Topic
Ionic conductivity
About: Ionic conductivity is a research topic. Over the lifetime, 19412 publications have been published within this topic receiving 519167 citations.
Papers published on a yearly basis
Papers
More filters
••
TL;DR: In this paper, a simple method was developed to deposit multiple layers of composites consisting of alternating layers of the P2Mo18O626- anion and large, multiply-charged cations such as Os(bpy)32+.
Abstract: The unusually strong, irreversible adsorption of monolayer quantities of the P2Mo18O626- anion on glassy carbon, highly ordered pyrolytic graphite, indium tin oxide, and gold-coated quartz electrodes was examined by electrochemical, spectroelectrochemical, and quartz crystal microgravimetric techniques. A very simple method was developed to deposit multiple layers of composites consisting of alternating layers of the P2Mo18O626- anion and large, multiply-charged cations such as Os(bpy)32+. The resulting deposit is stable and exhibits electroactivity from both of the components that reflects the structure and ionic conductivity of the solid multilayer.
215 citations
••
TL;DR: In this paper, a flexible composite solid electrolyte membrane consisting of inorganic solid particles (Li1.3Al0.3Ti1.7(PO4)3), polyethylene oxide (PEO), and boronized polyethylenes glycol (BPEG) is prepared and investigated.
Abstract: A flexible composite solid electrolyte membrane consisting of inorganic solid particles (Li1.3Al0.3Ti1.7(PO4)3), polyethylene oxide (PEO), and boronized polyethylene glycol (BPEG) is prepared and investigated. This membrane exhibits good stability against lithium dendrite, which can be attributed to its well-designed combination components: the compact inorganic lithium ion conducting layer provides the membrane with good mechanical strength and physically barricades the free growth of lithium dendrite; while the addition of planar BPEG oligomers not only disorganizes the crystallinity of the PEO domain, leading to good ionic conductivity, but also facilitates a “soft contact” between interfaces, which not only chemically enables homogeneous lithium plating/stripping on the lithium metal anode, but also reduces the polarization effects. In addition, by employing this membrane to a LiFePO4/Li cell and testing its galvanostatic cycling performances at 60 °C, capacities of 158.2 and 94.2 mA h g−1 are delivered at 0.1 C and 2 C, respectively.
215 citations
••
TL;DR: In this article, the phase formation of cubic tantalum substituted LLZTO ceramics was studied by X-ray powder diffraction, where Ta substitution was found to facilitate the formation of the cubic garnet modification at lower synthesis temperature.
214 citations
••
TL;DR: In this article, a detailed study on the local chemical nature of the thiophosphate building units within these materials was performed using Raman and 31P MAS NMR (Magic Angle Spinning- Nuclear Magnetic Resonance) spectroscopy.
Abstract: Motivated by the high lithium ion conductivities of lithium thiophosphate glasses, a detailed study is performed on the local chemical nature of the thiophosphate building units within these materials. Using Raman and 31P MAS NMR (Magic Angle Spinning – Nuclear Magnetic Resonance) spectroscopy, the continuous change from dominant P2S74− (di-tetrahedral) anions to PS43− (mono-tetrahedral) anions with increasing Li2S fraction in the (Li2S)x(P2S5)(100−x) glasses is observed. In addition, synchrotron pair distribution function analysis (PDF) of synchrotron X-ray total scattering data is employed to monitor in situ crystallization and phase evolution in this class of materials. Depending on the composition, different crystalline phases evolve, which possess different decomposition temperatures into less conducting phases. The results highlight the critical influence of the local anionic building units on the cation mobility and thermal stability, with PS43− tetrahedra forming the most thermally robust glass ceramics with the highest ionic conductivity.
214 citations
••
TL;DR: In this paper, the relationship between nonstoichiometry, electrical properties and diffusion of perovskite-type oxides, ABO3 (B = Al, Zr, Bi, Cr, Mn, Fe, Co), was reviewed to elucidate the characteristics of pervskite type electrode materials, La1-xSrxBO3.
214 citations