Fourier transform spectroscopy

About: Fourier transform spectroscopy is a research topic. Over the lifetime, 5418 publications have been published within this topic receiving 134133 citations.

Fourier transform ion cyclotron resonance mass spectrometry

Abstract: As for Fourier transform infrared (FT-IR) interferometry and nuclear magnetic resonance (NMR) spectroscopy, the introduction of pulsed Fourier transform techniques revolutionized ion cyclotron resonance mass spectrometry: increased speed (factor of 10,000), increased sensitivity (factor of 100), increased mass resolution (factor of 10,000—an improvement not shared by the introduction of FT techniques to IR or NMR spectroscopy), increased mass range (factor of 500), and automated operation. FT-ICR mass spectrometry is the most versatile technique for unscrambling and quantifying ion-molecule reaction kinetics and equilibria in the absence of solvent (i.e., the gas phase). In addition, FT-ICR MS has the following analytically important features: speed (∼1 second per spectrum); ultrahigh mass resolution and ultrahigh mass accuracy for analysis of mixtures and polymers; attomole sensitivity; MS n with one spectrometer, including two-dimensional FT/FT-ICR/MS; positive and/or negative ions; multiple ion sources (especially MALDI and electrospray); biomolecular molecular weight and sequencing; LC/MS; and single-molecule detection up to 10 8 Dalton. Here, some basic features and recent developments of FT-ICR mass spectrometry are reviewed, with applications ranging from crude oil to molecular biology.

Fourier transform spectroscopy with a laser frequency comb

Abstract: Molecular fingerprinting using absorption spectroscopy is a powerful analytical method, particularly in the infrared, the region of intense spectral signatures Fourier transform spectroscopy—the widely used and essential tool for broadband spectroscopy—enables the recording of multi-octave-spanning spectra, exhibiting 100 MHz resolution with an accuracy of 1 × 10−9 and 1 × 10−2 in wavenumber and intensity determination, respectively Typically, 1 × 106 independent spectral elements may be measured simultaneously within a few hours, with only average sensitivity Here, we show that by using laser frequency combs as the light source of Fourier transform spectroscopy it is possible to record well-resolved broadband absorption and dispersion spectra in a single experiment, from the beating signatures of neighbouring comb lines in the interferogram The sensitivity is thus expected to increase by several orders of magnitude Experimental proof of principle is here carried out on the 15-µm overtone bands of acetylene, spanning 80 nm with a resolution of 15 GHz Consequently, without any optical modification, the performance of Fourier spectrometers may be drastically boosted By using an optical frequency comb as the light source for Fourier transform spectroscopy, scientists show that well-resolved broadband absorption and dispersion spectra can be recorded in a single experiment, providing sensitive detection of multiple molecular species over a broad spectral window

Two-dimensional Fourier transform electronic spectroscopy

Abstract: Two-dimensional Fourier transform electronic spectra of the cyanine dye IR144 in methanol are used to explore new aspects of optical 2D spectroscopy on a femtosecond timescale. The experiments reported here are pulse sequence and coherence pathway analogs of the two-dimensional magnetic resonance techniques known as COSY (correlated spectroscopy) and NOESY (nuclear Overhauser effect spectroscopy). Noncollinear three pulse scattering allows selection of electronic coherence pathways by choice of phase matching geometry, temporal pulse order, and Fourier transform variables. Signal fields and delays between excitation pulses are measured by spectral interferometry. Separate real (absorptive) and imaginary (dispersive) 2D spectra are generated by measuring the signal field at the sample exit, performing a 2D scan that equally weights rephasing and nonrephasing coherence pathways, and phasing the 2D spectra against spectrally resolved pump–probe signals. A 3D signal propagation function is used to correct the...

Gas phase infrared spectroscopy of selectively prepared ions.

Abstract: The first example of direct structural characterization of polyaromatic ions by coupling a Fourier transform ion cyclotron resonance mass spectrometer with an infrared free-electron laser is presented. Measurement of the IR spectra of selectively prepared ionic reactive intermediates is allowed by the association of the high peak power and wide tunability of the laser with the flexibility of the spectrometer, where several mass selection and ion reaction steps can be combined, as demonstrated in the case of iron cation complexes of hydrocarbons. The present experimental setup opens the way to understanding chemical reaction paths.