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ITIES

About: ITIES is a research topic. Over the lifetime, 401 publications have been published within this topic receiving 10985 citations.


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Journal ArticleDOI
TL;DR: The faradaic and non-faradaic processes taking place at the interface of two immiscible electrolyte solutions have been compared with analogous processes occurring at interface metal-electrolyte solution as discussed by the authors.

336 citations

Journal ArticleDOI
TL;DR: In this paper, the kinetics of electron transfer and ion transfer at the interface between two immiscible electrolyte solutions (ITIES) were probed directly by scanning electrochemical microscopy (SECM).
Abstract: The kinetics of the electron transfer and ion transfer at the interface between two immiscible electrolyte solutions (ITIES) were probed directly by scanning electrochemical microscopy (SECM). The liquid/liquid (Le., waterhitrobenzene) interface appeared to be sharp and wave-free on the submicrometer scale. The use of SECM allowed the electron transfer between ferrocene species in nitrobenzene and other redox species in the aqueous phase to be quantitatively separated from the ion transfer processes. The rate constants were extracted from the dependence of the steady-state current at a micrometer-sized tip electrode on the distance between the tip and the phase boundary by comparison to theoretical working curves. In some experiments, the ultramicroelectrode tip penetrating the ITIES trapped a micrometer-thick layer of water inside the nitrobenzene, forming a thin-layer cell.

310 citations

Journal ArticleDOI
TL;DR: An inventory of theoretical and methodological concepts in electrochemistry at the interface between two immiscible electrolyte solutions (ITIES) is provided in this paper, together with recommendations for the preferred symbols, terminology, and nomenclature.
Abstract: This document provides an inventory of theoretical and methodological concepts in electrochemistry at the interface between two immiscible electrolyte solutions (ITIES) Definitions of basic relationships are given, together with recommendations for the preferred symbols, terminology, and nomenclature Methods of study of ITIES are briefly described, current experimental problems are indicated, and representative experimental data are shown The practical applications of electrochemistry at ITIES are summarized

282 citations

Journal ArticleDOI
TL;DR: In this article, a review of charge transfer reactions in biphasic systems is presented, with some emphasis on certain studies that marked the advances of electrochemistry at ITIES and that have been presented in large majority at the ISE meetings during the last two decades.

271 citations

Journal ArticleDOI
TL;DR: In this article, the authors reviewed recent advances in the electrochemistry at the interface between two immiscible electrolyte solutions (ITIES) and discussed the polarizability of ITIES, ion transfer across the interface, facilitated transfer of ions, adsorption at the oil/water interface, electron transfer and applications to ion-selective electrodes, solvent extraction and membrane phenomena.

258 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
202310
202215
202113
20207
20197
201813