process and led to suppression of the solution propagation preventing any visible gel formation. Thus, graft copolymerization of methacrylic acid and ethylene glycol dimethacrylate using 2-phenylprop-2-yl-dithiobenzoate as the chain transfer agent and in the presence of l-phenylalanine anilide as the template led to imprinted thin film composite beads. The resulting composites were characterized by Fourier transform infrared spectroscopy, nitrogen sorption analysis, elemental analysis, fluorescence microscopy, and scanning electron microscopy and as stationary phases in chromatography. This indicated the presence of thin homogeneous films (thickness: 1−2 nm) containing imprinted sites for the template (l-phenylalanine anilide). The...