Incompatible element

About: Incompatible element is a research topic. Over the lifetime, 2420 publications have been published within this topic receiving 154052 citations.

Time-evolution of magma sources in a continental back-arc setting: the Cenozoic basalts from Sierra de San Bernardo (Patagonia, Chubut, Argentina)

Abstract: East of the Patagonian Andes, mafic volcanic rocks (mainly lava flows and scoriae) are exposed in the Sierra de San Bernardo fold belt and neighbouring areas (central Patagonia; 44.5–46° S, 69–71° W). They were erupted over a wide interval of time (late Eocene–Pleistocene; 14 new K–Ar ages), and show systematic chemical and Sr–Nd–Pb isotopic variations in time. The alkaline lavas (Mg number 57–66) erupted during the late Eocene and early Miocene, have an intraplate geochemical affinity, and have the highest 143Nd/144Nd and 206Pb/204Pb and the lowest 87Sr/86Sr ratios of the dataset. Their compositions indicate that their depth of equilibration in the mantle was greater than that of subsequent lavas. In contrast, the Plio-Pleistocene alkaline lavas (Mg number 58–71) are the most enriched in incompatible elements, still showing an intra-plate signature, and have the lowest 143Nd/144Nd and 206Pb/204Pb and the highest 87Sr/86Sr ratios. A distinctive group of early Miocene subalkaline lavas is characterized by slightly more evolved compositions (Mg number 56–59), coupled with very low incompatible element contents, flat LREE and fractionated HREE patterns (‘kinked’ pattern), and intermediate Sr–Nd–Pb isotope compositions. The Pleistocene basanites (Mg number 71–72) from the Cerro Ante monogenetic cone, on the easternmost slopes of the Patagonian Andes, have a marked orogenic geochemical signature and Sr–Nd–Pb isotope ratios that overlap with those of volcanic rocks from the adjacent active Andean arc. They originated in a mantle source extensively modified by the addition of materials from the subducting Pacific oceanic plates. We suggest that the wide chemical and isotopic variability of the Sierra de San Bernardo lavas reflects the upwelling of asthenospheric mantle beneath the study area, which induced lithospheric erosion and progressive involvement of enriched mantle domains in the genesis of magmas. In this context, late Eocene and early Miocene alkaline magmatism was dominantly sourced from the asthenospheric mantle, whereas Plio-Pleistocene alkaline magmas contain the largest proportion of an enriched lithospheric component. The peculiar compositional features of the early Miocene subalkaline lavas are interpreted in terms of high-degree mantle melting followed by melt–lithospheric mantle reaction processes. Based on current knowledge about the relative movement and decoupling between lithosphere and asthenosphere, we propose that the asthenosphere below the study area rose up to compensate for the westward drift of the mantle wedge coupled with the South American lithosphere.

Petrology and geochemistry of peridotites and associated vein rocks of Zabargad Island, Red Sea, Egypt

Abstract: Zabargad (St. John's) Island in the Red Sea contains three ultramafic bodies, one of which bas produced the famous gem olivine (peridot). The ultramafic rock types consist of two major groups—the peridotites and the vein rocks within them. The peridotites are divided into three groups: primitive, depleted and metasomatized. The primitive peridotites are the most abundant and are represented by mainly pristine spinellherzolites which have chemical compositions representative of the subcontinental upper mantle. The depleted peridotites are mainly harzburgites and nome dunites and both are similar to worldwide occurrences. The most depleted peridotites also appear to have the greatest metasomatic additions of incompatible elements, as has been noted at other localities. Metasomatic additions were clearly accompanied by tectonic shearing. Metasomatism included infiltration of incompatible elements and the formation of porphyroblasts of clinopyroxene, amphibole, Al-spinel and plagioclase; il took place under a variety of p-T conditions and with fluids of differing compositions. The vein rocks are mainly monomineralic and comprise olivinites, orthopyroxenites, clinopyroxenites, websterites, hornblendites and plagioclasites. These rocks are believed to have formed from fluids similar to that which metasomatized the host rock, rather than by some kind of igneous process. The fluids were derived from peridotite reservoirs (fertile and depleted) and apparently were in equilibrium with these reservoirs. Highly abundant fluid inclusions document the hypersaline and CO2-dominated character of these fluids. Monomineralic vein rocks are closely associated with metasomatic and tectonic processes, and there is a complete transition between metasomatic impregnation and formation of vein rocks. These processes may have also been active in other peridotite bodies of the world, as was earlier recognized and documented in the Seiad Ultramafic Complex, California. Metasomatism is evident along clinopyroxenite and hornblendite veins, whereas orthopyroxenites, olivinites and plagioclasites do not show any interaction with the wall rocks. Olivinites are probably the latest (lowest p-T) vein rock type, and the latest olivine which formed within their open cavities became the gem peridot. Zabargad ultramafic rocks preserve relic phases indicating an initial depth of origin greater than 85 km. Clinopyroxenites preserve the memories of the highest p-T conditions and they may be the first vein rock type formed in the peridotites. The p-T path of uplift coincides with the oceanic geotherm at great depth but deviates systematically from it with falling pressure in a series of tectonic stages accompanied by metasomatism and recrystallization. The p-T and petrologic history indicates rapid uplift, a feature which is supported by extensive contact metamorphism of the associated metasediments.

Geochemistry of basalt from the North Gorda segment of the Gorda Ridge: Evolution toward ultraslow spreading ridge lavas due to decreasing magma supply

Abstract: [1] High-density, precisely located, dive and rock-corer basalt samples from the 65-km-long North Gorda ridge segment reveal compositional diversity as great as for the entire Gorda Ridge. Lava compositions along the ridge axis show considerable major and minor element diversity (MgO 9.2–4.4%, K2O 0.04–0.36%) for lavas erupted in close proximity. Although they form a near-continuum in the higher MgO range, the samples can be separated into two groups; one is typical N-type mid-ocean ridge basalt (MORB) (K2O/TiO2 0.09). Incompatible elements also reflect this grouping with (Ce/Yb)N 20 for N-MORB and (Ce/Yb)N > 1 and Zr/Nb 1.0–3.0). Arctic E-MORB compositions lie along a common mixing trend with those from North Gorda. As the magma budget and/or partial melting decreases, a similar enriched component, especially in K, Ba, and LREE, widely present in the oceanic mantle is apparently incorporated to a greater degree. At North Gorda, morphology and chemical characteristics appear to evolve with time toward that of ultraslow spreading ridges.