Topic
Glycal
About: Glycal is a research topic. Over the lifetime, 897 publications have been published within this topic receiving 17422 citations.
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TL;DR: Synthese d'anhydro-1,5 desoxy-2 di-O-acetyl-3,4 O-tosyl-6 (ou Sacetyl -6) hexene-1 itol (ou thio-6 hexene 1 itol) a partir de D-glucose and de chlorure d'acide p-toluenesulfonique (ou de thioacetate de potassium) as discussed by the authors.
10 citations
TL;DR: Some amino, acetylated, and isopropylidene derivatives of leucrose have been prepared and characterised.
10 citations
TL;DR: Iodosulfonamidation of peracetylated glycals was investigated using either a combination of N-iodosuccinimide/iodine or iodine chloride as a source of iodonium ion, and both series of isomers were successfully converted to 1,2-di-nitrogenated compounds.
10 citations
TL;DR: In this paper, auranoid glycal was utilized as a starting material for the nucleoside derivatives with the aid of benzenesulfenyl chloride and showed high stereoselectivity.
Abstract: Furanoid glycal was utilized as a starting material for the nucleoside derivatives with the aid of benzenesulfenyl chloride. Condensation reaction with silylated nucleic bases was high in the presence of SnCl 4 . Electrophilic addition of benzenesulfenyl chloride to the glycal with substituent also proceeded in high stereoselectivity. Phenylthio-substituted nucleoside was used to convert 2',3'-dideoxynucleoside and 2',3'-didehydro-2',3'-dideoxynucleoside
10 citations
TL;DR: In this article, enantiomerically pure furanoid glycals (5a,d) and highly functionalized 2,5-dihydrofurans (6a,b) were synthesized from their respective 2,3,4-trisubstituted tetrahydro-furans.
10 citations