Incompatible element

About: Incompatible element is a research topic. Over the lifetime, 2420 publications have been published within this topic receiving 154052 citations.

Geochemistry and petrogenesis of the Proterozoic dykes in Tamil nadu, southern India: another example of the Archaean lithospheric mantle source

Abstract: Approximately 1650-Ma-old NW/SE and NE/SW-trending dolerite dykes in the Tiruvannamalai (TNM) area and approximately 1800-Ma-old NW/SE-trending dolerite dykes in the Dharmapuri (DP) area constitute major Proterozoic dyke swarms in the high-grade granulite region of Tamil nadu, southern India. The NW- and NE-trending TNM dykes are compositionally very similar and can be regarded as having been formed during a single magmatic episode. The DP dykes may relate to an earlier similar magmatic episode. The dolerites are Fe-rich tholeiites and most of the elemental variations can be explained in terms of fractional crystallisation. Clinopyroxene and olivine are the inferred ferromagnesian fractionation phases followed by plagioclase during the late fractionation stages. All the studied dykes have, similar to many continental flood basalts (CFB), large-ion lithophile element (LILE) and light rare-earth element (LREE) enrichment and Nb and Ta depletion. The incompatible element abundance patterns are comparable to the patterns of many other Proterozoic dykes in India and Antarctica, to the late Archaean (∼2.72 Ga) Dominion volcanics in South Africa and to the early Proterozoic (∼2.0 Ga) Scourie dykes of Scotland. The geochemical characteristics of the TNM and DP dykes cannot be explained by crustal contamination alone. Instead, they are consistent with derivation from an enriched lithospheric mantle source which appears to have been developed much earlier than the dyke intrusions during a major crustal building event in the Archaean. The dyke magmas may have been formed by dehydration melting induced by decompression and lithospheric attenuation or plume impingement at the base of the lithosphere. These magmas, compared with CFB, appear to be the minor partial melts from plume heads of smaller diameter and of shallow origin (650 km). Therefore, the Proterozoic thermal events could induce crustal attenuation and dyke intrusions in contrast to the extensive CFB volcanism and continental rifting generally associated with the Phanerozoic plumes of larger head diameter (>1000 km) and of deeper origin (at crust mantle boundary).

Dynamical geochemistry of the mantle

Abstract: . The reconciliation of mantle chemistry with the structure of the mantle inferred from geophysics and dynamical modelling has been a long-standing problem. This paper reviews three main aspects. First, extensions and refinements of dynamical modelling and theory of mantle processing over the past decade. Second, a recent reconsideration of the implications of mantle heterogeneity for melting, melt migration, mantle differentiation and mantle segregation. Third, a recent proposed shift in the primitive chemical baseline of the mantle inferred from observations of non-chondritic 142Nd in the Earth. It seems most issues can now be resolved, except the level of heating required to maintain the mantle's thermal evolution. A reconciliation of refractory trace elements and their isotopes with the dynamical mantle, proposed and given preliminary quantification by Hofmann, White and Christensen, has been strengthened by work over the past decade. The apparent age of lead isotopes and the broad refractory-element differences among and between ocean island basalts (OIBs) and mid-ocean ridge basalts (MORBs) can now be quantitatively accounted for with some assurance. The association of the least radiogenic helium with relatively depleted sources and their location in the mantle have been enigmatic. The least radiogenic helium samples have recently been recognised as matching the proposed non-chondritic primitive mantle. It has also been proposed recently that noble gases reside in a so-called hybrid pyroxenite assemblage that is the result of melt from fusible pods reacting with surrounding refractory peridotite and refreezing. Hybrid pyroxenite that is off-axis may not remelt and erupt at MORs, so its volatile constituents would recirculate within the mantle. Hybrid pyroxenite is likely to be denser than average mantle, and thus some would tend to settle in the D" zone at the base of the mantle, along with some old subducted oceanic crust. Residence times in D" are longer, so the hybrid pyroxenite there would be less degassed. Plumes would sample both the degassed, enriched old oceanic crust and the gassy, less enriched hybrid pyroxenite and deliver them to OIBs. These findings can account quantitatively for the main He, Ne and Ar isotopic observations. It has been commonly inferred that the MORB source is strongly depleted of incompatible elements. However it has recently been argued that conventional estimates of the MORB source composition fail to take full account of mantle heterogeneity, and in particular focus on an ill-defined "depleted" mantle component while neglecting less common enriched components. Previous estimates have also been tied to the composition of peridotites, but these probably do not reflect the full complement of incompatible elements in the heterogeneous mantle. New estimates that account for enriched mantle components suggest the MORB source complement of incompatibles could be as much as 50–100 % larger than previous estimates. A major difficulty has been the inference that mass balances of incompatible trace elements could only be satisfied if there is a deep enriched layer in the mantle, but the Earth's topography precludes such a layer. The difficulty might be resolved if either the Earth is depleted relative to chondritic or the MORB source is less depleted than previous estimates. Together these factors can certainly resolve the mass balance difficulties.

Alkali granite-syenite-carbonatite association in Munnar Kerala, India; implications for rifting, alkaline magmatism and liquid immiscibility

Abstract: Occurrence of carbonatite is reported from the Munnar area, Kerala, where an alkali granite-syenite-carbonatite association is seen emplaced along the intersection zone of the Attur and Kerala fault-lineaments. The carbonatites are of two varieties, a calcite-rich sovite and a very coarse grained, calcite and dolomite bearing alvikite. Higher levels of SiO2, Al2O3 and CaO are characteristic of these as compared to the composition of typical carbonatites. The transition element levels are high whereas the incompatible elements show lower values. The low Sr values, lower amount of apatite and absence of rare metal minerals preclude a primary carbonatite magma. The associated syenite and alkali granite have higher K2O, K2O/Na2O, K/Rb, K/Ba and transition element levels. Petrochemical features suggest the rock association to be a result of separation of an immiscible fraction of less viscous carbonate liquid during cooling and ascent from a more viscous polymerized alkali silicate phase. The pre-requisites for melt equilibration and liquid immiscibility were achieved through volatile degassing related to crustal warping and rifting. The unique alkaline association of Munnar, which shows spatial relationships with deep-seated faults as well as a probable triple-point junction, is suggested to be a signature of late Precambrian alkaline magmatism which manifested in the Indian shield as a precursor to the rifting of the continental margin.