Topic
Glucal
About: Glucal is a research topic. Over the lifetime, 590 publications have been published within this topic receiving 8960 citations. The topic is also known as: D-glucal.
Papers published on a yearly basis
Papers
More filters
TL;DR: A highly efficient stereoselective synthesis of sugar fused 1,2-annulated isochromans is reported by utilizing the oxa-Pictet-Spengler cyclization reaction.
Abstract: A highly efficient stereoselective synthesis of sugar fused 1,2-annulated isochromans is reported by utilizing the oxa-Pictet–Spengler cyclization reaction The process is found to be very general as both glucal and galactal derived C2-hydroxy-α-C-aryl glycosides lead to the target molecules in good yields The utility of this strategy was extended to the synthesis of sugar fused isochromanones, which are bergenin type molecules
4 citations
17 Feb 2005
TL;DR: In this article, a new class of 1,5- benzodiazepines in good yields was proposed in the presence of 2 mol% of InCl3 under mild conditions.
Abstract: o-Phenylenediamines (OPDA) undergo smooth condensation with 4,6-di-O-benzyl- or 4,6-di-O- acetyl- or 4,6-di-O-ethyl-2,3-dideoxy-aldehydo-D-erythro-trans-hex-2-enose derived from D- glucal in the presence of 2 mol% of InCl3 under mild conditions to afford a new class of 1,5- benzodiazepines in good yields.
4 citations
TL;DR: The reaction of glucal (I) with alcohols affords 2,3-unsaturated glucopyranosides in high yield and α-selectivity as discussed by the authors, which is the same as the reaction of the reaction in this paper.
Abstract: The reaction of glucal (I) with alcohols affords 2,3-unsaturated glucopyranosides in high yield and α-selectivity.
4 citations
TL;DR: Under the same conditions, the use of 2-methylthiophene, furan, 2-methylfuran, or N-methylpyrrole yields (2S,3R,4R,5S)-1,3,4-tribenzyloxy-6,6-diheteroaryl-5-(p-tolylthio)-2-hexanoles.
4 citations
TL;DR: The high similarity in large-scale solid state structures between 1 and glucosamide bolaamphiphile 4 suggest a strong dependence on head group stereochemistry, and that only a few, key intermolecular interactions between head groups are necessary in controlling the ultimate structure observed.
4 citations