Topic
Geopolymer
About: Geopolymer is a research topic. Over the lifetime, 6776 publications have been published within this topic receiving 157991 citations. The topic is also known as: geopolymers.
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TL;DR: In this paper, ground fly ash (GFA), with a median particle size of 10.5μm, was used as source material for making geopolymers cured at room temperature, and compressive strength tests and microstructure observations using SEM, EDX, XRD and FTIR were performed.
755 citations
TL;DR: The microstructural evolution of alkali-activated binders based on blast furnace slag, fly ash and their blends during the first six months of sealed curing is assessed in this article.
Abstract: The microstructural evolution of alkali-activated binders based on blast furnace slag, fly ash and their blends during the first six months of sealed curing is assessed. The nature of the main binding gels in these blends shows distinct characteristics with respect to binder composition. It is evident that the incorporation of fly ash as an additional source of alumina and silica, but not calcium, in activated slag binders affects the mechanism and rate of formation of the main binding gels. The rate of formation of the main binding gel phases depends strongly on fly ash content. Pastes based solely on silicate-activated slag show a structure dominated by a C–A–S–H type gel, while silicate-activated fly ash are dominated by N–A–S–H ‘geopolymer’ gel. Blended slag-fly ash binders can demonstrate the formation of co-existing C–A–S–H and geopolymer gels, which are clearly distinguishable at earlier age when the binder contains no more than 75 wt.% fly ash. The separation in chemistry between different regions of the gel becomes less distinct at longer age. With a slower overall reaction rate, a 1:1 slag:fly ash system shares more microstructural features with a slag-based binder than a fly ash-based binder, indicating the strong influence of calcium on the gel chemistry, particularly with regard to the bound water environments within the gel. However, in systems with similar or lower slag content, a hybrid type gel described as N–(C)–A–S–H is also identified, as part of the Ca released by slag dissolution is incorporated into the N–A–S–H type gel resulting from fly ash activation. Fly ash-based binders exhibit a slower reaction compared to activated-slag pastes, but extended times of curing promote the formation of more cross-linked binding products and a denser microstructure. This mechanism is slower for samples with lower slag content, emphasizing the correct selection of binder proportions in promoting a well-densified, durable solid microstructure.
736 citations
01 Jan 2005
TL;DR: The first part of the work carried out by the geopolymer research group at Curtin University of Technology as discussed by the authors describes the development and properties of heat-cured low-calcium fly ash-based concrete.
Abstract: This Research Report describes the first part of the work carried out by the geopolymer research group at Curtin University of Technology. It describes the development and properties of heat-cured low-calcium fly ash-based geopolymer concrete. This Report will be followed by two other Reports describing the long-term properties of geopolymer concrete, and the behaviour of reinforced geopolymer concrete beams and columns.
723 citations
TL;DR: In this paper, the use of granulated blast furnace slag as an active filler in the making of geopolymers was described, and a 10 mm thick geopolymer panel was exposed to a 1100 °C flame, with the measured reverse-side temperatures reaching less than 350 °C after 35 min.
719 citations
TL;DR: In this article, the basic properties viz., workability and strength of geopolymer mortar made from coarse lignite high calcium fly ash were investigated, and the results revealed that the workable flow of the geopolymers was in the range of 110 −±5% −135 −± 5% and was dependent on the ratio by mass of sodium silicate to NaOH and the concentration of NaOH.
Abstract: In this paper, the basic properties viz., workability and strength of geopolymer mortar made from coarse lignite high calcium fly ash were investigated. The geopolymer was activated with sodium hydroxide (NaOH), sodium silicate and heat. The results revealed that the workable flow of geopolymer mortar was in the range of 110 ± 5%–135 ± 5% and was dependent on the ratio by mass of sodium silicate to NaOH and the concentration of NaOH. The obtained compressive strength was in the range of 10–65 MPa. The optimum sodium silicate to NaOH ratio to produce high strength geopolymer was 0.67–1.0. The concentration variation of NaOH between 10 M and 20 M was found to have a small effect on the strength. The geopolymer samples with high strength were obtained with the following practices: the delay time after moulding and before subjecting the sample to heat was 1 h and the optimum curing temperature in the oven was 75 °C with the curing duration of not less than two days.
706 citations