Topic
Intramolecular reaction
About: Intramolecular reaction is a research topic. Over the lifetime, 5015 publications have been published within this topic receiving 138213 citations.
Papers published on a yearly basis
Papers
More filters
TL;DR: N,N-Bis(dimethylsilyl) allylamines undergo intramolecular hydrosilation in the presence of Pt[{(CH 2 =CH)Me 2 Si} 2 O] 2 (0.2 mol %) to form four-membered cyclic compounds, 1-aza-2-silacyclobutane derivatives, which can be transformed into 2-amino alcohols by oxidation with 30% H 2 O 2 2 (KF and KHCO 3 ) as mentioned in this paper.
Abstract: N,N-Bis(dimethylsilyl) allylamines undergo intramolecular hydrosilation in the presence of Pt[{(CH 2 =CH)Me 2 Si} 2 O] 2 (0.2 mol %) to form four-membered cyclic compounds, 1-aza-2-silacyclobutane derivatives, which can be transformed into 2-amino alcohols by oxidation with 30% H 2 O 2 in the presence of KF and KHCO 3
47 citations
TL;DR: In this article, the authors proposed a method for the exo-dig cyclization of primary acetylenic alkyllithium carbocycles bearing a phenyl substituent on the triple bond.
47 citations
TL;DR: An efficient approach to rigid tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels-Alder (IMDA) cycloaddition of pyrrole is described.
Abstract: An efficient approach to rigid tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels−Alder (IMDA) cycloaddition of pyrrole is described. The one-pot Ugi four-component ...
47 citations
TL;DR: In this article, a short and enantioselective total synthesis of the neurotoxic alkaloid (+)-Anatoxin-a (1 ) from the L-pyroglutamic acid derivative 2 is described.
47 citations
TL;DR: In this article, a cyclisation du pentyne-5yl-1cyclopentene en tricyclo [6.3.0.0 4,8 ] undecene-1one-3 avec CO 2 (CO) 8 suivie de la conversion en bis norisocomene
Abstract: Preparation et cyclisation du pentyne-5yl-1cyclopentene en tricyclo [6.3.0.0 4,8 ] undecene-1one-3 avec CO 2 (CO) 8 suivie de la conversion en bis norisocomene
47 citations