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Hydrogen peroxide

About: Hydrogen peroxide is a research topic. Over the lifetime, 42583 publications have been published within this topic receiving 1043732 citations. The topic is also known as: H2O2 & dioxidane.


Papers
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Journal ArticleDOI
TL;DR: Differences in oxidative ability of the activated persulfate were related to different radicals generated during activation, and greater removal of high molecular weight PAHs was measured with Persulfate activation.

312 citations

Journal ArticleDOI
TL;DR: Acetic acid was found to be superior to formic acid for the in situ cottonseed oil epoxidation and was possible to obtain up to 78% relative conversion to oxirane with very lessOxirane cleavage by in situ technique.

311 citations

Journal ArticleDOI
TL;DR: A peroxidase-based bioelectrochemical sensor of hydrogen peroxide and a Clark-type oxygen electrode were applied to continuous monitoring and kinetic analysis of the autoxidation of catechins and it was found that dioxygen is quantitatively reduced to H(2)O(2).

311 citations

Journal ArticleDOI
TL;DR: Recent progress in the direct synthesis of hydrogen peroxide using supported palladium and gold-palladium alloy catalysts is described and some of the problems that have to be overcome are considered.
Abstract: Today hydrogen peroxide is produced by an indirect process in which an alkyl anthraquinone is sequentially hydrogenated and oxidized. In this way hydrogen and oxygen are kept separate during the manufacturing process. A process where molecular oxygen is directly hydrogenated could be preferred if control of the sequential hydrogenation can be achieved, particularly if high rates can be attained under intrinsically safe, non-explosive conditions. Herein we describe recent progress in the direct synthesis of hydrogen peroxide using supported palladium and gold-palladium alloy catalysts and consider some of the problems that have to be overcome.

310 citations

Journal ArticleDOI
TL;DR: The a-oxyacetylation of ketones catalyzed by the in situ generated iodine(III) in the presence of an excess amount of BF3·Et2O in wet acetic acid is developed.
Abstract: The introduction of an O-acyl group at the α-position of carbonyl compounds is smoothly achieved using tetrabutylammonium iodide catalyst in the presence of hydrogen peroxide or tert-butyl hydroperoxide.

310 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
20242
20231,644
20223,392
2021897
20201,112
20191,301