Showing papers on "Gibbs–Duhem equation published in 1987"
TL;DR: In this paper, the problem is reduced to shift spaces and solved there by constructing suitable conjugating homeomorphisms in order to verify the conditions for Gibbs states which Bowen gave for shift spaces, where the equivalence to equilibrium states is known.
Abstract: Ruelle and Capocaccia gave a new definition of Gibbs states on Smale spaces. Equilibrium states of suitable functions thereon are known to be Gibbs states. The converse is discussed in this paper, where the problem is reduced to shift spaces and solved there by constructing suitable conjugating homeomorphisms in order to verify the conditions for Gibbs states which Bowen gave for shift spaces, where the equivalence to equilibrium states is known.
10 citations
7 citations
TL;DR: In this paper, a new approach to chemical equilibrium is proposed to narrow the gap between introductory teaching and texts that deal with irreversible processes, in order to bridge the gap of introductory and non-introductory teaching.
Abstract: Proposal of a new approach to chemical equilibrium in order to narrow the gap between introductory teaching and texts that deal with irreversible processes.
3 citations
TL;DR: The relationship between the Gibbs energy change and the equilibrium constant for a chemical reaction, Δ G 0 = − RT In K, seemingly has either extensive dimensions or intensive dimensions.
2 citations