Showing papers on "Heck reaction published in 1974"
TL;DR: In the presence of lithium chloropalladite, 2-vinylpyridine reacted with phenylmercuric chloride to give di-μ-chloro-bis[2-phenyl-2-(α-pyridyl)ethyl]dipalladium (II) as discussed by the authors.
Abstract: In the presence of lithium chloropalladite, 2-vinylpyridine reacted with phenylmercuric chloride to give di-μ-chloro-bis[2-phenyl-2-(α-pyridyl)ethyl]dipalladium (II). Similar complexes were obtained from p-toy-, p-anisyl-, or m-nitrophenylmercuric chloride. The σ-bonded structures of these complexes have been confirmed by a study of their absorption and of the NMR spectra.
11 citations
TL;DR: In the presence of lithium chloropalladite, 2-vinylpyridine reacted with phenylmercuric chloride to give di-μ-chloro-bis[2-phenyl-2-(α-pyridyl)ethyl]dipalladium (II).
Abstract: In the presence of lithium chloropalladite, 2-vinylpyridine reacted with phenylmercuric chloride to give di-μ-chloro-bis[2-phenyl-2-(α-pyridyl)ethyl]dipalladium (II). Similar complexes were obtained from p-toy-, p-anisyl-, or m-nitrophenylmercuric chloride. The σ-bonded structures of these complexes have been confirmed by a study of their absorption and of the NMR spectra.