Topic
Glycal
About: Glycal is a research topic. Over the lifetime, 897 publications have been published within this topic receiving 17422 citations.
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Papers
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TL;DR: La synthese du squelette pyranno [2,3b] pyranne de la brevetoxine B est effectuee; le compose obtenu comporte un phosphonium quaternaire as discussed by the authors.
Abstract: La synthese du squelette pyranno [2,3-b] pyranne de la brevetoxine B est effectuee; le compose obtenu comporte un phosphonium quaternaire
77 citations
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76 citations
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75 citations
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TL;DR: The C-glycosyl compounds produced by mono-Claisen rearrangement were suitable for Pd(0)-catalyzed allylic alkylations, providing an unusually facile entry into the pseudomonic acid-ring systems.
75 citations
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TL;DR: With an excess of diphenyl sulfoxide, glycal formation can be completely suppressed and excellent yields are obtained for coupling to a wide range of primary, secondary, and tertiary acceptors.
74 citations