Topic
Glucal
About: Glucal is a research topic. Over the lifetime, 590 publications have been published within this topic receiving 8960 citations. The topic is also known as: D-glucal.
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21 citations
TL;DR: Rhodium catalyst mediated hydroformylation of glucal derivatives has been achieved for the first time in good yields and selectivies using [Rh2{µ-S(CH2)3NMe2}2(cycloocta-1,5-diene)2] and tris(ortho-tert-butylphenyl) phosphite as auxiliary ligand giving, principally, 2-formyl derivatives as discussed by the authors.
Abstract: Rhodium catalyst mediated hydroformylation of glucal derivatives has been achieved for the first time in good yields and selectivies using [Rh2{µ-S(CH2)3NMe2}2(cycloocta-1,5-diene)2] and tris(ortho-tert-butylphenyl) phosphite as auxiliary ligand giving, principally, 2-formyl derivatives.
21 citations
21 citations
TL;DR: An efficient method for the conversion of 2,4,6-tri-O -acetyl-d -glucal to 2,3-unsaturated glycosides by using triflic acid on SiO 2 as catalyst has been established.
21 citations
TL;DR: Er(OTf) 3 in 2-MeTHF provides a new and eco-friendly process for Ferrier glycosylation of sulfonamides and amino acids with various N -nucleophiles.
21 citations