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Master equation

About: Master equation is a research topic. Over the lifetime, 10541 publications have been published within this topic receiving 276095 citations.


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Journal ArticleDOI
TL;DR: In this paper, a NASA database of state-to-state transition rates for N 2 + N 2 was used to perform master equation studies for various nonequilibrium heat bath conditions.

142 citations

Journal ArticleDOI
TL;DR: An exact solution of the master equation is obtained and the types of nonequilibrium steady states that can be generated are studied and it is demonstrated that the steady state for certain discrete values of the external field strength and detuning is a pure state.
Abstract: We consider the dynamics of a collection of atoms interacting with a coherent field and a broadband squeezed vacuum. We obtain an exact solution of the master equation and study in detail the types of nonequilibrium steady states that can be generated. We show that in the absence of coherent drive the atoms are in a state whose properties are similar to those of the squeezed vacuum for photons. We demonstrate that the steady state for certain discrete values of the external field strength and detuning is a pure state which is the eigenstate of the non-Hermitian operator cosh(‖ξ‖)S-+sinh(‖ξ‖)S+, where ξ is the squeezing parameter associated with the input radiation field. These eigenstates play a very fundamental role in the theory and satisfy the equality sign in the Heisenberg uncertainty relation Δ SxΔSy≥ ½‖Sz‖. We also present detailed numerical results for the characteristics of the field generated by the collective system.

142 citations

Journal ArticleDOI
TL;DR: This work presents a model reduction method for study of stochastic chemical kinetic systems that takes advantage of multiple time scales and is implemented in a novel numerical algorithm that exploits the time scale separation to achieve model order reductions while enabling error checking and control.
Abstract: The dynamics of chemical reaction networks often takes place on widely differing time scales--from the order of nanoseconds to the order of several days. This is particularly true for gene regulatory networks, which are modeled by chemical kinetics. Multiple time scales in mathematical models often lead to serious computational difficulties, such as numerical stiffness in the case of differential equations or excessively redundant Monte Carlo simulations in the case of stochastic processes. We present a model reduction method for study of stochastic chemical kinetic systems that takes advantage of multiple time scales. The method applies to finite projections of the chemical master equation and allows for effective time scale separation of the system dynamics. We implement this method in a novel numerical algorithm that exploits the time scale separation to achieve model order reductions while enabling error checking and control. We illustrate the efficiency of our method in several examples motivated by recent developments in gene regulatory networks.

142 citations

Journal ArticleDOI
TL;DR: In this paper, the authors examine the methodology from a rigorous point of view, discussing where it can be expected to work, and where it should fail, where the Kohn-Sham levels are misaligned.
Abstract: Density functional calculations for the electronic conductance of single molecules are now common. We examine the methodology from a rigorous point of view, discussing where it can be expected to work, and where it should fail. When molecules are weakly coupled to leads, local and gradient-corrected approximations fail, as the Kohn–Sham levels are misaligned. In the weak bias regime, exchange–correlation corrections to the current are missed by the standard methodology. For finite bias, a new methodology for performing calculations can be rigorously derived using an extension of time-dependent current density functional theory from the Schrodinger equation to a master equation.

141 citations

Journal ArticleDOI
TL;DR: In this paper, the scaling of the spectral gap with the system length is studied and a generic bound that the gap cannot be larger than ∼1/L is established for systems with only boundary dissipation.
Abstract: We study relaxation times, also called mixing times, of quantum many-body systems described by a Lindblad master equation. We in particular study the scaling of the spectral gap with the system length, the so-called dynamical exponent, identifying a number of transitions in the scaling. For systems with bulk dissipation we generically observe different scaling for small and for strong dissipation strength, with a critical transition strength going to zero in the thermodynamic limit. We also study a related phase transition in the largest decay mode. For systems with only boundary dissipation we show a generic bound that the gap cannot be larger than ∼1/L. In integrable systems with boundary dissipation one typically observes scaling of ∼1/L(3), while in chaotic ones one can have faster relaxation with the gap scaling as ∼1/L and thus saturating the generic bound. We also observe transition from exponential to algebraic gap in systems with localized modes.

141 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
2023140
2022344
2021431
2020460
2019420
2018427