Showing papers on "Ionization published in 2022"

The Low-redshift Lyman Continuum Survey. II. New Insights into LyC Diagnostics

Abstract: The Lyman continuum (LyC) cannot be observed at the epoch of reionization (z ≳ 6) owing to intergalactic H i absorption. To identify LyC emitters (LCEs) and infer the fraction of escaping LyC, astronomers have developed various indirect diagnostics of LyC escape. Using measurements of the LyC from the Low-redshift Lyman Continuum Survey (LzLCS), we present the first statistical test of these diagnostics. While optical depth indicators based on Lyα, such as peak velocity separation and equivalent width, perform well, we also find that other diagnostics, such as the [O iii]/[O ii] flux ratio and star formation rate surface density, predict whether a galaxy is an LCE. The relationship between these galaxy properties and the fraction of escaping LyC flux suggests that LyC escape depends strongly on H i column density, ionization parameter, and stellar feedback. We find that LCEs occupy a range of stellar masses, metallicities, star formation histories, and ionization parameters, which may indicate episodic and/or different physical causes of LyC escape.

Chemical reaction monitoring by ambient mass spectrometry.

Abstract: Chemical reactions conducted in different media (liquid phase, gas phase, or surface) drive developments of versatile techniques for the detection of intermediates and prediction of reasonable reaction pathways. Without sample pretreatment, ambient mass spectrometry (AMS) has been applied to obtain structural information of reactive molecules that differ in polarity and molecular weight. Commercial ion sources (e.g., electrospray ionization, atmospheric pressure chemical ionization, and direct analysis in real-time) have been reported to monitor substrates and products by offline reaction examination. While the interception or characterization of reactive intermediates with short lifetime are still limited by the offline modes. Notably, online ionization technologies, with high tolerance to salt, buffer, and pH, can achieve direct sampling and ionization of on-going reactions conducted in different media (e.g., liquid phase, gas phase, or surface). Therefore, short-lived intermediates could be captured at unprecedented timescales, and the reaction dynamics could be studied for mechanism examinations without sample pretreatments. In this review, via various AMS methods, chemical reaction monitoring and mechanism elucidation for different classifications of reactions have been reviewed. The developments and advances of common ionization methods for offline reaction monitoring will also be highlighted.

Direct measurement of the ionization quenching factor of nuclear recoils in germanium in the keV energy range

Abstract: This article reports the measurement of the ionization quenching factor in germanium for nuclear recoil energies between 0.4 and 6.3 keV$_{nr}$. Precise knowledge of this factor in this energy range is relevant for coherent elastic neutrino-nucleus scattering and low mass dark matter searches with germanium-based detectors. Nuclear recoils were produced in a thin high-purity germanium target with a very low energy threshold via irradiation with monoenergetic neutron beams. The energy dependence of the ionization quenching factor was directly measured via kinematically constrained coincidences with surrounding liquid scintillator based neutron detectors. The systematic uncertainties of the measurements are discussed in detail. With measured quenching factors between 0.16 and 0.23 in the [0.4, 6.3] keV$_{nr}$ energy range, the data are compatible with the Lindhard theory with a parameter $k$ of 0.162 $\pm$ 0.004 (stat+sys).

Search for Dark-Matter-Nucleon Interactions via Migdal Effect with DarkSide-50.

Abstract: Dark matter elastic scattering off nuclei can result in the excitation and ionization of the recoiling atom through the so-called Migdal effect. The energy deposition from the ionization electron adds to the energy deposited by the recoiling nuclear system and allows for the detection of interactions of sub-GeV/c^{2} mass dark matter. We present new constraints for sub-GeV/c^{2} dark matter using the dual-phase liquid argon time projection chamber of the DarkSide-50 experiment with an exposure of (12 306±184) kg d. The analysis is based on the ionization signal alone and significantly enhances the sensitivity of DarkSide-50, enabling sensitivity to dark matter with masses down to 40 MeV/c^{2}. Furthermore, it sets the most stringent upper limit on the spin independent dark matter nucleon cross section for masses below 3.6 GeV/c^{2}.

Development of an ultra‐thin parallel plate ionization chamber for dosimetry in FLASH radiotherapy

Abstract: Abstract Background Conventional air ionization chambers (ICs) exhibit ion recombination correction factors that deviate substantially from unity when irradiated with dose per pulse magnitudes higher than those used in conventional radiotherapy. This fact makes these devices unsuitable for the dosimetric characterization of beams in ultra‐high dose per pulse as used for FLASH radiotherapy. Purpose We present the design, development, and characterization of an ultra‐thin parallel plate IC that can be used in ultra‐high dose rate (UHDR) deliveries with minimal recombination. Methods The charge collection efficiency (CCE) of parallel plate ICs was modeled through a numerical solution of the coupled differential equations governing the transport of charged carriers produced by ionizing radiation. It was used to find out the optimal parameters for the purpose of designing an IC capable of exhibiting a linear response with dose (deviation less than 1%) up to 10 Gy per pulse at 4 μs pulse duration. As a proof of concept, two vented parallel plate IC prototypes have been built and tested in different ultra‐high pulse dose rate electron beams. Results It has been found that by reducing the distance between electrodes to a value of 0.25 mm it is possible to extend the dose rate operating range of parallel plate ICs to ultra‐high dose per pulse range, at standard voltage of clinical grade electrometers, well into several Gy per pulse. The two IC prototypes exhibit behavior as predicted by the numerical simulation. One of the so‐called ultra‐thin parallel plate ionization chamber (UTIC) prototypes was able to measure up to 10 Gy per pulse, 4 μs pulse duration, operated at 300 V with no significant deviation from linearity within the uncertainties (ElectronFlash Linac, SIT). The other prototype was tested up to 5.4 Gy per pulse, 2.5 μs pulse duration, operated at 250 V with CCE higher than 98.6% (Metrological Electron Accelerator Facility, MELAF at Physikalisch‐Technische Bundesanstalt, PTB). Conclusions This work demonstrates the ability to extend the dose rate operating range of ICs to ultra‐high dose per pulse range by reducing the spacing between electrodes. The results show that UTICs are suitable for measurement in UHDR electron beams.

Photoionization of the aqueous phase: clusters, droplets and liquid jets

Abstract: This perspective article reviews specific challenges associated with photoemission spectroscopy of bulk liquid water, aqueous solutions, water droplets and water clusters. The main focus lies on retrieving accurate energetics and photoelectron angular information from measured photoemission spectra, and on the question how these quantities differ in different aqueous environments. Measured photoelectron band shapes, vertical binding energies (ionization energies), and photoelectron angular distributions are influenced by various phenomena. We discuss the influences of multiple energy-dependent electron scattering in aqueous environments, and we discuss different energy referencing methods, including the application of a bias voltage to access absolute energetics of solvent and solute. Recommendations how to account for or minimize the influence of electron scattering are provided. The example of the hydrated electron in different aqueous environments illustrates how one can account for electron scattering, while reliable methods addressing parasitic potentials and proper energy referencing are demonstrated for ionization from the outermost valence orbital of neat liquid water.

Influence of the magnetic field on the discharge physics of a high power impulse magnetron sputtering discharge

Abstract: The magnetic field is a key feature that distinguishes magnetron sputtering from simple diode sputtering. It effectively increases the residence time of electrons close to the cathode surface and by that increases the energy efficiency of the discharge. This becomes apparent in high power impulse magnetron sputtering (HiPIMS) discharges, as small changes in the magnetic field can result in large variations in the discharge characteristics, notably the peak discharge current and/or the discharge voltage during a pulse. Here, we analyze the influence of the magnetic field on the electron density and temperature, how the discharge voltage is split between the cathode sheath and the ionization region, and the electron heating mechanism in a HiPIMS discharge. We relate the results to the energy efficiency of the discharge and discuss them in terms of the probability of target species ionization. The energy efficiency of the discharge is related to the fraction of pulse power absorbed by the electrons, and favors Ohmic heating of electrons in the ionization region as opposed to electron energization in the sheath. We find that the electron density and ionization probability of the sputtered species depend largely on the discharge current. The results suggest ways to adjust electron density and electron temperature using the discharge current and the magnetic field, respectively, and how these influence the ionization probability.

Chromospheric extension of the MURaM code

Abstract: Context. Detailed numerical models of chromosphere and corona are required to understand the heating of the solar atmosphere. An accurate treatment of the solar chromosphere is complicated by the effects arising from Non Local Thermodynamic Equilibrium (NLTE) radiative transfer. A small number of strong, highly scattering lines dominate the cooling and heating in the chromosphere. Additionally, the recombination times of ionised hydrogen are longer than the dynamical timescales, requiring a non-equilibrium (NE) treatment of hydrogen ionisation. Aims. We describe a set of necessary additions to the MURaM code so that it might handle some of the important NLTE effects. We investigate the impact on models of the solar chromosphere caused by NLTE and NE effects in radiation magnetohydrodynamic (rMHD) simulations of the solar atmosphere. Methods. The MURaM code was extended to include the physical process required for accurate simulation of the solar chromosphere, as implemented in the Bifrost code. This includes a time-dependent treatment of hydrogen ionisation, a scattering multi-group radiation transfer scheme and approximations for NLTE radiative cooling. Results. The inclusion of NE and NLTE physics has a large impact on the structure of the chromosphere; the NE treatment of hydrogen ionisation leads to a higher ionisation fraction and enhanced populations in the first excited state throughout cold inter-shock regions of the chromosphere. Additionally this prevents hydrogen ioniation from buffering energy fluctuations, leading to hotter shocks and cooler inter-shock regions. The hydrogen populations in the ground and first excited state are enhanced by 10 2 − 10 3 in the upper chromosphere and up to 10 9 near the transition region. Conclusions. Including the necessary NLTE physics leads to significant differences in chromospheric structure and dynamics. The thermodynamics and hydrogen populations calculated using the extended version of the MURaM code are consistent with previous non-equilibrium simulations. The electron number and temperature calculated using the non-equilibrium treatment of the chromosphere are required to accurately synthesise chromospheric spectral lines.

Attosecond spectroscopy for the investigation of ultrafast dynamics in atomic, molecular and solid-state physics

Abstract: Since the first demonstration of the generation of attosecond pulses (1 as = 10−18 s) in the extreme-ultraviolet spectral region, several measurement techniques have been introduced, at the beginning for the temporal characterization of the pulses, and immediately after for the investigation of electronic and nuclear ultrafast dynamics in atoms, molecules and solids with unprecedented temporal resolution. The attosecond spectroscopic tools established in the last two decades, together with the development of sophisticated theoretical methods for the interpretation of the experimental outcomes, allowed to unravel and investigate physical processes never observed before, such as the delay in photoemission from atoms and solids, the motion of electrons in molecules after prompt ionization which precede any notable nuclear motion, the temporal evolution of the tunneling process in dielectrics, and many others. This review focused on applications of attosecond techniques to the investigation of ultrafast processes in atoms, molecules and solids. Thanks to the introduction and ongoing developments of new spectroscopic techniques, the attosecond science is rapidly moving towards the investigation, understanding and control of coupled electron–nuclear dynamics in increasingly complex systems, with ever more accurate and complete investigation techniques. Here we will review the most common techniques presenting the latest results in atoms, molecules and solids.

Spontaneous Formation of Hydrogen Peroxide in Water Microdroplets.

Abstract: There is accumulating evidence that many chemical reactions are accelerated by several orders of magnitude in micrometer-sized aqueous or organic liquid droplets compared to their corresponding bulk liquid phase. However, the molecular origin of the enhanced rates remains unclear as in the case of spontaneous appearance of 1 μM hydrogen peroxide in water microdroplets. In this Letter, we consider the range of ionization energies and whether interfacial electric fields of a microdroplet can feasibly overcome the high energy step from hydroxide ions (OH-) to hydroxyl radicals (OH•) in a primary H2O2 mechanism. We find that the vertical ionization energies (VIEs) of partially solvated OH- ions are greatly lowered relative to the average VIE in the bulk liquid, unlike the case of the Cl- anion which shows no reduction in the VIEs regardless of solvation environment. Overall reduced hydrogen-bonding and undercoordination of OH- are structural features that are more readily present at the air-water interface, where the energy scale for ionization can be matched by statistically probable electric field values.

Ionization of gravitational atoms

Abstract: Superradiant instabilities may create clouds of ultralight bosons around rotating black holes, forming so-called “gravitational atoms“. It was recently shown that the presence of a binary companion can induce resonant transitions between bound states of these clouds, whose backreaction on the binary’s orbit leads to characteristic signatures in the emitted gravitational waves. In this work, we show that the interaction with the companion can also trigger transitions from bound to unbound states of the cloud—a process that we refer to as “ionization” in analogy with the photoelectric effect in atomic physics. The orbital energy lost in the process overwhelms the losses due to gravitational wave emission and contains sharp features carrying information about the energy spectrum of the cloud. Moreover, we also show that if the companion is a black hole, then the part of the cloud impinging on the event horizon will be absorbed. This “accretion” leads to a significant increase of the companion’s mass, which alters the dynamical evolution and ensuing waveform of the binary. We argue that a combined treatment of resonances, ionization, and accretion is crucial to discover and characterize gravitational atoms with upcoming gravitational-wave detectors.9 MoreReceived 1 March 2022Accepted 3 June 2022DOI:https://doi.org/10.1103/PhysRevD.105.115036© 2022 American Physical SocietyPhysics Subject Headings (PhySH)Research AreasClassical black holesGravitational wavesHypothetical particle physics modelsParticle dark matterGravitation, Cosmology & AstrophysicsParticles & Fields

EMPRESS. V. Metallicity Diagnostics of Galaxies over 12 + log(O/H) ≃ 6.9–8.9 Established by a Local Galaxy Census: Preparing for JWST Spectroscopy

Abstract: We present optical-line gas metallicity diagnostics established by the combination of local SDSS galaxies and the largest compilation of extremely metal-poor galaxies (EMPGs) including new EMPGs identified by the Subaru EMPRESS survey. A total of 103 EMPGs are included, covering a large parameter space of magnitude (M i = −19 to −7) and Hβ equivalent width (10–600 Å), i.e., wide ranges of stellar mass and star formation rate. Using reliable metallicity measurements from the direct method for these galaxies, we derive the relationships between strong optical-line ratios and gas-phase metallicity over the range of 12+log(O/H) ≃ 6.9–8.9, corresponding to 0.02–2 solar metallicity Z ⊙. We confirm that the R23 index, ([O iii]+[O ii])/Hβ, is the most accurate metallicity indicator with a metallicity uncertainty of 0.14 dex over the range among various popular metallicity indicators. The other metallicity indicators show large scatters in the metal-poor range (≲0.1 Z ⊙). It is explained by our CLOUDY photoionization modeling that, unlike the R23 index, the other metallicity indicators do not use a sum of singly and doubly ionized lines and cannot trace both low- and high-ionization gas. We find that the accuracy of the metallicity indicators is significantly improved if one uses Hβ equivalent width measurements that tightly correlate with ionization states. In this work, we also present the relation of physical properties with the UV-continuum slope β and ionization production rate ξ ion derived with GALEX data for the EMPGs and provide local anchors of galaxy properties together with the optical-line metallicity indicators that are available in the form of a machine-readable table and useful for forthcoming JWST spectroscopic studies.

Cosmic rays in molecular clouds probed by H2 rovibrational lines. Perspectives for the James Webb Space Telescope

Abstract: Context. Low-energy cosmic rays (<1 TeV) play a fundamental role in the chemical and dynamical evolution of molecular clouds, as they control the ionisation, dissociation, and excitation of H2. Their characterisation is therefore important both for the interpretation of observations and for the development of theoretical models. However, the methods used so far for estimating the cosmic-ray ionisation rate in molecular clouds have several limitations due to uncertainties in the adopted chemical networks. Aims. We refine and extend a previously proposed method to estimate the cosmic-ray ionisation rate in molecular clouds by observing rovibrational transitions of H2 at near-infrared wavelengths, which are mainly excited by secondary cosmic-ray electrons. Methods. Combining models of interstellar cosmic-ray propagation and attenuation in molecular clouds with the rigorous calculation of the expected secondary electron spectrum and updated electron-H2 excitation cross sections, we derive the intensity of the four H2 rovibrational transitions observable in cold dense gas: (1−0)O(2), (1−0)Q(2), (1−0)S(0), and (1−0)O(4). Results. The proposed method allows the estimation of the cosmic-ray ionisation rate for a given observed line intensity and H2 column density. We are also able to deduce the shape of the low-energy cosmic-ray proton spectrum impinging upon the molecular cloud. In addition, we present a look-up plot and a web-based application that can be used to constrain the low-energy spectral slope of the interstellar cosmic-ray proton spectrum. We finally comment on the capability of the James Webb Space Telescope to detect these near-infrared H2 lines, which will make it possible to derive, for the first time, spatial variation in the cosmic-ray ionisation rate in dense gas. Besides the implications for the interpretation of the chemical-dynamic evolution of a molecular cloud, it will finally be possible to test competing models of cosmic-ray propagation and attenuation in the interstellar medium, as well as compare cosmic-ray spectra in different Galactic regions.

Origin of the complex main and satellite features in Fe 2p XPS of Fe2O3.

Abstract: Although the origin and assignment of the complex XPS features of the cations in ionic compounds has been the subject of extensive theoretical work, agreement with experimental observations remains insufficient for unambiguous interpretation. This paper presents a rigorous ab initio treatment of the main and satellite features in the Fe 2p XPS of Fe2O3. This has been possible using a unique methodology for the selection of orbitals that are used to form the ionic wavefunctions. This orbital selection makes it possible to treat both the angular momentum coupling of the open shell core and valence electrons as well the shake excitations from the closed shell orbitals associated with the O ligands into the valence open shell orbitals associated with the Fe 3d shell. This allows the character of the ionic states in terms of the occupations of the open shell core and valence orbitals and of the contributions of 2p1/2 and 2p3/2 ionization to the XPS intensities to be determined. Our analysis gives strong evidence that many body effects are essential for a correct description of the ionic states and, in general the states cannot be described by a single configuration over the open shell orbitals. An important consequence is that the Fe 2p XPS intensity in most of the features arises from small contributions from the ionization to many, tens to hundreds, of often unresolved ionic states. While the usual understanding of the lower binding energy main and satellite features as being dominantly from 2p3/2 ionization is confirmed, this is not the case for the higher binding energy features where 2p1/2 and 2p3/2 ionization and shake excitations in the valence space mix strongly. Furthermore, we have been able to show that a very large fraction, 88%, of the total Fe 2p XPS intensity is contained in a relatively small binding energy range of ∼35 eV. This is relevant if one wants to extract the stoichiometry of Fe2O3 from Fe 2p/O 1s intensity ratios. Similar considerations about the importance of many-body effects are likely to be relevant for other ionic compounds as well.

BASS. XXVIII. Near-infrared Data Release 2: High-ionization and Broad Lines in Active Galactic Nuclei

Abstract: We present the BAT AGN Spectroscopic Survey (BASS) Near-infrared Data Release 2 (DR2), a study of 168 nearby ( z¯=0.04 , z < 0.6) active galactic nuclei (AGN) from the all-sky Swift Burst Array Telescope X-ray survey observed with the Very Large Telescope (VLT)/X-shooter in the near-infrared (NIR; 0.8–2.4 μm). We find that 49/109 (45%) Seyfert 2 and 35/58 (60%) Seyfert 1 galaxies observed with VLT/X-shooter show at least one NIR high-ionization coronal line (CL; ionization potential χ > 100 eV). Comparing the emission of the [Si vi] λ1.9640 CL with the X-ray emission for the DR2 AGN, we find a significantly tighter correlation, with a lower scatter (0.37 dex) than that for the optical [O iii] λ5007 line (0.71 dex). We do not find any correlation between CL emission and the X-ray photon index Γ. We find a clear trend of line blueshifts with increasing ionization potential in several CLs, such as [Si vi] λ1.9640, [Si x] λ1.4300, [S viii] λ0.9915, and [S ix] λ1.2520, indicating the radial structure of the CL region. Finally, we find a strong underestimation bias in black hole mass measurements of Sy 1.9 using broad Hα due to the presence of significant dust obscuration. In contrast, the broad Paα and Paβ emission lines are in agreement with the M–σ relation. Based on the combined DR1 and DR2 X-shooter sample, the NIR BASS sample now comprises 266 AGN with rest-frame NIR spectroscopic observations, the largest set assembled to date.

Filming movies of attosecond charge migration in single molecules with high harmonic spectroscopy

Abstract: Abstract Electron migration in molecules is the progenitor of chemical reactions and biological functions after light-matter interaction. Following this ultrafast dynamics, however, has been an enduring endeavor. Here we demonstrate that, by using machine learning algorithm to analyze high-order harmonics generated by two-color laser pulses, we are able to retrieve the complex amplitudes and phases of harmonics of single fixed-in-space molecules. These complex dipoles enable us to construct movies of laser-driven electron migration after tunnel ionization of N 2 and CO 2 molecules at time steps of 50 attoseconds. Moreover, the angular dependence of the migration dynamics is fully resolved. By examining the movies, we observe that electron holes do not just migrate along the laser polarization direction, but may swirl around the atom centers. Our result establishes a general scheme for studying ultrafast electron dynamics in molecules, paving a way for further advance in tracing and controlling photochemical reactions by femtosecond lasers.

Strong Lyman-α emission in an overdense region at <i>z</i> = 6.8: a very large (<i>R</i> ∼ 3 physical Mpc) ionized bubble in COSMOS?

Abstract: ABSTRACT Our understanding of reionization has advanced considerably over the past decade, with several results now demonstrating that the intergalactic medium transitioned from substantially neutral at z = 7 to largely reionized at z = 6. However, little remains known about the sizes of ionized bubbles at z ≳ 7 as well as the galaxy overdensities which drive their growth. Fortunately, rest-ultraviolet (UV) spectroscopic observations offer a pathway towards characterizing these ionized bubbles thanks to the resonant nature of Lyman-alpha photons. In a previous work, we presented Ly α detections from three closely separated Lyman-break galaxies at z ≃ 6.8, suggesting the presence of a large (R &gt; 1 physical Mpc) ionized bubble in the 1.5 deg2 COSMOS field. Here, we present new deep Ly α spectra of 10 UV-bright ($\mathrm{\mathit{ M}}_{\mathrm{UV}}^{} \le -20.4$) z ≃ 6.6–6.9 galaxies in the surrounding area, enabling us to better characterize this potential ionized bubble. We confidently detect (S/N &gt; 7) Ly α emission at z = 6.701–6.882 in nine of ten observed galaxies, revealing that the large-scale volume spanned by these sources (characteristic radius R = 3.2 physical Mpc) traces a strong galaxy overdensity (N/〈N〉 ≳ 3). Our data additionally confirm that the Ly α emission of UV-bright galaxies in this volume is significantly enhanced, with 40 per cent (4/10) showing strong Ly α emission (equivalent width &gt;25 Å) compared to the 8–9 per cent found on average at z ∼ 7. The median Ly α equivalent width of our observed galaxies is also ≈2 times that typical at z ∼ 7, consistent with expectations if a very large (R ∼ 3 physical Mpc) ionized bubble is allowing the Ly α photons to cosmologically redshift far into the damping wing before encountering H i.

Magnetic-Field Effect in High-Order Above-Threshold Ionization

Abstract: We experimentally and theoretically investigate the influence of the magnetic component of an electromagnetic field on high-order above-threshold ionization of xenon atoms driven by ultrashort femtosecond laser pulses. The nondipole shift of the electron momentum distribution along the light-propagation direction for high energy electrons beyond the 2U_{p} classical cutoff is found to be vastly different from that below this cutoff, where U_{p} is the ponderomotive potential of the driving laser field. A local minimum structure in the momentum dependence of the nondipole shift above the cutoff is identified for the first time. With the help of classical and quantum-orbit analysis, we show that large-angle rescattering of the electrons strongly alters the partitioning of the photon momentum between electron and ion. The sensitivity of the observed nondipole shift to the electronic structure of the target atom is confirmed by three-dimensional time-dependent Schrödinger equation simulations for different model potentials. Our work paves the way toward understanding the physics of extreme light-matter interactions at long wavelengths and high electron kinetic energies.

Multiphoton ionization of standard optical fibers

Abstract: 1Department of Information Engineering, Electronics and Telecommunications, Sapienza University of Rome, Via Eudossiana 18, 00184 Rome, Italy 2Physics Department and STAR infrastructure, University of Calabria, I-87036 Arcavacata di Rende, CS, Italy 3Department of Information Engineering, University of Brescia, Via Branze 38, 25123 Brescia, Italy 4Université de Limoges, XLIM, UMR CNRS 7252, 123 Avenue A. Thomas, 87060 Limoges, France 5Institute of Automation and Electrometry, SB RAS, Novosibirsk 630090, Russia 6Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia †These authors have contributed equally *Corresponding author: mario.ferraro@uniroma1.it

Changing-look Event in NGC 3516: Continuum or Obscuration Variability?

Abstract: Abstract The Seyfert-1 galaxy NGC 3516 has undergone major spectral changes in recent years. In 2017 we obtained Chandra, NuSTAR, and Swift observations during its new low-flux state. Using these observations, we model the spectral energy distribution (SED) and the intrinsic X-ray absorption, and compare the results with those from historical observations taken in 2006. We thereby investigate the effects of the changing-look phenomenon on the accretion-powered radiation and the ionized outflows. Compared to its normal high-flux state in 2006, the intrinsic bolometric luminosity of NGC 3516 was lower by a factor of 4–8 during 2017. Our SED modeling shows a significant decline in the luminosity of all the continuum components from the accretion disk and the X-ray source. As a consequence, the reprocessed X-ray emission lines have also become fainter. The Swift monitoring of NGC 3516 shows remarkable X-ray spectral variability on short (weeks) and long (years) timescales. We investigate whether this variability is driven by obscuration or the intrinsic continuum. We find that the new low-flux spectrum of NGC 3516, and its variability, do not require any new or variable obscuration, and instead can be explained by changes in the ionizing SED that result in the lowering of the ionization of the warm-absorber outflows. This in turn induces enhanced X-ray absorption by the warm-absorber outflows, mimicking the presence of new obscuring gas. Using the response of the ionized regions to the SED changes, we place constraints on their densities and locations.

Charged particle kinetics and gas heating in CO2 microwave plasma contraction: comparisons of simulations and experiments

Abstract: This work investigates kinetics and transport of CO2 microwave plasmas through simulation results from a 1D radial fluid model and experiments. Simulation results are validated against spatially resolved measurements of neutral species mole fractions, gas temperature, electron number density and temperature obtained by means of Thomson and Raman scattering diagnostics, yielding good agreement. As such, the model is used to complement experiments and assess the main chemical reactions, mass and energy transport in diffuse and contracted plasma regimes. From model results, it is found that, as pressure is raised, the inhomogeneous gas heating induces significant gradients in neutral and charged species mole fractions profiles. Moreover, the transition from diffuse to contracted plasma is accompanied by a change in the dominant charged species, which favours electron–ion recombination over dissociative attachment. Associative ionization rates increase in the plasma core from diffuse to contracted regime. These processes contribute to the increase in the peak electron number density with pressure, that determines radial plasma contraction.

On the characteristic features of ionization in QED environments.

Abstract: The ionization of molecular systems is important in many chemical processes, such as electron transfer and hot electron injection. Strong coupling between molecules and quantized fields (e.g., inside optical cavities) represents a new promising way to modify molecular properties in a non-invasive way. Recently, strong light-matter coupling has shown the potential to significantly improve the rates of hot electron driven processes, for instance, in water splitting. In this paper, we demonstrate that inside an optical cavity, the residual interaction between an outgoing free electron and the vacuum field is significant. We further show that since the quantized field is also interacting with the ionized molecule, the free electron and the molecular system are correlated. We develop a theoretical framework to account for the field induced correlation and show that the interaction between the free electron and the field, free electron-field interaction, has sizable effects on the ionization potential of typical organic molecules.

Isolating Attosecond Electron Dynamics in Molecules where Nuclei Move Fast.

Abstract: Capturing electronic dynamics in real time has been the ultimate goal of attosecond science since its beginning. While for atomic targets the existing measurement techniques have been thoroughly validated, in molecules there are open questions due to the inevitable copresence of moving nuclei, which are not always mere spectators of the phototriggered electron dynamics. Previous work has shown that not only can nuclear motion affect the way electrons move in a molecule, but it can also lead to contradictory interpretations depending on the chosen experimental approach. In this Letter we investigate how nuclear motion affects and eventually distorts the electronic dynamics measured by using two of the most popular attosecond techniques, reconstruction of attosecond beating by interference of two-photon transitions and attosecond streaking. Both methods are employed, in combination with ab initio theoretical calculations, to retrieve photoionization delays in the dissociative ionization of H_{2}, H_{2}→H^{+}+H+e^{-}, in the region of the Q_{1} series of autoionizing states, where nuclear motion plays a prominent role. We find that the experimental reconstruction of attosecond beating by interference of two-photon transitions results are very sensitive to bond softening around the Q_{1} threshold (27.8 eV), even at relatively low infrared (IR) intensity (I_{0}∼1.4×10^{11} W/cm^{2}), due to the long duration of the probe pulse that is inherent to this technique. Streaking, on the other hand, seems to be a better choice to isolate attosecond electron dynamics, since shorter pulses can be used, thus reducing the role of bond softening. This conclusion is supported by very good agreement between our streaking measurements and the results of accurate theoretical calculations. Additionally, the streaking technique offers the necessary energy resolution to accurately retrieve the fast-oscillating phase of the photoionization matrix elements, an essential requirement for extending this technique to even more complicated molecular targets.

Intermolecular Coulombic Decay in Liquid Water

Abstract: We report the first observation of intermolecular Coulombic decay (ICD) in liquid water following inner-valence ionization. By combining a monochromatized table-top high-harmonic source with a liquid micro-jet, we recorded electron-electron coincidence spectra at two photon energies that identify the ICD electrons, together with the photoelectrons originating from the 2a1 inner-valence band of liquid water. Our results confirm the importance of ICD as a source of low-energy electrons in bulk liquid water and provide quantitative results for modeling the velocity distribution of the slow electrons that are thought to dominate radiation damage in aqueous environments.

Foundations of physical vapor deposition with plasma assistance

Abstract: Physical vapor deposition (PVD) refers to the removal of atoms from a solid or a liquid by physical means, followed by deposition of those atoms on a nearby surface to form a thin film or coating. Various approaches and techniques are applied to release the atoms including thermal evaporation, electron beam evaporation, ion-driven sputtering, laser ablation, and cathodic arc-based emission. Some of the approaches are based on a plasma discharge, while in other cases the atoms composing the vapor are ionized either due to the release of the film-forming species or they are ionized intentionally afterward. Here, a brief overview of the various PVD techniques is given, while the emphasis is on sputtering, which is dominated by magnetron sputtering, the most widely used technique for deposition of both metallic and compound thin films. The advantages and drawbacks of the various techniques are discussed and compared.

Lorentz-force shifts in strong-field ionization with mid-infrared laser fields

Abstract: In the past, the ionization of atoms and molecules by strong, mid-infrared (IR) laser fields has attracted recurrent interest. Measurements with different IR pulses have demonstrated the crucial role of the magnetic field on the electron dynamics, classically known as the Lorentz force ${\mathbf{F}}_{L}=q\phantom{\rule{0.16em}{0ex}}(\mathsc{E}+\mathbf{v}\ifmmode\times\else\texttimes\fi{}\mathsc{B})$, that acts upon all particles with charge $q$ in motion. These measurements also require the advancement of theory beyond the presently applied methods. In particular, the strong-field approximation (SFA) is typically based on the dipole approximation alone and neglects both the magnetic field and the spatial dependence of the driving electric field. Here we show and discuss that several, if not most, observations from strong-field ionization experiments with mid-IR fields can be quantitatively explained within the framework of SFA, if the Lorentz force is taken into account by nondipole Volkov states in the formalism. The details of such a treatment are analyzed for the (peak) shifts of the polar-angle distribution of above-threshold ionization photoelectrons along the laser propagation, the steering of electron momenta by two not quite collinear laser beams, or the enhanced momentum transfer to photoelectrons in standing-light fields. Moreover, the same formalism promises to explain the generation of high harmonics and other strong-field rescattering phenomena when driven by mid-IR laser fields. All these results show how strong-field processes can be understood on equal footings within the SFA, if one goes beyond the commonly applied dipole approximation.

GOALS-JWST: Resolving the Circumnuclear Gas Dynamics in NGC 7469 in the Mid-infrared

Abstract: The nearby, luminous infrared galaxy NGC 7469 hosts a Seyfert nucleus with a circumnuclear star-forming ring and is thus the ideal local laboratory for investigating the starburst–AGN (active galactic nucleus) connection in detail. We present integral-field observations of the central 1.3 kpc region in NGC 7469 obtained with the JWST Mid-InfraRed Instrument. Molecular and ionized gas distributions and kinematics at a resolution of ∼100 pc over the 4.9–7.6 μm region are examined to study the gas dynamics influenced by the central AGN. The low-ionization [Fe ii] λ5.34 μm and [Ar ii] λ6.99 μm lines are bright on the nucleus and in the starburst ring, as opposed to H2 S(5) λ6.91 μm, which is strongly peaked at the center and surrounding ISM. The high-ionization [Mg v] line is resolved and shows a broad, blueshifted component associated with the outflow. It has a nearly face-on geometry that is strongly peaked on the nucleus, where it reaches a maximum velocity of −650 km s−1, and extends about 400 pc to the east. Regions of enhanced velocity dispersion in H2 and [Fe ii] ∼ 180 pc from the AGN that also show high L(H2)/L(PAH) and L([Fe ii])/L(Pfα) ratios to the W and N of the nucleus pinpoint regions where the ionized outflow is depositing energy, via shocks, into the dense interstellar medium between the nucleus and the starburst ring. These resolved mid-infrared observations of the nuclear gas dynamics demonstrate the power of JWST and its high-sensitivity integral-field spectroscopic capability to resolve feedback processes around supermassive black holes in the dusty cores of nearby luminous infrared galaxies.

Ionization Waves (Striations) in a Low-Current Plasma Column Revisited

Abstract: The formation of striations in a low temperature plasma column has been known for more than a century and a considerable number of papers have been devoted to experimental and theoretical studies of these striations. Due to the large variety of regimes and to the complexity of the physics involved, our understanding of these instabilities is still limited. In this presentation we focus on the formation of striations under low current and low pressure conditions, i.e. when stepwise ionization or Coulomb collisions are negligible.

Quantification of surface charging memory effect in ionization wave dynamics

Abstract: The dynamics of ionization waves (IWs) in atmospheric pressure discharges is fundamentally determined by the electric polarity (positive or negative) at which they are generated and by the presence of memory effects, i.e. leftover charges and reactive species that influence subsequent IWs. This work examines and compares positive and negative IWs in pulsed plasma jets (1 [Formula: see text]s on-time), showing the difference in their nature and the different resulting interaction with a dielectric BSO target. For the first time, it is shown that a surface charging memory effect is produced, i.e. that a significant amount of surface charges and electric field remain in the target in between discharge pulses (200 [Formula: see text]s off-time). This memory effect directly impacts IW dynamics and is especially important when using negative electric polarity. The results suggest that the remainder of surface charges is due to the lack of charged particles in the plasma near the target, which avoids a full neutralization of the target. This demonstration and the quantification of the memory effect are possible for the first time by using an unique approach, assessing the electric field inside a dielectric material through the combination of an advanced experimental technique called Mueller polarimetry and state-of-the-art numerical simulations.

Effect of the electric field profile on the accuracy of E-FISH measurements in ionization waves

Abstract: Abstract Electric field induced second harmonic (E-FISH) generation has emerged as a versatile tool for measuring absolute electric field strengths in time-varying, non-equilibrium plasmas and gas discharges. Yet recent work has demonstrated that the E-FISH signal, when produced with tightly focused laser beams, exhibits a strong dependence on both the length and shape of the applied electric field profile (along the axis of laser beam propagation). In this paper, we examine the effect of this dependence more meaningfully, by predicting what an E-FISH experiment would measure in a plasma, using 2D axisymmetric numerical fluid simulations as the true value. A pin-plane nanosecond discharge at atmospheric pressure is adopted as the test configuration, and the electric field evolution during the propagation of the ionization wave (IW) is specifically analysed. We find that the various phases of this evolution (before and up to the front arrival, immediately behind the front and after the connection to the grounded plane) are quite accurately described by three unique electric field profile shapes, each of which produces a different response in the E-FISH signal. As a result, the accuracy of an E-FISH measurement is generally predicted to be comparable in the first and third phases of the IW evolution, and significantly poorer in the second (intermediate) phase. Fortunately, even though the absolute error in the field strength at certain time instants could be large, the overall shape of the field evolution curve is relatively well captured by E-FISH. Guided by the simulation results, we propose a procedure for estimating the error in the initial phase of the IW development, based on the presumption that the starting field profile mirrors that of its corresponding Laplacian conditions before evolving further. We expect that this approach may be readily generalized and applicable to other IW problems or phenomena, thus extending the utility of the E-FISH diagnostic.