Incompatible element

About: Incompatible element is a research topic. Over the lifetime, 2420 publications have been published within this topic receiving 154052 citations.

Nature and distribution of dykes and related melt migration structures in the mantle section of the Oman ophiolite

Abstract: [1] We conducted a comprehensive field, petrographic, and microprobe study of the dykes and porous flow channels cropping out in the Oman harzburgites. The 36 rock types we recognized among of about 1000 samples can be grouped in two main magma suites contrasted in terms of structural and textural characteristics, modal composition, order of crystallization, and phase chemistry. One suite (troctolites, olivine gabbros, opx-poor gabbronorites, and rare oxyde gabbros) derives from MORB-like melts. The other suite (pyroxenites, opx-rich gabbronorites, diorites, and tonalite-trondhjemites) derives from melts richer in silica and water than MORBs and ultradepleted in incompatible elements. Dykes and porous flow channels from the MORB suite are restricted to a few areas, covering only 25% of the mantle section. This is an unexpected result as the deep Oman crust is made essentially of cumulates from MORB-like melts. Their composition, texture, and relations with the host harzburgites point to high mantle temperatures at the time of crystallization (likely above 1100°C, up to 1200°C for part of them), i.e., conditions close to the “asthenosphere/lithosphere” boundary. The largest outcrop of mantle harzburgites enclosing MORB like dykes is a 80 km long and 10 km wide corridor, parallel to the strike of the sheeted dyke complex and centered on an area where a former mantle upwelling has been unambiguously defined (the Maqsad “diapir”). A few other occurrences of mantle cumulates from the MORB suite are smaller than the Maqsad area and have a lesser abundance of troctolites (i.e., of high-temperature cumulates). We interpret the troctolite zones of Oman as the witnesses of former diapirs frozen at various stages of their development. Dykes belonging to the depleted suite are the most common in Oman harzburgites. Their structural and textural characteristics show that they crystallized in a mantle colder than the melt (likely in the range 600°C to 1100°C). A possible origin for the parent melts of this suite is in situ partial melting of the shallow and partly hydrated lithosphere residual after MORB extraction. Our data support the view that feeding magma chambers with MORBs is a focused (and likely episodic) process involving the rise of hot mantle to the base of the crust through a lithospheric lid accreted during a previous diapiric event. They suggest also that the shallow mantle beneath spreading centers is a place of important petrologic processes, some of them predicted on the basis of MORB composition (e.g., fractionation inside melt conduits) and other ones unexpected (e.g., remelting of the depleted lithosphere).

Deep-seated fractionation during the rise of a small-volume basalt magma batch: Crater Hill, Auckland, New Zealand

Abstract: Crater Hill is a small volume alkali olivine basalt volcano in the Auckland volcanic field. Crater Hill consists of a sequence of pyroclastic and effusive eruptive units of which the earliest have low silica, ferromagnesian elements and Mg/Fe ratios, high incompatible elements and are more silica undersaturated while the last material to be erupted has higher silica, ferromagnesian elements and Mg/Fe ratios but relatively low incompatible elements. Through the sequence, Mg-number changes from 59 to 67 and LaN/LuN decreases by a factor of 3. This systematic compositional variation is interpreted to be the result of clinopyroxene ± spinel fractionation at pressures of at least 1.4–1.9 GPa, from a primary magma generated by small-degree partial melting in the garnet peridotite stability field (>2.5 GPa). Fractionation occurred where early crystals grew and accumulated along the conduit walls. The rising magma evolved along a polybaric liquid line of descent until it encountered lithosphere cold enough to chill the dike margin. Above this depth, further cooling resulted only in the growth of suspended phenocrysts in a magma separated from the country rock by a chilled margin. This process is observed in the Auckland volcanic field because the rate of magma production is very small allowing compositional features to be preserved that would be overwhelmed in a larger scale magmatic system.

Arc Basalt Simulator version 2, a simulation for slab dehydration and fluid‐fluxed mantle melting for arc basalts: Modeling scheme and application

Abstract: [1] Convergent margin magmas typically have geochemical signatures that include elevated concentrations of large-ion lithophile elements; depleted heavy rare earth elements and high field strength elements; and variously radiogenic Sr, Pb, and Nd isotopic compositions. These have been attributed to the melting of depleted mantle peridotite by the fluxing of fluids or melts derived from subducting oceanic crust. High Mg # basalts and high Mg # andesites are inferred to make up the bulk of subduction-related primary magmas and may be generated by fluid or melt fluxing of mantle peridotite. The difference in contributions from the subducted slab found among various arcs appears to be mostly controlled by thermal structure. Cold slabs yield fluids, and hot slabs yield melts. Recent experimental studies and thermodynamic models better constrain the phase petrology of the slab components during prograde metamorphism and melting, mantle wedge melting, and mantle slab melt reaction. Experimental results also constrain the behavior of many elements in these processes. In addition, geodynamic models allow increasingly realistic, quantitative modeling of the temperature and pressure in the subducted slab and mantle wedge. These developments together enable generation of forward models to explain arc magma geochemistry. The Arc Basalt Simulator (ABS) version 2 (ABS2) uses an Excel® spreadsheet-based calculator to predict the partitioning of incompatible element and Sr-Nd-Pb isotopic composition in a slab-derived fluid and in arc basalt magma generated by an open system fluid-fluxed melting of mantle wedge peridotite. The ABS2 model is intended to simulate high Mg # basalt geochemistry in relatively cold subduction zones. The modeling scheme of ABS2 is presented and is applied to primitive arc magmas.