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Intramolecular reaction
About: Intramolecular reaction is a research topic. Over the lifetime, 5015 publications have been published within this topic receiving 138213 citations.
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TL;DR: In this article, the Ferrier reaction was used to obtain (−)-Calystegine B2 from D-Glucose via Ferrier reactions followed by regiospecific ring enlargement of a polysubstituted cyclohexanone and intramolecular cyclisation of 4-aminocycloheptanone.
49 citations
49 citations
TL;DR: In this paper, the total synthesis of combretastatin D-2, a cytotoxic constituent of Combretum caffrum (Combretaceae), is detailed and is based on the implementation of a key intramolecular Ullmann macrocyclization reaction for formation of the cyclic 15-membered caffrane biaryl ether.
Abstract: The total synthesis of combretastatin D-2, a cytotoxic constituent of Combretum caffrum (Combretaceae), is detailed and is based on the implementation of a key intramolecular Ullmann macrocyclization reaction for formation of the cyclic 15-membered caffrane biaryl ether
49 citations
TL;DR: Construction d'un cyclopenta [a] pentalene carboxylate-3 d'ethyle precurseur de la corioline as discussed by the authors, a cyclopentina is constructed by the construction of cyclopenia.
Abstract: Construction d'un cyclopenta [a] pentalene carboxylate-3 d'ethyle precurseur de la corioline
49 citations
TL;DR: Par cyclisation intramoleculaire puis photoenolisation du [(methoxy-2 pyridyl-4]-5 benzo [c][2,7]naphtyridinemethanol-4 precurseur de l'amphimedine] as mentioned in this paper.
Abstract: Par cyclisation intramoleculaire puis photoenolisation du [(methoxy-«2» pyridyl-4) vinyl-2' anilino methyl]-5 oxazolecarboxylate-4 de methyle, on obtient le [methoxy-2 pyridyl-4]-5 benzo [c][2,7]naphtyridinemethanol-4 precurseur de l'amphimedine
49 citations