Showing papers on "Magnetization published in 2022"

Untethered small-scale magnetic soft robot with programmable magnetization and integrated multifunctional modules

Abstract: Intelligent magnetic soft robots capable of programmable structural changes and multifunctionality modalities depend on material architectures and methods for controlling magnetization profiles. While some efforts have been made, there are still key challenges in achieving programmable magnetization profile and creating heterogeneous architectures. Here, we directly embed programmed magnetization patterns (magnetization modules) into the adhesive sticker layers to construct soft robots with programmable magnetization profiles and geometries and then integrate spatially distributed functional modules. Functional modules including temperature and ultraviolet light sensing particles, pH sensing sheets, oil sensing foams, positioning electronic component, circuit foils, and therapy patch films are integrated into soft robots. These test beds are used to explore multimodal robot locomotion and various applications related to environmental sensing and detection, circuit repairing, and gastric ulcer coating, respectively. This proposed approach to engineering modular soft material systems has the potential to expand the functionality, versatility, and adaptability of soft robots.

Beyond Conventional Ferromagnetism and Antiferromagnetism: A Phase with Nonrelativistic Spin and Crystal Rotation Symmetry

Abstract: The search for novel magnetic quantum phases, phenomena and functional materials has been guided by relativistic magnetic-symmetry groups in coupled spin and real space from the dawn of the field in 1950s to the modern era of topological matter. However, the magnetic groups cannot disentangle non-relativistic phases and effects, such as the recently reported unconventional spin physics in collinear antiferromagnets from the typically weak relativistic spin-orbit coupling phenomena. Here we discover that more general spin symmetries in decoupled spin and crystal space categorize non-relativistic collinear magnetism in three phases: conventional ferromagnets and antiferromagnets, and a third distinct phase combining zero net magnetization with an alternating spin-momentum locking in energy bands, which we dub "altermagnetic". For this third basic magnetic phase, which is omitted by the relativistic magnetic groups, we develop a spin-group theory describing six characteristic types of the altermagnetic spin-momentum locking. We demonstrate an extraordinary spin-splitting mechanism in altermagnetic bands originating from a local electric crystal field, which contrasts with the conventional magnetic or relativistic splitting by global magnetization or inversion asymmetry. Based on first-principles calculations, we identify altermagnetic candidates ranging from insulators and metals to a parent crystal of cuprate superconductor. Our results underpin emerging research of quantum phases and spintronics in high-temperature magnets with light elements, vanishing net magnetization, and strong spin-coherence.

Publisher Correction: An anomalous Hall effect in altermagnetic ruthenium dioxide

Abstract: The anomalous Hall effect is a time-reversal symmetry-breaking magneto-electronic phenomenon originally discovered in ferromagnets. Recently, ruthenium dioxide (RuO2) with a compensated antiparallel magnetic order has been predicted to generate an anomalous Hall effect of comparable strength to ferromagnets. The phenomenon arises from an altermagnetic phase of RuO2 with a characteristic alternating spin polarization in both real-space crystal structure and momentum-space band structure. Here we report an anomalous Hall effect in RuO2 with an anomalous Hall conductivity exceeding 1,000 Ω−1 cm−1. We combine the vector magnetometry and magneto-transport measurements of epitaxial RuO2 films of different crystallographic orientations. We show that the anomalous Hall effect dominates over an ordinary Hall contribution, and a contribution due to a weak field-induced magnetization. Our results could lead to the exploration of topological Berry phases and dissipationless quantum transport in crystals of abundant elements and with a compensated antiparallel magnetic order. By combining vector magnetometry and magneto-transport measurements of epitaxial films with different crystallographic orientations, an anomalous Hall effect can be measured in collinear altermagnetic ruthenium dioxide with an anomalous Hall conductivity exceeding 1,000 Ω–1 cm–1.

Independent Control Strategy of Multiple Magnetic Flexible Millirobots for Position Control and Path Following

Abstract: Magnetically actuated small-scale robots have great potential for numerous applications in remote, confined, or enclosed environments. Multiple small-scale robots enable cooperation and increase the operating efficiency. However, independent control of multiple magnetic small-scale robots is a great challenge, because the robots receive identical control inputs from the same external magnetic field. In this article, we propose a novel strategy of completely decoupled independent control of magnetically actuated flexible swimming millirobots. A flexible millirobot shows a crawling motion on a flat plane within an oscillating magnetic field. Millirobots with different magnetization directions have the same velocity response curve to the oscillating magnetic field but with a difference of phase. We designed and fabricated a group of up to four heterogeneous millirobots with identical geometries and different magnetization directions. According to their velocity response curves, an optimal direction of oscillating magnetic field is calculated to induce a desired velocity vector for the millirobot group, one of which is nonzero and the others are approximately zero. The strategy is verified by experiments of independent position control of up to four millirobots and independent path following control of up to three millirobots with small errors. We further expect that with this independent control strategy, the millirobots will be able to cooperate to finish complicated tasks.

Emerging Research Landscape of Altermagnetism

Abstract: Magnetism is one of the largest, most fundamental, and technologically most relevant fields of condensed-matter physics. Traditionally, two basic magnetic phases have been considered – ferromagnetism and antiferromagnetism. The breaking of the time-reversal symmetry and spin splitting of the electronic states by the magnetization in ferromagnets underpins a range of macroscopic responses in this extensively explored and exploited type of magnets. By comparison, antiferromagnets have vanishing net magnetization. This Perspective reflects on recent observations of materials hosting an intriguing ferromagnetic-antiferromagnetic dichotomy, in which spin-split spectra and macroscopic observables, akin to ferromagnets, are accompanied by antiparallel magnetic order with vanishing magnetization, typical of antiferromagnets. An unconventional non-relativistic symmetry-group formalism offers a resolution of this apparent contradiction by delimiting a third basic magnetic phase, dubbed altermagnetism. Our Perspective starts with an overview of the still emerging unique phenomenology of the phase, and of the wide array of altermagnetic material candidates. In the main part of the article, we illustrate how altermagnetism can enrich our understanding of overarching condensed-matter physics concepts, and have impact on prominent condensed-matter research areas.

Room-temperature magnetoresistive and magnetocaloric effect in La1−xBaxMnO3 compounds: Role of Griffiths phase with ferromagnetic metal cluster above Curie temperature

Abstract: The evolution of the Griffiths phase (GP) with a ferromagnetic metal (FMM) cluster above the Curie temperature (TC) and its effect on the magnetic properties, electrical transport, magnetoresistance (MR), and magnetocaloric effect (MCE) is studied comprehensively, using bulk compounds of La1−xBaxMnO3 (0.15 ≤ x ≤ 0.25) with different lattice distortions but with the same structural symmetry and space group. These La1−xBaxMnO3 samples show ferromagnetic transition at TC increasing from 229 K for x = 0.15–300 K for x = 0.25, in addition to the presence of GP with FMM clusters in the paramagnetic (PM) region, which have been confirmed by the combination of magnetization (susceptibility) measurements, the GP theory, and electron paramagnetic resonance technology. With increasing the Ba2+ ion doping, GP temperature (TG) and TC of La1−xBaxMnO3 are increased, and the GP regime is strengthened. The GP ratio in the PM region reached 27.7% for the sample with x = 0.20. The resistivity decreases and the FMM phase increases with increasing x from 0.15 to 0.25, which can be explained by the decrease in the bandgap (Eg) and the enhancement of the double-exchange effect. Remarkably, large room-temperature MR (∼44.7%) can be observed in the sample with x = 0.25 under 60 kOe, which is related to the presence of the GP regime. Furthermore, the MCE is also affected by the GP regime, and it is deduced that the magnetic transition is of second order. The value of magnetic entropy change ( |ΔSM|) reaches 3.04 J/kg K near room temperature for the sample with x = 0.25 under 50 kOe. This value is associated with a relative cooling power (RCP) of 248.1 J/kg. For the sample with x = 0.15, the value of RCP reaches 307.6 J/kg under 50 kOe. The discovery of the MR and MCE near room temperature is of great significance from the practical application of perovskite manganites in magnetic sensors and magnetic refrigerants.

Spin–Orbit Torque Switching in an All‐Van der Waals Heterostructure

Abstract: Current-induced control of magnetization in ferromagnets using spin-orbit torque (SOT) has drawn attention as a new mechanism for fast and energy efficient magnetic memory devices. Energy-efficient spintronic devices require a spin-current source with a large SOT efficiency (ξ) and electrical conductivity (σ), and an efficient spin injection across a transparent interface. Herein, single crystals of the van der Waals (vdW) topological semimetal WTe2 and vdW ferromagnet Fe3 GeTe2 are used to satisfy the requirements in their all-vdW-heterostructure with an atomically sharp interface. The results exhibit values of ξ ≈ 4.6 and σ ≈ 2.25 × 105 Ω-1 m-1 for WTe2 . Moreover, the significantly reduced switching current density of 3.90 × 106 A cm-2 at 150 K is obtained, which is an order of magnitude smaller than those of conventional heavy-metal/ferromagnet thin films. These findings highlight that engineering vdW-type topological materials and magnets offers a promising route to energy-efficient magnetization control in SOT-based spintronics.

Observation of the Orbital Rashba-Edelstein Magnetoresistance

Abstract: We report the observation of magnetoresistance (MR) that could originate from the orbital angular momentum (OAM) transport in a permalloy (Py)/oxidized Cu (Cu^{*}) heterostructure: the orbital Rashba-Edelstein magnetoresistance. The angular dependence of the MR depends on the relative angle between the induced OAM and the magnetization in a similar fashion as the spin Hall magnetoresistance. Despite the absence of elements with large spin-orbit coupling, we find a sizable MR ratio, which is in contrast to the conventional spin Hall magnetoresistance which requires heavy elements. Through Py thickness-dependence studies, we conclude another mechanism beyond the conventional spin-based scenario is responsible for the MR observed in Py/Cu^{*} structures-originated in a sizable transport of OAM. Our findings not only suggest the current-induced torques without using any heavy elements via the OAM channel but also provide an important clue towards the microscopic understanding of the role that OAM transport can play for magnetization dynamics.

Efficient perpendicular magnetization switching by a magnetic spin Hall effect in a noncollinear antiferromagnet

Abstract: Current induced spin-orbit torques driven by the conventional spin Hall effect are widely used to manipulate the magnetization. This approach, however, is nondeterministic and inefficient for the switching of magnets with perpendicular magnetic anisotropy that are demanded by the high-density magnetic storage and memory devices. Here, we demonstrate that this limitation can be overcome by exploiting a magnetic spin Hall effect in noncollinear antiferromagnets, such as Mn3Sn. The magnetic group symmetry of Mn3Sn allows generation of the out-of-plane spin current carrying spin polarization collinear to its direction induced by an in-plane charge current. This spin current drives an out-of-plane anti-damping torque providing the deterministic switching of the perpendicular magnetization of an adjacent Ni/Co multilayer. Due to being odd with respect to time reversal symmetry, the observed magnetic spin Hall effect and the resulting spin-orbit torque can be reversed with reversal of the antiferromagnetic order. Contrary to the conventional spin-orbit torque devices, the demonstrated magnetization switching does not need an external magnetic field and requires much lower current density which is useful for low-power spintronics.

Impact of Sm3+ and Er3+ Cations on the Structural, Optical, and Magnetic Traits of Spinel Cobalt Ferrite Nanoparticles: Comparison Investigation

Abstract: In this study, we investigated a comparison of the structure, morphology, optic, and magnetic (room temperature (RT)) features of Er3+ and Sm3+ codoped CoFe2O4 (CoErSm) nanospinel ferrite (NSFs) (x ≤ 0.05) synthesized via hydrothermal (H-CoErSm NSFs) and sonochemical (S-CoErSm NSFs) approaches. The formation of all products via both synthesis methods has been validated by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM), along with energy-dispersive X-ray (EDX) and transmission electron microscopy (TEM) techniques. The single phase of the spinel structure (except for the Hyd sample with x = 0.03) was evidenced by XRD analysis. The DXRD (crystallite size) values of H-CoErSm and S-CoErSm NSFs are in the 10–14.7 and 10–16 nm ranges, respectively. TEM analysis presented the cubic morphology of all products. A UV–visible percent diffuse reflectance (DR %) study was performed on all products, and Eg (direct optical energy band gap) values varying in the 1.32–1.48 eV range were projected from the Tauc plots. The data of RT magnetization demonstrated that all prepared samples are ferromagnetic in nature. M–H data revealed that rising the contents of cosubstituent elements (Sm3+ and Er3+ ions) caused an increase in Ms (saturation magnetization) and Hc (coercive field) in comparison to pristine samples. Although concentration dependence is significant (x > 0.02), no strict regularity (roughly fluctuating) has been ruled out in Ms values for doped samples prepared via the hydrothermal method. However, sonochemically prepared samples demonstrated that Ms values increase with increasing x up to x = 0.04 and then decrease with the further rise in cosubstituent Sm3+ and Er3+ ions. The calculated values of Ms and Hc were found to be greater in H-CoErSm NSFs compared to those in S-CoErSm NSFs. The present investigation established that the distribution of cations and the variation in crystallite/particle sizes are efficient to control the intrinsic properties of all samples.

Influence of magnetization, variable viscosity and thermal conductivity on Von Karman swirling flow of H2O-FE3O4 and H2O-Mn-ZNFe2O4 ferromagnetic nanofluids from a spinning DISK: Smart spin coating simulation

Abstract: • Mathematical model developed for a Ferromagnetic nanofluids through rotating disk. • Features of Magnetization, variable viscosity and thermal conductivity are included. • Galerkin weighted residual method with Simpson’s 1/3rd rule utilized for solutions. • Rapidly convergent and accurate solutions are achieved with GWRM. Motivated by smart nano-ferromagnetic spin coating applications, A theoretical study is described for steady swirling Von Karman thermo-magnetic water-based flowing nanoliquids containing ferromagnetic nanoparticles from a rotating disk in Darcian permeable media. The governing mass, momentum and temperature equations are converted into nonlinear-coupled ordinary derivative momentum and energy equations via appropriate similarity transformations, resulting boundary value ordinary differential problem is solved by a Galerkin weighted residual method (GWRM) along with Simpson’s one-third rule. Verification of the GWRM solutions is achieved with numerical shooting quadrature (MAPLE) and very good correlation is demonstrated. Ferromagnetic Fe 3 O 4 nanofluid is observed to achieve superior thermal conductivity enhancement relative to ferromagnetic Mn-ZnFe 2 O 4 nanofluid. Increasing magnetic field intensity δ substantially modifies the viscosity and produces a consistent retardation in both axial and radial velocity whereas it weakly enhances the tangential velocity field. With greater ferromagnetic interaction number β axial velocity is enhanced strongly, and radial velocity is also boosted.

Supercurrent diode effect, spin torques, and robust zero-energy peak in planar half-metallic trilayers

Abstract: We consider trilayer ${\mathrm{F}}_{1}{\mathrm{F}}_{2}{\mathrm{F}}_{3}$ Josephson junctions that are finite in two dimensions and have arbitrary magnetizations in each ferromagnet ${\mathrm{F}}_{i}\phantom{\rule{0.28em}{0ex}}(i=1,2,3)$. The trilayers are sandwiched between two $s$-wave superconductors with a macroscopic phase difference $\mathrm{\ensuremath{\Delta}}\ensuremath{\varphi}$. Our results reveal that when the magnetizations have three orthogonal components, a supercurrent can flow at $\mathrm{\ensuremath{\Delta}}\ensuremath{\varphi}=0$. With our generalized theoretical and numerical techniques, we study the planar spatial profiles and $\mathrm{\ensuremath{\Delta}}\ensuremath{\varphi}$ dependencies of the charge supercurrents, spin supercurrents, spin torques, and density of states. Remarkably, upon increasing the magnetization strength in the central ferromagnet layer up to the half-metallic limit, the self-biased current and induced second harmonic component become dramatically enhanced while the critical supercurrent reaches its maximum value. Additionally, for a broad range of exchange-field strengths and orientations, the ground state of the system can be tuned to an arbitrary phase difference ${\ensuremath{\varphi}}_{0}$. For intermediate exchange-field strengths in the middle layer ${\mathrm{F}}_{2}$, a ${\ensuremath{\varphi}}_{0}$ state can arise that creates a superconducting diode effect, whereby $\mathrm{\ensuremath{\Delta}}\ensuremath{\varphi}$ can be tuned to create a one-way dissipationless current flow. The spin currents and effective magnetic moments reveal a long-ranged spin torque in the half-metallic phase. Moreover, the density of states unveils the emergence of zero-energy peaks for the mutually orthogonal magnetization configurations. Our results suggest that this simple trilayer Josephson junction can be an excellent candidate for producing experimentally accessible signatures for long-ranged self-biased supercurrents and supercurrent diode effects.

Hydrogen-Bonded Framework of a Cobalt(II) Complex Showing Superior Stability and Field-Induced Slow Magnetic Relaxation

Abstract: A unique hydrogen-bonded organic-inorganic framework (HOIF) constructed from a mononuclear cobalt(II) complex, [Co(MCA)2·(H2O)2] (HMCA = 4-imidazolecarboxylic acid), via multiple hydrogen-bonding interactions was synthesized and structurally characterized. The Co(II) center in the HOIF features a highly distorted octahedral coordination environment. Remarkably, the CoII HOIF showed permanent porosity with superior stability as established by combined thermogravimetric analysis (TGA), variable-temperature infrared spectra (IR), variable-temperature powder X-ray diffraction data (PXRD), and a CO2 isotherm. Structural studies reveal that short multiple hydrogen bonds should be responsible for the superior thermal and chemical stability of a HIOF. Magnetic investigations reveal the large easy-plane magnetic anisotropy of the Co2+ ions with the fitted D values being 22.1 (magnetic susceptibility and magnetization data) and 29.1 cm-1 (reduced magnetization data). In addition, the HOIF exhibits field-induced slow magnetic relaxation at low temperature with an effective energy barrier of Ueff = 45.2 cm-1, indicative of a hydrogen-bonded framework single-ion magnet of the compound. The origin of the significant magnetic anisotropy of the complex was also understood from computational studies. In addition, BS-DFT calculations indicate that the superexchange interactions between the neighboring CoII ions are non-negligible antiferromagnetism with JCo-Co = -0.5 cm-1. The foregoing results provide not only a carboxylate-imidazole ligand approach toward a stable HOIF but also a promising way to build a robust single-ion magnet via hydrogen-bond interactions.

Laser-induced terahertz spin transport in magnetic nanostructures arises from the same force as ultrafast demagnetization

Abstract: The authors observe here that (a) laser-induced ultrafast demagnetization (UDM) of a metallic ferromagnet $F$ has the same time evolution as (b) terahertz spin transport (TST) from $F$ into an adjacent normal metal $N$. They conclude that UDM in $F$ and TST in $F$|$N$ samples are driven by the same force: (c) a generalized spin voltage, i.e., an excess magnetization of $F$. One can now apply the vast knowledge of UDM to TST to significantly increase spin-current amplitudes for ultrafast spintronic applications.

Field-Free Switching of Perpendicular Magnetization Induced by Longitudinal Spin-Orbit-Torque Gradient

Abstract: Spin-orbit-torque (SOT) symmetry in a heavy-metal--ferromagnet bilayer forbids the deterministic switching of perpendicular magnetization. Traditionally, an external magnetic field-exchange bias-tilted magnetic anisotropy is introduced to break the symmetry, which is not suitable for practical applications. Here, we propose to break the SOT symmetry by introducing a longitudinal composition gradient in $\mathrm{Cu}\text{\ensuremath{-}}\mathrm{Pt}$ heavy metal. We demonstrate the deterministic switching of a perpendicularly magnetized $\mathrm{Co}/\mathrm{Ni}$ multilayer with good endurance when the electric current flows along the direction of the composition gradient. No field-free switching is observed when the current is applied transverse to the gradient or the gradient is removed. The composition gradient of $\mathrm{Cu}\text{\ensuremath{-}}\mathrm{Pt}$ leads to a longitudinal gradient of SOT, which results in the field-free switching of perpendicular magnetization. Our work offers a promising approach for lowering the symmetry of the material system for developing spintronic applications.

Topological Magnets: Functions Based on Berry Phase and Multipoles

Abstract: Macroscopic responses of magnets are often governed by magnetization and, thus, have been restricted to ferromagnets. However, such responses are strikingly large in the newly developed topological magnets, breaking the conventional scaling with magnetization. Taking the recently discovered antiferromagnetic (AF) Weyl semimetals as a prime example, we highlight the two central ingredients driving the significant macroscopic responses: the Berry curvature enhanced because of nontrivial band topology in momentum space, and the cluster magnetic multipoles in real space. The combination of large Berry curvature and multipoles enables large macroscopic responses such as the anomalous Hall and Nernst effects, the magneto-optical effect, and the novel magnetic spin Hall effect in antiferromagnets with negligible net magnetization, but also allows us to manipulate these effects by electrical means. Furthermore, nodal-point and nodal-line semimetallic states in ferromagnets may provide the strongly enhanced Berry curvature near the Fermi energy, leading to large responses beyond the conventional magnetization scaling. These significant properties and functions of the topological magnets lay the foundation for future technological development such as spintronics and thermoelectric technology.

Orbit-Transfer Torque Driven Field-Free Switching of Perpendicular Magnetization

Abstract: The reversal of perpendicular magnetization (PM) by electric control is crucial for high-density integration of low-power magnetic random-access memory. Although the spin-transfer torque and spin-orbit torque technologies have been used to switch the magnetization of a free layer with perpendicular magnetic anisotropy, the former has limited endurance because of the high current density directly through the junction, while the latter requires an external magnetic field or unconventional configuration to break the symmetry. Here we propose and realize the orbit-transfer torque (OTT), that is, exerting torque on the magnetization using the orbital magnetic moments, and thus demonstrate a new strategy for current-driven PM reversal without external magnetic field. The perpendicular polarization of orbital magnetic moments is generated by a direct current in a few-layer WTe 2 due to the existence of nonzero Berry curvature dipole, and the polarization direction can be switched by changing the current polarity. Guided by this principle, we construct the WTe 2 /Fe 3 GeTe 2 heterostructures to achieve the OTT driven field-free deterministic switching of PM.

From Low to High Saturation Magnetization in Magnetite Nanoparticles: The Crucial Role of the Molar Ratios Between the Chemicals

Abstract: In this study, a comprehensive characterization of iron oxide nanoparticles synthesized by using a simple one-pot thermal decomposition route is presented. In order to obtain monodisperse magnetite nanoparticles with high saturation magnetization, close to the bulk material, the molar ratios between the starting materials (solvents, reducing agents, and surfactants) were varied. Two out of nine conditions investigated in this study resulted in monodisperse iron oxide nanoparticles with high saturation magnetization (90 and 93% of bulk magnetite). The X-ray diffraction analyses along with the inspection of the lattice structure through transmission electron micrographs revealed that the main cause of the reduced magnetization in the other seven samples is likely due to the presence of distortion and microstrain in the particles. Although the thermogravimetric analysis, Raman and Fourier transform infrared spectroscopies confirmed the presence of covalently bonded oleic acid on the surface of all the samples, the particles with higher polydispersity and the lowest surface coating molecules showed the lowest saturation magnetization. Based on the observed results, it could be speculated that the changes in the kinetics of the reactions, induced by varying the molar ratio of the starting chemicals, can lead to the production of the particles with higher polydispersity and/or lattice deformation in their crystal structures. Finally, it was concluded that the experimental conditions for obtaining high-quality iron oxide nanoparticles, particularly the molar ratios and the heating profile, should not be chosen independently; for any specific molar ratio, there may exist a specific heating profile or vice versa. Because this synthetic consideration has rarely been reported in the literature, our results can give insights into the design of iron oxide nanoparticles with high saturation magnetization for different applications.

Metal-metal bond in lanthanide single-molecule magnets.

Abstract: Lanthanide (Ln) compounds represent a unique chemical platform for developing high-temperature single-molecule magnets (SMMs). The shift in research focus from increasing the magnetic anisotropy barrier (Ueff) to raising the blocking temperature (TB) has upgraded the design criteria from considering only the static crystal field (CF) to paying attention to the effects of molecular vibrations beyond the first coordination environment on the relaxation of magnetization. Although the realization of high working temperatures for Ln SMMs remains a formidable challenge, recent remarkable advances in dimetallofullerenes (di-EMFs) with Ln ions and mixed-valence dilanthanide complexes both feature single-electron Ln-Ln bonds to afford room-temperature molecular magnets. In this review, we provide critical discussion on the achievements of metal-metal (MM) bonded lanthanide SMMs, focusing on the effects of MM bonds on the magnetization dynamics, and shedding light on the future developments of high-temperature Ln SMMs.

Tuning the structure and magnetic properties <i>via</i> distinct pyridine derivatives in cobalt(<scp>ii</scp>) coordination polymers

Abstract: Precise modulation of the structure and magnetic properties of coordination compounds is of great importance in the development of framework magnetic materials. Herein, we report that the coordination self-assembly of a neutral cobalt(II) magnetic building block and selective pyridine derivatives as organic linkers has led to two distinct cobalt(II) coordination polymers, {Co(DClQ)2(bpy)}n (1) and {Co2(DClQ)4(tpb)}n (2) (DClQ = (5,7-dichloro-8-hydroxyquinoline; bpy = 4, 4'-dipyridine; tpb = 1,2,4,5-tetra(4-pyridyl)benzene)). Structural analyses revealed that 1 and 2 are one-dimensional (1D) and 2D coordination polymers containing the same neutral magnetic building block [Co(DClQ)2] bridged by bitopic bpy and tetratopic tpb ligands, respectively. Both the complexes have a distorted octahedral CoN4O2 coordination geometry around each cobalt center offered by the bidentate ligand and organic linkers. Magnetic studies reveal large easy-plane and easy-axis magnetic anisotropy for 1 and 2, respectively. However, because of the weak antiferromagnetic coupling between the bpy-bridged CoII centers, no slow relaxation of the magnetization was observed in 1 under both zero or applied dc fields. Interestingly, complex 2 exhibits slow magnetic relaxation under external fields, indicative of a framework single-ion magnet of 2. Theoretical calculations further support the experimental results and unveil that the D values are +65.3 and -91.2 cm-1 for 1 and 2, respectively, while the magnetic exchange interaction was precisely estimated as -0.16 (1) and -0.009 (2) cm-1. The foregoing results show that the structural dimensionality and magnetic properties can be rationally modified via pre-designed magnetic building blocks and a suitable choice of organic bridging ligands.