Topic
Gibbs–Duhem equation
About: Gibbs–Duhem equation is a research topic. Over the lifetime, 393 publications have been published within this topic receiving 6248 citations. The topic is also known as: Gibbs-Duhem equation.
Papers published on a yearly basis
Papers
More filters
TL;DR: The large deviation principle characterising the exponential decay rate of macroscopic fluctuations of spatial densities generated by local observables from Gibbs lattice systems with absolutely summable interactions was established in this paper.
1 citations
1 citations
TL;DR: It is proved that, in the general case, the Gibbs distribution may not provide an entropy maximum.
Abstract: It is proved that, in the general case, the Gibbs distribution may not provide an entropy maximum.
1 citations
TL;DR: In this paper, the authors studied the mass action law for a competitive reaction in non-stoichiometric conditions and in the presence of a solvent, and discussed the nature of the coupling.
Abstract: In this paper, the authors study the mass action law for a competitive reaction in nonstoichiometric conditions and in the presence of a solvent. They go on to discuss the nature of the coupling be...
1 citations
01 Nov 1979
TL;DR: In this paper, two approximate representations of a one-particle Gibbs state, both of which become asymptotically exact in trace norm as m → ∞, were obtained.
Abstract: We obtain two approximate representations of a one-particle Gibbs state, both of which become asymptotically exact in trace norm as m → ∞. The second representation is an integral of pure coherent states over phase space, and can therefore be regarded as a classical approximation to the Gibbs state. We also obtain a version of the second representation applicable to the microcanonical ensemble.
1 citations