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Incompatible element
About: Incompatible element is a research topic. Over the lifetime, 2420 publications have been published within this topic receiving 154052 citations.
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TL;DR: A 500m-thick lens of carbonatitic ultrabasic lapilli tuffs and lavas interbedded with platformal Povungnituk sediments in the foreland of the Cape Smith Belt is its earliest known magmatism and may relate to its initial rifting as mentioned in this paper.
Abstract: A 500 m-thick lens of carbonatitic ultrabasic lapilli tuffs and lavas interbedded with platformal Povungnituk sediments in the foreland of the Cape Smith Belt is its earliest known magmatism and may relate to its initial rifting. The sequence comprises tuffs capped in part by effusives. Accretionary and cored lapilli in the tuffs and pillows in the lavas suggest emplacement in a shallow marine environment. Its current assemblage of antigorite, chlorite, talc, and (in part primary?) carbonate, magnetite, ilmenite, minor chromite, and phlogopite results from probable concurrent hydro-thermal alteration and subsequent greenschist regional metamorphism. Surviving accessory minerals: apatite, monazite, zircon, rutile, and aeschenite(?) are widespread but scarce. Carbonate (mostly dolomite) is a major and integral component of the rock and interpreted as an original, albeit recrystallized, magmatic constituent. Magnetite is conspicuous in the tuffs: as lapilli and lapilli cores, locally as giant crystals, and as stringers. Except in subhedral groundmass crystals, its negligible TiO2 is evidence of its hydrothermal reconstitution. Compositions of chromite cores and rare relicts of phlogopite crystals are consistent with mantle derivation. Rock compositions are low in SiO2 ( 25 wt.%) and alkaline. The immobile incompatible elements (e.g., Zr, average 260 ppm; Nb, average 130 ppm) and the light rare-earth elements are enriched. The rocks are compositionally similar to type Siberian meimechites and closely resemble the “meimechite”–carbonatite eruptives of Castignon Lake, Labrador Trough. Based on experimental evidence, Lac Leclair magmas are interpreted as originating by minor partial melting of carbonated mantle at ∼100 km depths and reaching the surface via conduits opened by deep rifting that initiated the Cape Smith segment of the Trans-Hudson Orogen.
15 citations
TL;DR: A 6 mm-diameter dark spherule, 15434,28, from the Apollo 15 landing site has a homogeneous glass interior with a 200 microns-thick rind of devitrified or crystallized melt as discussed by the authors.
15 citations
TL;DR: In this paper, the trace element contents of D'Orbigny phases were reported and compared with the popular igneous genetic model for the origin of angrites in the early solar nebula.
Abstract: D'Orbigny is an exceptional angrite. Chemically, it resembles other angrites such as Asuka-881371, Sahara 99555, Lewis Cliff (LEW) 87051, and LEW 86010, but its structure and texture are peculiar. It has a compact and porous lithology, abundant glasses, augite-bearing druses, and chemical and mineralogical properties that are highly unusual for igneous rocks. Our previous studies led us to a new view on angrites: they can possibly be considered as CAIs that grew to larger sizes than the ones we know from carbonaceous chondrites. Thus, angrites may bear a record of rare and special conditions in some part of the early solar nebula. Here we report trace element contents of D'Orbigny phases. Trace element data were obtained from both the porous and the compact part of this meteorite. We have confronted our results with the popular igneous genetic model. According to this model, if all phases of D'Orbigny crystallized from the same system, as an igneous origin implies, a record of this genesis should be expressed in the distribution of trace elements among early and late phases. Our results show that the trace element distribution of the two contemporaneous phases olivine and plagioclase, which form the backbone of the rock, seem to require liquids of different composition. Abundances of highly incompatible elements in all olivines, including the megacrysts, indicate disequilibrium with the bulk rock and suggest liquids very rich in these elements (>10,000 x CI), which is much richer than any fractional crystallization could possibly produce. In addition, trace element contents of late phases are incompatible with formation from the bulk systems residual melt. These results add additional severe constraints to the many conflicts that existed previously between an igneous model for the origin of angrites and the mineralogical and chemical observations. This new trace element content data, reported here, corroborate our previous results based on the shape, structure, mineralogy, chemical, and isotopic data of the whole meteorite, as well as on a petrographic and chemical composition study of all types of glasses and give strength to a new genetic model that postulates that D'Orbigny (and possibly all angrites) could have formed in the solar nebula under changing redox conditions, more akin to chondritic constituents (e.g., CAIs) than to planetary differentiated rock.
15 citations
TL;DR: In this paper, the authors reported new geological, mineralogical, geochemical and geochronological data about the Katugin Ta-Nb-Y-Zr (REE) deposit, which is located in the Kalar Ridge of Eastern Siberia (the southern part of the Siberian Craton).
15 citations
TL;DR: The off-rift central volcano of Oraefajokull has very distinctive EM1-like isotopic compositions compared with other Icelandic lavas as discussed by the authors, which can be interpreted as a result of mixing.
Abstract: The off-rift central volcano of Oraefajokull has very distinctive EM1-like isotopic compositions compared with other Icelandic lavas. New Pb–Nd–Sr isotopic data from Oraefajokull show strong correlations interpreted as a result of mixing. End-members are a depleted mantle source incorporating 0.5 % subduction-processed sediment and a mantle source with an isotopic signature similar to lavas of the Reykjanes Peninsula. Sr–Nd–Pb isotopic correlations of Icelandic Eastern Rift Zone (ERZ) lavas are almost completely distinct from those of the Reykjanes Peninsula and the Western Rift Zone (WRZ) and require a high-207Pb/204Pb, low-143Nd/144Nd end-member that resembles Oraefajokull compositions, which is very distinct from the enriched end-members suggested for the Reykjanes Peninsula and the WRZ. Given the similar depth and degree of melting at rift zones, variation in the observed enriched end-members between rift zones must indicate spatial variations in enriched mantle sources within the shallow mantle under Iceland rather than purely mixing of melts from a bi-lithological mantle. This is consistent with observations that the ERZ lavas erupted closest to Oraefajokull exhibit the most Oraefajokull-like isotopic compositions, implying that a homogenised Oraefajokull source with positive ∆207Pb is focused under the Oraefajokull centre and its associated flank zone. This then mixes laterally with the dominant negative-∆207Pb ERZ mantle source. Like Reykjanes Peninsula and WRZ lavas, the ERZ mantle source has strongly negative Δ207Pb and low K/Nb (<170), and these provide evidence for a recycled oceanic crust contribution. The range in 206Pb/204Pb in mantle sources with negative Δ207Pb was probably generated by heterogeneity in 206Pb/204Pb and μ in the recycled oceanic crust, which is the dominant source of incompatible elements in Icelandic lavas.
15 citations