Master equation

About: Master equation is a research topic. Over the lifetime, 10541 publications have been published within this topic receiving 276095 citations.

Benchmark results for particle transport in a binary Markov statistical medium

Abstract: We give numerical benchmark results for particle transport in a randomly mixed binary medium, with the mixing statistics described as a homogeneous Markov process. A Monte Carlo procedure is used to generate a physical realization of the statistics, and a discrete ordinate numerical transport solution is generated for this realization. The ensemble averaged solution, as well as the variance, is obtained by averaging a large number of such calculations. Reflection and transmission results are given for several problems in both rod and planar geometry. In a separate development, two coupled transport equations are derived which formally described transport in a random binary mixture for arbitrary mixing statistics. Closing these equations by approximating their coupling terms in a low order and intuitive way leads to a model for stochastic transport previously obtained via the master equation. The present derivation, based upon approximating exact equations, allows in principle the opportunity to develop more accurate models by making higher order approximations in the coupling terms.

First-principles calculations of anisotropic charge-carrier mobilities in organic semiconductor crystals

Abstract: The orientational dependence of charge carrier mobilities in organic semiconductor crystals and the correlation with the crystal structure are investigated by means of quantum chemical first principles calculations combined with a model using hopping rates from Marcus theory. A master equation approach is presented which is numerically more efficient than the Monte Carlo method frequently applied in this context. Furthermore, it is shown that the widely used approach to calculate the mobility via the diffusion constant along with rate equations is not appropriate in many important cases. The calculations are compared with experimental data, showing good qualitative agreement for pentacene and rubrene. In addition, charge transport properties of core-fluorinated perylene bisimides are investigated.

Master equation for a kinetic model of a trading market and its analytic solution.

Abstract: We analyze an ideal-gas-like model of a trading market with quenched random saving factors for its agents and show that the steady state income (m) distribution P(m) in the model has a power law tail with Pareto index nu exactly equal to unity, confirming the earlier numerical studies on this model. The analysis starts with the development of a master equation for the time development of P(m) . Precise solutions are then obtained in some special cases.

Shot noise spectrum of open dissipative quantum two-level systems.

Abstract: We study the current noise spectrum of qubits under transport conditions in a dissipative bosonic environment. We combine (non-)Markovian master equations with correlation functions in Laplace space to derive a noise formula for both weak and strong coupling to the bath. The coherence-induced reduction of noise is diminished by weak dissipation and/or a large level separation (bias). For weak dissipation, we demonstrate that the dephasing and relaxation rates of the two-level systems can be extracted from noise. In the strong dissipation regime, the localization-delocalization transition becomes visible in the low-frequency noise.