Topic
Glucal
About: Glucal is a research topic. Over the lifetime, 590 publications have been published within this topic receiving 8960 citations. The topic is also known as: D-glucal.
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TL;DR: Hydrolysis of the glycal with hydrochloric acid led to 4-(5-hydroxymethylfuran-2-yl)imidazole, which contains both hydrophilic and hydrophobic aromatic heterocycles.
Abstract: Reaction of ribofuranosyl chlorides with 2 eq of 5-lithio-imidazole afforded 1-(5-imidazolyl)ribofuranoid glycals in good yields. Hydrolysis of the glycal (3) with hydrochloric acid led to 4-(5-hydroxymethylfuran-2-yl)imidazole (7), which contains both hydrophilic and hydrophobic aromatic heterocycles.
8 citations
TL;DR: A library of glucal-derived triazoles have been synthesized using the copper-catalyzed azide-alkyne cyclization reaction starting from 3,4,6-tri-O-acetyl-d-glucal.
8 citations
TL;DR: The enzyme was found to be an effective catalyst to synthesize the beta-(1-->4) linkage of 2-deoxy-d-arabino-hexopyranoside.
8 citations
8 citations
TL;DR: In this article, tri-O-acetyl-d-glucal 1 with various alcohols and phenols in the presence of InCl3/CH2Cl2 at ambient temperature gave the corresponding alkyl and aryl 2,3-unsaturated glycopyranosides in excellent yields with short reaction times and good anomeric selectivity.
Abstract: Treatment of tri-O-acetyl- d -glucal 1 with various alcohols and phenols in the presence of InCl3/CH2Cl2 at ambient temperature gave the corresponding alkyl and aryl 2,3-unsaturated glycopyranosides in excellent yields with short reaction times and good anomeric selectivity.
8 citations