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Gibbs–Duhem equation
About: Gibbs–Duhem equation is a research topic. Over the lifetime, 393 publications have been published within this topic receiving 6248 citations. The topic is also known as: Gibbs-Duhem equation.
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TL;DR: In this paper, an approximate distribution of the number of ways arranging molecules in a binary lattice solution of nonrandom mixing with a specific interaction was derived from the distribution of excess Gibbs energy.
Abstract: Performing random number simulations, we obtained an approximate distribution of the number of ways arranging molecules in a binary lattice solution of nonrandom mixing with a specific interaction. From the distribution an approximate equation of excess Gibbs energy for a binary lattice solution was derived. Using the equation, liquid-vapor equilibrium at constant pressure for 15 binary solutions were calculated and compared with the result from Wilson equation, Van Laar equation and Redlich-Kister equation.
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TL;DR: For infinite classical systems under a generalised free evolution, it was shown in this article that the Gibbs measure follows in a natural way from invariance and stability for states which are flowless and clustering in the mean.
Abstract: It is shown for infinite classical systems under a generalised free evolution, that the Gibbs measure follows in a natural way from invariance and stability for states which are flowless and clustering in the mean.
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