Topic
Glucal
About: Glucal is a research topic. Over the lifetime, 590 publications have been published within this topic receiving 8960 citations. The topic is also known as: D-glucal.
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TL;DR: The ratio of 2 to 3 depends largely on the polarity of the solvent rather than on the size of the substituents on the hydroxyl groups of glucal as mentioned in this paper.
11 citations
TL;DR: In this article, Lewis acid mediated reactions of vinyl ethers with ArSCl adducts of benzyl protected D-glucal followed by quenching of the five-membered sulfonium salt intermediates with external nucleophiles, H2O, MeOH, and n-Bu4NBH4, lead to a highly stereoselective formation of β-Cglucopyranosides with different functional groups in the lateral chain.
11 citations
TL;DR: In this paper, the relationship between unsaturated nucleosides is studied and an allylic carbonium ion is proposed as an intermediate for these isomerizations, and the conformation and anomeric configuration of the N -glycosyl compounds obtained were assigned by NMR spectroscopy.
11 citations
TL;DR: In this paper, an eight-step sequence that features a stereoselective methyl Grignard addition to an iodo-hexenulose was used to convert glucal to epoxy allylic alcohol 4.
11 citations
TL;DR: In this paper, the C8-C20 and C1-C7 coupling partners were synthesized from TBS protected 3,4,6-tri-O -acetyl-d -glucal in eight steps.
11 citations