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Landau theory

About: Landau theory is a research topic. Over the lifetime, 2882 publications have been published within this topic receiving 57078 citations.


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TL;DR: Using the Ginzburg criterion, it is demonstrated that the width of the critical region associated with the smectic-A-smectic C transition is dependent on the observable studied, which affords an explanation of the results obtained for terephthal-bis-p-p'-butylaniline.
Abstract: Using the Ginzburg criterion, we demonstrate that the width of the critical region associated with the smectic-A-smectic-C transition is dependent on the observable studied. This affords an explanation of the results obtained for terephthal-bis-p-p'-butylaniline, which shows specific-heat behavior consistent with a Landau-type model, unlike that of the elastic constants. This analysis could apply to other phase transitions

18 citations

Journal ArticleDOI
TL;DR: In this paper, the cubic-tetragonal (c-t) phase equilibria in the system ZrO2-YO1.5 are thermodynamically analyzed from Landau's phenomenological theory.
Abstract: The cubic-tetragonal (c-t) phase equilibria in the system ZrO2-YO1.5 are thermodynamically analyzed from Landau's phenomenological theory. The calculated c-t two-phase field is depicted as a miscibility gap with a sharp maximum and the spinodal region as originally predicted by Hillert and Sakuma. However, the observed c-t two-phase field and the spinodal region are better described by the present model. In addition, this model can be used to discuss the nature of the c-t diffusionless transformation from the order parameter in contrast with the original model. The predicted change in the tetragonality of t-ZrO2 with YO1.5 content is slightly different from that in the c/a axial ratio estimated from X-ray diffraction analysis. The displacement of cations and anions may not take place simultaneously during the c-t transformation.

18 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
202317
202242
202142
202041
201949
201855