Topic
Hydrogen peroxide
About: Hydrogen peroxide is a research topic. Over the lifetime, 42583 publications have been published within this topic receiving 1043732 citations. The topic is also known as: H2O2 & dioxidane.
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TL;DR: The poor decontamination achieved in anodic oxidation and electro-Fenton with Pt is explained by the slow removal of most pollutants by ()OH formed from water oxidation at the Pt anode in comparison to their quick destruction with ()OH produced at BDD.
245 citations
TL;DR: Gold nanoparticle loading has led to a drastic enhancement of TiO(2)-photocatalized generation of H(2)O( 2) from O(2), with a unique inversed volcano-type relation between the activity and Au particle size.
Abstract: Gold nanoparticle loading has led to a drastic enhancement of TiO2-photocatalized generation of H2O2 from O2 with a unique inversed volcano-type relation between the activity and Au particle size.
245 citations
TL;DR: Results are not consistent with a specific mechanism for cytochrome P-450-dependent ethanol oxidation but indicate that hydroxyl radicals, formed in an iron-catalyzed Haber-Weiss reaction and in a Fenton reaction, constitute the active oxygen species.
245 citations
TL;DR: A new chiral Fe(salan) complex was synthesized, and it was found to serve as an efficient catalyst for asymmetric oxidation of sulfides using hydrogen peroxide in water without surfactant.
Abstract: A new chiral Fe(salan) complex was synthesized, and it was found to serve as an efficient catalyst for asymmetric oxidation of sulfides using hydrogen peroxide in water without surfactant. Not only alkyl aryl sulfides but also various methyl alkyl sulfides were oxidized to the corresponding sulfoxides with high enantioselectivities up to 96% ee. It should be noted that the turnover number of complex 4 amounts to 8000.
244 citations
TL;DR: All proteins tested nonspecifically inhibited copper-dependent damage but have little effect on the iron-dependent reaction, as fluorescent changes in amino acid residues.
244 citations