Incompatible element

About: Incompatible element is a research topic. Over the lifetime, 2420 publications have been published within this topic receiving 154052 citations.

Contrasting compositions of Mariana Trough fallout tephra and Mariana Island arc volcanics: a fractional crystallization link

Abstract: Discrete Quaternary (<400 ka) tephra fallout layers (mostly <1 cm thick) within the siliceous oozes of the central Mariana Trough at 18°N are characterized by medium-K to high-K subalkalic volcanic glasses (K2O=0.8–3.2 wt.%) with high large-ion lithophile elements (LILE)/high-field-strength elements (HFSE) ratios and Nb depletion (Ba/La≈35; Ba/Zr≈3.5; La/Nb≈4) typical for convergent margin volcanic rocks. Compositional zoning within layers ranges from basaltic to dacitic (SiO2=48–71 wt.%; MgO=0.7–6.5 wt.%); all layers contain basaltic andesites. The tephra layers are interpreted as single explosive eruptive events tapping chemically zoned reservoirs, the sources being the Mariana arc volcanoes (MAV) due to their proximity (100–400 km) and similar element ratios (MAV: Ba/La=36±7; Ba/Zr=3.5±0.9). The glasses investigated, however, contrast with the contemporaneous basaltic to dacitic lavas of the MAV by being more enriched in TiO2 (≈1.2 wt.%; MAV≈0.8 wt.%), FeO* (≈10 wt.%, MAV≈8–9 wt.%), K2O (≈1.1 wt.%; MAV≈0.8 wt.%) and P2O5 (≈0.4 wt.%; MAV≈0.2 wt.%). (Semi-)Incompatible trace elements (including Rare Earth Elements (REE)) of the basaltic-andesitic and dacitic glasses match those of the dacitic MAV lavas, which became enriched by fractional crystallization. Moreover, the glasses follow a tholeiitic trend of fractionation in contrast to MAV transitional trends and have a characteristic P2O5 trend that reaches a maximum of 0.6 wt.% P2O5 at ≈57 wt.% SiO2, whereas MAV lavas increase linearly in P2O5 from 0.1 to 0.3 wt.% with increasing silica. Both explosive and effusive series are interpreted to have evolved in common magma reservoirs by convective fractionation. Similar parental magmas are suggested to have separated into coexisting Si-andesitic to dacitic and basaltic melts by in situ crystallization. The differentiated melt is interstitial in an apatite-saturated crystalline mush of plag+px±ox±ol at the cooler chamber margins in contrast to the less differentiated basaltic to basaltic-andesitic magmas, which are not yet saturated in apatite and occupy the chamber interior. Reinjection of interstitial melt into the chamber interior and mixing with larger melt fractions of the interior liquid (mixing ratios about ≈1: 8–9) can explain the paradoxical behavior of apatite-controlled P and MREE variation in the basaltic andesite glasses and their MAV dacite-like fractionation patterns. The process may also account for the exclusively tholeiitic trend of fractionation of the glass shard series, but in situ crystallization alone cannot cause their absolute enrichment in (semi-)incompatible elements. The newly mixed melt is suggested to form the basaltic end member of the glass shard series. However, it must have become physically separated from the main MAV magma body (possibly by density-driven convective fractionation) in order to allow for further evolution of the contrasting geochemical paths as well as differentiation.