Incompatible element

About: Incompatible element is a research topic. Over the lifetime, 2420 publications have been published within this topic receiving 154052 citations.

31. mantle melting systematics: transition from continental to oceanic volcanism on the southeast greenland margin 1

Abstract: We present trace element analyses of basaltic and picritic lavas recovered from the Ocean Drilling Program Leg 152 transect on the southeast Greenland volcanic rifted margin. These lavas span the stratigraphic interval from continental to oce anic magmatism. Incompatible element patterns define two geochemical groups within the Site 917 upper series. Group 1 flows are characterized by (La/Sm) N = 0.3-0.8, whereas group 2 flows have (La/Sm) N = 0.7-1.2 and higher mantle-normalized Th, Ba, and Pb, and lower Nb and U concentrations. The transition upsection from group 1 to group 2 at Site 917 occurs between 114 and 65 meters below seafloor, and is represented by interfingering of flows belonging to the two groups. (La/Sm) N, Ba/Zr, and Th/Pb ratios and mantle-normalized incompatible element concentrations decrease systematically with stratigraphic height within each group, and the Site 915 and Site 918 units are generally continuous with group 2. These variations imply an increase in the extent of partial melting with time. Lu/Hf ratios vary from 0.14 to 0.25 through the upper series and into the Site 915 and Site 918 flows. This relationship suggests the importance of residual garnet in the mantle source melting decreased with time. We develop a quantitative model for mantle melting to investigate melting systematics responsible for these relation ships. Comparison between observed data and model results suggests a progressive increase in the extent of partial melting (from 4% to 12%) and decrease in mean pressure of melting with time. This temporal evolution of primary magma compositions is explicable by rapid thinning of the continental lithosphere during eruption of the upper series. We conclude that grou p 1 units were derived from mantle with normal mid-ocean-ridge basalt source characteristics, whereas units from group 2 and from Sites 915 and 918 were derived from a source similar to depleted Icelandic mantle. We infer that the thermal anomaly associated with the ancestral Iceland plume pre-dated the transition in mantle source compositions.

Chemical and isotopic constraints on the origin of basalts from Ninetyeast Ridge, Indian Ocean: results from DSDP Legs 22 and 26 and ODP Leg 121

Abstract: There are significant variations in isotope ratios and highly incompatible element ratios between sites, which suggest that the mantle source for the ridge basalts was compositionally variable. The authors agree with previous models that relate Ninetyeast Ridge to a mantle plume in the southern Indian Ocean. The tholeiitic, iron-enriched, and voluminous character of the ridge basalts is typical of oceanic islands associated with plumes on or near a mid-ocean ridge. The major element data, like the gravity data, strongly suggest that the ridge was erupted on or very close to an active spreading center. Isotopically, the most likely plume that created the excess magmatism on the Ridge is the Kerguelen-Heard plume system, but the Ninetyeast Ridge basalts do not represent a simple mixing of the Kerguelan plume and mid-ocean Ninetyeast Ridge basalt mantle. -from Authors

Trace-element partitioning between plagioclase, alkali feldspar, Ti-magnetite, biotite, apatite, and evolved potassic liquids from Campi Flegrei (Southern Italy)

Abstract: Partition coefficients (Min/L D ) for a series of geochemically relevant elements have been calculated from combined EMP/LA-ICP-HRMS analyses of plagioclase, alkali feldspar, Ti-magnetite, biotite, apatite, and trachytic/trachyphonolitic melt pairs in selected Campi Flegrei rocks. Pl/L D and Kfs/L D values are generally very low for most of the trace-elements but Sr, Ba, and Eu. Kfs/L D for the latter elements record a systematic increase as the melt composition changes from trachyte to trachyphonolite, likely due to increasing structural compliance of the sanidine in the trachyphonolites related to larger Na/K values. Conversely, Kfs/L D values for transitional, highly charged incompatible elements (e.g., LREE) decrease from trachyte to trachyphonolite, possibly in response to the decrease of melt polymerization. Min/L D values for titanomagnetite generally decrease with the increasing melt evolution, the highest values being those measured for Ti, V, and Sc. Ti, Ba, Sc, Rb, Nb, Ta, and V are compatible in biotite in equilibrium with trachytic melt, whereas Cs, Sr, and Pb are incompatible and REE are strongly incompatible, as supported by the extremely low Bt/L D Y (0.003–0.008). Partition coefficients for apatite and trachyphonolitic glass pairs are high for Sr, REE (particularly MREE), and Y, large for Th, U, and V, generally low for HFSE, and variable for other LILE. The comparison of measured Min/L D values for Campi Flegrei trachytes/trachyphonolites with other sets of partition coefficients reported in literature for evolved systems suggests that a reliable data set for magma evolution modeling requires: (1) a thorough preliminary selection of natural samples; (2) the adoption of accurate microanalytical techniques; (3) the direct measurement of Min/L D values for each specific melt composition.

Magma Mixing in Komatiitic Lavas from Munro Township, Ontario

Abstract: Komatiites at Munro Township, northeast Ontario, show greater LREE depletion and have lower ratios of highly to moderately incompatible elements (e.g. Ti/Sc) than associated komatiitic basalts. These differences indicate that the two magma types are not related to one another by low pressure fractional crystallization: they formed either from mantle sources with slightly different compositions, or from the same source under different conditions of partial melting or high pressure fractionation.

Triassic morb magmatism in the southern mirdita zone (albania)

Abstract: In southern Albania the Mirdita Ophiolitic nappe is characterized by subophiolitic complexes in which remnants of volcanic ophiolite sequences of Triassic age have been identified, either as rare blocks of variable dimension in the Rubik Complex, or as a thin tectonic unit (the Porava Unit), sited immediately under the main ophiolitic masses of the Eastern Ophiolite Belt. In this paper the results of petrological investigations on basalts and biostratigraphical studies on associated radiolarian cherts included in these subophiolitic complexes units are presented. Biostratigraphical investigations indicate that cherts have ages ranging from Middle to Late Triassic. The associated basalts are represented by both high- Ti mid-ocean ridge basalts (MORB) and alkaline ocean island basalts (OIB). MORB rocks mainly consist of basalts and ferrobasalts with a mild enrichment in low field strength elements and flat rare earth element patterns and, subordinately, by basalts strongly depleted in incompatible elements and light rare earth elements. The chemistry of slightly enriched MORB is consistent with a generation in a mid-ocean ridge setting, from somewhat enriched sub-oceanic mantle source(s), whereas depleted MORB generated from a primitive MOR-type mantle source. The OIB rocks imply a generation in a within-plate oceanic setting from a mantle source enriched by plume chemical components. Basalts and associated cherts from southern Albania subophiolitic melanges represent remnants of a Triassic oceanic lithosphere, which testify for the existence, from northern Albania to southern Greece, of a Middle to Late Triassic oceanic basin located between the Adria and Eurasia plates. The occurrence in the Rubik Complex and Porava Unit of MOR basalts generated from differently enriched sources, as well as of alkaline OIBs, suggests that the early stage of oceanic spreading was variably associated with a plume activity.