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Showing papers on "Inorganic compound published in 2007"






Journal ArticleDOI
TL;DR: In this paper, a concept of "combinatorial synthesis" is introduced for the cases of combining two or more functional units in a typical synthesis into a single one, which will lead to a unique distribution and high concentration of functional groups.
Abstract: Great interests have been imparted on organically modified mesoporous silica materials due to their high surface areas, uniform pore sizes and integrated functionality. Besides the inherent character of inorganic and organic components, the interactions between them should also be recognised for the synthesis, including organic-group loading, mesostructure and particle morphology, condensation, as well as organic-group distribution. To obtain long range ordered hybrid materials, several factors, such as relative hydrolysis and condensation rates of the inorganic and organic sources, chemical character such as hydrophobicity/hydrophilicity and acid/base of organic ligand as well as the surfactant category, should be surveyed. A concept of 'combinatorial synthesis' is introduced here for the cases of combining two or more functional units in a typical synthesis into a single one. The silica precursors in the preparation of periodic mesoporous organosilanes (PMOs) are the aggregation of inorganic and organic silicates. The assembly will lead to a unique distribution and high concentration of functional groups. Both the confinement within the mesopores and the pore surface nature will affect the accessibility to the active sites, and therefore, the adsorption and relative applications. These characters win them ample host-guest chemistry. They can seek the opportunities in the fields of catalysis, separation, electronic devices, biomedicines, nanomaterial fabrication, etc.

33 citations




Patent
26 Sep 2007
TL;DR: In this paper, the authors proposed a method of forming an OLED device, which consists of a first electrode, a second electrode, one or more organic layers formed between the first and second electrodes, at least one organic layer being a light-emitting layer, and a thin film encapsulation layer.
Abstract: The invention is directed towards an OLED device, comprising a first electrode (12), a second electrode (16), one or more organic layers (14) formed between the first electrode and second electrode, at least one organic layer being a light-emitting layer; and a thin film encapsulation layer (17) comprising either (a) at least one first layer of zinc oxide and at least one second layer of a second inorganic compound, or (b) a layer that is a mixture of zinc oxide and a second inorganic compound. The invention is also directed to a method of forming such an OLED device.

29 citations


Patent
20 Dec 2007
TL;DR: In this paper, a gas barrier laminate is constructed with a base material consisting of an inorganic compound and at least one set of inorganic layer and organic layer formed on the base material film.
Abstract: In a gas barrier laminate film comprising a base material film containing an inorganic compound and at least one set of inorganic layer and organic layer formed on the base material film, the base material film is formed with a resin having a glass transition temperature of 250° C. or higher. A gas barrier laminate film that has superior durability, heat resistance and gas barrier performance, shows a small difference in coefficient of linear expansion relative to an contiguous layer and can maintain superior gas barrier property even if it is bent is provided.

26 citations


Journal ArticleDOI
TL;DR: In this paper, the UO7 and SeO4 polyhedra polymerize by sharing common O atoms to form chains (compound 1) or sheets (compounds 2 and 3).

24 citations



Patent
25 Jan 2007
TL;DR: In this paper, a composite layer containing an organic compound and an inorganic compound is provided in at least part of one of a source electrode and a drain electrode in an organic field effect transistor, and as the organic compound, a carbazole derivative represented by the general formula (1) is used.
Abstract: It is an object to provide an organic field effect transistor including an electrode which can reduce an energy barrier at an interface between a conductive layer and a semiconductor layer, and a semiconductor device including the organic field effect transistor. A composite layer containing an organic compound and an inorganic compound is provided in at least part of one of a source electrode and a drain electrode in an organic field effect transistor, and as the organic compound, a carbazole derivative represented by the general formula (1) is used. By providing the composite layer in at least part of one of the source electrode and the drain electrode, an energy barrier at an interface between a conductive layer and a semiconductor layer can be reduced.

Journal ArticleDOI
TL;DR: Diode performance and electroluminescence are obtained from devices based on semiconductor polymer-incorporated semiconducting SnS2, demonstrating that judicious selection of the composite components in combination with the optimization of material synthesis conditions allows new hierarchical structures to be tailored for electronic and optoelectronic applications.
Abstract: Lamellar nanocomposites based on semiconducting polymers incorporated into layered inorganic matrices are prepared by the co-assembly of organic and inorganic precursors Semiconducting polymer-incorporated silica is prepared by introducing the semiconducting polymers into a tetrahydrofuran (THF)/water homogeneous sol solution containing silica precursor species and a surface-active agent Semiconducting polymer-incorporated MoS2 and SnS2 are prepared by Li intercalation into the inorganic compound, exfoliation and restack in the presence of the semiconducting polymer All lamellar nanocomposite films are organized in domains aligned parallel to the substrate surface plane The incorporated polymers maintain their semiconducting properties, as evident from their optical absorption and photoluminescence spectra The optoelectronic properties of the nanocomposites depend on the properties of both the inorganic host and the incorporated guest polymer as demonstrated by integrating the nanocomposite films into light-emitting diodes Devices based on polymer-incorporated silica and polymer-incorporated MoS2 show no diode behaviour and no light emission due to the insulating and metallic properties of the silica and MoS2 hosts In contrast, diode performance and electroluminescence are obtained from devices based on semiconducting polymer-incorporated semiconducting SnS2, demonstrating that judicious selection of the composite components in combination with the optimization of material synthesis conditions allows new hierarchical structures to be tailored for electronic and optoelectronic applications

Journal ArticleDOI
TL;DR: In this article, the absorption coefficients for the three compounds were determined from the spectra, and the monitoring by UV-vis spectroscopy measurements in real time of the oxidation in the air of the two unstable compounds, GRCl and GRSO4, showed that the two green rusts have a different behaviour due to their own structure.

Patent
05 Dec 2007
TL;DR: In this paper, an electrophoretic display particle and synthesizing method is described, which is characterized by the following: the electrophoreic display particles are finished through one-step reaction in the nonpolar and/or low-polar organic solvent; the reacting material also contains inorganic compound pigment, coupler, reacting initiator and monomer.
Abstract: The invention discloses an electrophoretic display particle and synthesizing method, which is characterized by the following: the electrophoretic display particle is finished through one-step reaction in the non-polar and/or low-polar organic solvent; the reacting material also contains inorganic compound pigment, coupler, reacting initiator and monomer; the low-polar organic solvent can be component of electrophoretic display particle directly without separating, which improves the production and productivity greatly. The invention improves the stability of electrophoretic particle with simple high effect, which is fit for multiple inorganic oxides, inorganics and compound inorganic pigments.

Patent
12 Mar 2007
TL;DR: In this article, a surface-treated metallic member is provided with a rust-preventive film having corrosion resistance, and corrosion resistance after heating, having a composition comprising (S) component as the silicate of at least one metal selected from Li, Na or K, and (Ox) component being a water soluble, oxidizable inorganic compound being a solid at ordinary temperature of selective elements E 1 other than Be, B, F, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Mo, Ag, Cd, Sb, Ba
Abstract: PROBLEM TO BE SOLVED: To provide a surface-treated metallic member provided with a rust-preventive film having corrosion resistance, and corrosion resistance after heating. SOLUTION: A metallic member having a surface made of aluminum based metal is coated with a rust-preventive film, whose coating weight is 0.02 to 5 g/m 2 , having a composition comprising (S) component as the silicate of at least one metal selected from Li, Na or K, and (Ox) component as a water soluble, oxidizable inorganic compound being a solid at ordinary temperature of selective elements E 1 other than Be, B, F, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Mo, Ag, Cd, Sb, Ba, Hg, Pb, In, Te and Tl as the constituting main components, or comprising the (S) component, and (Red) component as a water soluble, reducing inorganic compound being a solid at ordinary temperature of the selective elements E 1 as the constituting main components, or comprising the (S) component, and a compound of the selective elements E 1 , which is also a water soluble inorganic phosphate as the constituting main components, and in which the content of the (Ox) component, (Red) component or (P) component lies in the range of 0.5 to 20 mass%. COPYRIGHT: (C)2008,JPO&INPIT

Patent
08 Feb 2007
TL;DR: In this article, the authors proposed a manufacturing method for an organic EL element having an electron-transport layer, and a method for the manufacturing of such an element was proposed, where the mixture in which the at least two materials are mixed is composed of a mixture of an organic compound and one or more other organic compounds, or a mixture either of a metal or an inorganic compound and other metals or inorganic compounds.
Abstract: PROBLEM TO BE SOLVED: To provide an organic EL element having an electron-transport layer, and a manufacturing method thereof. SOLUTION: The organic EL element has a stack structure including a light-emitting layer and an electron-transport layer between an anode and a cathode. The electron-transport layer includes a first layer composed of a mixture in which at least two materials are mixed and adjacent to the light-emitting layer, and a second layer composed of a mixture in which at least two materials are mixed and adjacent to the cathode. The mixture in which the at least two materials are mixed is composed of a mixture of an organic compound and one or more other organic compounds, or a mixture of a metal or an inorganic compound and one or more other metals or inorganic compounds, or a mixture of one or more organic compounds and one or more metals or inorganic compounds. COPYRIGHT: (C)2007,JPO&INPIT

Patent
11 Oct 2007
TL;DR: In this article, a polysilane-carrying transition metal catalysts exhibit high activity to a hydrogenation reaction, the hydrosilylation reaction, a Heck reaction, and a Suzuki-Miyaura coupling reaction.
Abstract: PROBLEM TO BE SOLVED: To provide a polymer fixed transition metal catalyst fixing an organic polymer with a transition metal, having high activity, and easy in recovery and reuse. SOLUTION: Various transition metals are carried by polysilane, or a polysilane compound and an inorganic compound by combining a microencapsulation method with ligand exchange or reduction operation using the polysilane compound, or the poly silane compound and the inorganic compound. Polysilane carried with the transition metal can easily be cured by heating, microwave irradiation, ultraviolet irradiation or a chemical method such as a hydrosilylation reaction, and is insoluble to various solvents while maintaining the activity of a catalyst. Further, carrying this polysilane-carrying transition metal catalyst on the inorganic compound enhances stability and operability. These polysilane-carrying transition metal catalysts exhibit high activity to a hydrogenation reaction, the hydrosilylation reaction, a Heck reaction, a Suzuki-Miyaura coupling reaction or the like, are easy in recovery and reuse, and are extremely small in metal leakage. COPYRIGHT: (C)2008,JPO&INPIT

Patent
07 Mar 2007
TL;DR: In this article, a surface-defective layer existing on the surface of an anode on a CCM substrate, protecting the anode surface, preventing a drive voltage of an organic EL element from rising, and maintaining uniformity of luminescence was removed by sputtering.
Abstract: The purpose is to remove surface-defective layer existing on the surface of an anode on a CCM substrate, protect the anode surface, prevent a drive voltage of an organic EL element from rising, and maintain uniformity of luminescence On a substrate (12) a CCM layer (14) for converting light wavelength is formed On the CCM layer (14) an anode (16) of IZO is formed On the anode (16) a surface protective layer (18) containing an inorganic compound is formed by an inductively coupled RF plasma support magnetron sputtering A preferable inorganic compound is SiO 2 The surface defective layer of the anode (16) can be removed by sputtering and the state of being removed can be held by the inorganic compound Therefore the electrical stability of the anode (16) can be maintained for a long time, thereby improving the display quality of an organic EL display (100)

Patent
15 Feb 2007
TL;DR: In this paper, a soft magnetic material composed of composite particle powder is obtained in such a manner that silicon alcoxide is added into a suspension in which soft-magnetic particle powder are dispersed in an organic solvent, and a phosphoric-acid solution is added, mixed/agitated and dried at 30 to 120°C.
Abstract: PROBLEM TO BE SOLVED: To provide a soft magnetic material having excellent oxidation resistance, compressibility and fluidity while reducing the change of an electric resistance value even when baked at a high temperature, and a dust core containing the soft magnetic material and having a superior magnetic stability and the high electric resistance value. SOLUTION: The soft magnetic material is composed of composite particle powder in which an inorganic compound consisting of silicon, the inorganic compound consisting of phosphorus, and the inorganic compound consisting of aluminum as required, are attached or coated on the particle surfaces of soft-magnetic particle powder. The soft magnetic material is obtained in such a manner that silicon alcoxide is added into a suspension in which soft-magnetic particle powder is dispersed in an organic solvent, and a phosphoric-acid solution is added, mixed/agitated and dried at 30 to 120°C. COPYRIGHT: (C)2007,JPO&INPIT

Patent
30 May 2007
TL;DR: In this article, a reverse osmosis membrane antisludging agent and preparing method is described, which comprises the following steps: allocating raw material with organic carboxylic acid, compound with amide and sulfonic group, inorganic compound and deionized water; blending compound with ammonium sulfonate group, and water according to proportion; heating to 50-90 deg.c.
Abstract: The invention discloses a reverse osmosis membrane antisludging agent and preparing method, which comprises the following steps: allocating raw material with organic carboxylic acid, compound with amide and sulfonic group, inorganic compound and deionized water; blending compound with amide and sulfonic group, inorganic compound and water according to proportion; heating to 50-90 deg.c; dripping inorganic compound and organic carboxylic acid; stirring to react for 1.5-3.5h; insulating 1-4h; obtaining the product with molecular weight scale between 1500 and 3500; setting the medical quantity between 3ppm and 15ppm in the real water disposing course.

Patent
06 Jun 2007
TL;DR: A kind preparation method of low temperature germanium dioxides -organic modified silicate compound material, first mixing the gamma- (2, 3 ring oxygen propoxylate base) propyl trimethoxy-silane, alcohol and deionized water, then adding hydrochloric acid to be solution A; And then, mixing the isopropanol-germanium and 2-dimethoxy alcohol to be Solution B; solution A mixes solution B to get the compound mother liquor; Adding minor numerators 4-hydroxy azobenzene to
Abstract: A kind preparation method of low temperature germanium dioxides -organic modified silicate compound material, first mixing the gamma- (2, 3 ring oxygen propoxylate base) propyl trimethoxy-silane, alcohol and deionized water, then adding hydrochloric acid to be solution A; And then, mixing the isopropanol-germanium and 2- dimethoxy-alcohol to be solution B; solution A mixes solution B to get the compound mother liquor; Adding minor numerators 4-hydroxy azobenzene to the compound mother liquor then gets the suspended liquid; making use of revolution coating technology deposit the suspended liquid in quartz glass sheet, and heating the deposition film sample This invention uses the improved sol- gel technology as well as low temperature organic- inorganic compound technology , it has the characteristic that the combining temperature is low , the handicraft demands is simple, the repetitiveness is good, the low temperature organic- inorganic compound film material using germanium dioxides and organic modified silicate as the base, it is a kind of photon compound material which realizes the function of optical storage by adding organic dyestuff azobenzene small molecule function base and has the function of light waveguide characteristic at the same time

Patent
03 Sep 2007
TL;DR: In this article, the authors proposed a long-life organic field-effect element with high efficiency and a manufacturing method to provide a long life organic field effect element having high efficiency.
Abstract: PROBLEM TO BE SOLVED: To provide a long-life organic field-effect element having high efficiency, and to provide a manufacturing method therefor. SOLUTION: The organic field-effect element 10 comprises an anode 2 and a cathode 6, and a stack sandwiched between the anode 2 and cathode 6 and formed by stacking at least an inorganic compound layer 3 and an organic light-emitting layer 4, in this order, the organic field-effect element such that the inorganic compound layer 3 has hole transport capability and continuously varies in the work function along the direction of the film thickness. COPYRIGHT: (C)2009,JPO&INPIT

Journal ArticleDOI
TL;DR: In this article, the synthesis of composite organic and inorganic membranes for proton conduction was investigated, and the structure of the composite membranes was complex as several IR peaks were convoluted, indicating the assignment of several functional groups.
Abstract: In this work we investigated the synthesis of composite organic and inorganic membranes for proton conduction. Particles derived from metal alkoxides (M(OR)n) sol-gel processes (Ti, Zr, W with phosphoric acid) were embedded in polymeric matrices of poly-vinyl alcohol, (3-glycidoxypropyl)-trimethoxysilane and ethylene glycol. The structure of the composite membranes was complex as several IR peaks were convoluted, indicating the assignment of several functional groups. However, the peaks assigned to OH groups reduced in intensity in the composite membranes, indicating that cross-linking of hydroxyl groups in the organic and inorganic phases of the membrane may have occurred. The particles allowed for re-arrangement of the polymer matrix, as crystallinity was reduced compared to a polymer blank membrane. The composite membrane process resulted in homogeneous dispersion of nanoparticles into the polymer film. Proton conduction of the inorganic phase was mainly dominated by titania. Binary mixtures of titania phosphate (sample name TiP) resulted in proton conduction of 7.15 ? 10−2 S.cm−1, one order of magnitude higher than zirconia phosphate (ZrP). The addition of Zr and W to TiP forming ternary or quaternary phases also led to lower proton conduction as compared to TiP. Similar trends were also observed for the composite membranes, though the TiP composite membrane proton conduction reduced after several hours of testing at 50?C, which was mainly attributed to acid leaching.

Patent
06 Dec 2007
TL;DR: In this article, a method for obtaining an inorganic compound film having excellent water resistance and also high gas barrier property and transparency is presented, which consists of applying on the surface of a base, the liquid containing a hydrophobic inorganic layered compound in which such a compound is dispersed in an organic solvent, and drying to form a hydophoric inorganic layer compound layer 1, and further applying the above hydophobic compound-containing liquid onto the surface surface of the layer 2, drying to further form one more layer 1; and peeling the whole layered film from
Abstract: PROBLEM TO BE SOLVED: To obtain an inorganic compound film having excellent water resistance and also high gas barrier property and transparency. SOLUTION: The method for obtaining the inorganic compound film comprises: applying on the surface of a base, the liquid containing a hydrophobic inorganic layered compound in which such a compound is dispersed in an organic solvent, and drying to form a hydrophobic inorganic layered compound layer 1; applying the liquid containing a hydrophilic inorganic layered compound dispersed in water onto the surface of the above layer 1, and drying to form a hydrophilic inorganic layered compound layer 2; further applying the above hydrophobic compound-containing liquid onto the surface of the layer 2; drying to form one more layer 1; and peeling the whole layered film from the base. Thereby, it is possible to prepare a three-layered inorganic compound film having the hydrophobic inorganic layered compound layers 1, 1 on both sides of the layer 2. COPYRIGHT: (C)2008,JPO&INPIT

Patent
12 Sep 2007
TL;DR: In this paper, an organic-inorganic compound ultraviolet detector and its preparation method is described, which is based on spincoating or dip coating the titanium dioxide sol on the obstruct layer.
Abstract: The invention discloses an organic-inorganic compound ultraviolet detector and its preparation method. Its preparation step is: 1) coating a obstruct material in the basis, drying, obtains the obstruct layer; 2) the 1-50% volume ratio of tetrabutyl titanate dissolves into the absolute ethyl alcohol, joins intermixture which is composed by the deionized water, the glacial aceticacid, the absolute ethyl alcohol, stirs, obtains the titanium dioxide sol; 3) spincoating or dip coating the titanium dioxide sol on the obstruct layer, drying, obtains the titanium dioxide layer; 4) put the organic matter by 1-50% load ratio density dissolves into the methylene chloride or dioxane, after joins film former, dip coating or spincoating on the titanium dioxide layer, drying, obtains the organic layer, makes the ultraviolet surveythe organic - inorganic compound component. This invention fully synthesized the organic material price inexpensive, structure easy adjust, can big area manufacture, and inorganic material good stability merit, its craft simple, was easy to realize, and effectively reduce the cost.

Patent
23 May 2007
TL;DR: In this paper, a combined layer install technique and surface gel-sol technique was used to produce inorganic compound nanometer tube, wherein it uses surface gel sol sol technique, the reaction between two kinds of function groups, and the electric adsorption reaction of two different materials to prepare several nanometer tubes; the removes one component to form single-component in organic compound porous nanometry tube; said two materials comprise the compound with alkoxy which is hydrolyzed into inorganic compounds, with hydrogen key, compound key, biological molecule, to form dual-component nanometric tube;
Abstract: The invention relates to a combined layer install technique and surface gel-sol technique, which are used to produce inorganic compound nanometer tube, wherein it uses surface gel-sol technique, the reaction between two kinds of function groups, and the electric adsorption reaction of two different materials to prepare several nanometer tubes; the removes one component to form single-component inorganic compound porous nanometer tube; said two materials comprise the compound with alkoxy which is hydrolyzed into inorganic compound, with hydrogen key, compound key, biological molecule, to form dual-component nanometer tube; removing the organic component, to obtain the inorganic compound porous nanometer tube The invention uses the organic which can be moved easily as template, to form the porous inorganic compound nanometer tube with high specific surface area and large aperture Said product can be used in catalysis and hydrogen storage

Patent
23 Jan 2007
TL;DR: In this article, a surface-treating agent is defined as a crystalline layered inorganic compound formed with an organic amine or an organic ammonium into a nanosheet.
Abstract: Disclosed is a surface-treating agent comprising a crystalline layered inorganic compound formed with an organic amine or an organic ammonium into a nanosheet, wherein the organic amine or organic ammonium is a polyfucntional organic amine or polyfunctional organic ammonium. The surface-treating agent is a nanosheet-dispersed sol-type non-chromate surface-treating agent which shows excellent corrosion resistance and coating-adhesiveness at a processed part and can form a stiff film even used in the manufacture of a precoated metal plate which is applicable to an electric appliance, an automotive product or the like which is required to have a strictly machined shape.

Patent
26 Jul 2007
TL;DR: In this article, the problem of providing a Pr-doped inorganic compound which facilitates a Pr doping into a matrix oxide was solved by substituting at least a part of at least one kind of substitutable ions, which are contained at a substitutable ion site in a matrix, by Pr.
Abstract: PROBLEM TO BE SOLVED: To provide a Pr-doped inorganic compound which facilitates a Pr doping into a matrix oxide. SOLUTION: The Pr-doped inorganic compound contains a solid solution having been formed by substitution of at least a part of at least one kind of substitutable ions, which are contained at a substitutable ion site in a matrix oxide, by Pr. The Pr-doped inorganic compound satisfies the condition represented by the formula: 0.91r2≤r1≤1.05r2 (wherein r1 represents the mean ionic radiuses of all of elements, including Pr, which elements constitute the substitutable ion site having been doped with Pr; and r2 represents the ionic radius of Pr). It is preferable that the substitutable ions contain La and/or Gd. COPYRIGHT: (C)2007,JPO&INPIT

Patent
02 Aug 2007
TL;DR: In this paper, the authors proposed an approach to provide an aromatic polycarbonate sheet or film which has an excellent secondary processability and is also endowed with functions derived from an inorganic compound such as electrical properties, light reflection properties and flame retardance.
Abstract: PROBLEM TO BE SOLVED: To provide an aromatic polycarbonate sheet or film which has an excellent secondary processability and is also endowed with functions derived from an inorganic compound such as electrical properties, light reflection properties and flame retardance. SOLUTION: The sheet or the film comprises 100 pts.wt. of (A) a polycarbonate or a resin mainly composed of an aromatic polycarbonate and 1-30 pts.wt. of (B) an inorganic compound. The content of air bubbles of the sheet or the film is less than 0.5%. COPYRIGHT: (C)2007,JPO&INPIT