Topic
MCM-41
About: MCM-41 is a research topic. Over the lifetime, 2355 publications have been published within this topic receiving 91416 citations.
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TL;DR: In this article, the dispersing behavior of MoO3 on the inner surface of mesoporous silicate MCM-41 was investigated using SEM, XPS, and FTIR.
56 citations
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TL;DR: The results indicated that US-H(2)O(2)-α-Fe(2,O(3)/MCM-41 nanocomposite system is effective for the degradation of MB, suggesting its great potential in removal of dyes from wastewater.
56 citations
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TL;DR: In this paper, the catalytic activity of MCM-41 molecular sieves in the Si/Al ratios 25, 50, 75 and 100 were characterised using powder X-ray diffraction (XRD), FT-IR and BET surface area analyser.
Abstract: Mesoporous Al-MCM-41 molecular sieves in the Si/Al ratios 25, 50, 75 and 100 were synthesized under hydrothermal condition. They were characterised using powder X-ray diffraction (XRD), FT-IR and BET surface area analyser. The catalytic activity of these materials was tested for the slurry phase acetalization of cyclohexanone with methanol (MET), ethylene glycol (EG) and pentaerythritol (PEN) at 40–120 °C. MET conversion was found to be higher than that of EG and PEN. Hydrophobic property of catalyst and alcohols and also the steric properties of alcohols were suggested to play an important role in the acetalization. For MET and EG, Al-MCM-41 (100) was found to be more active than other catalyst but for PEN, Al-MCM-41 (25) was found to be more active. The reaction was also studied over H 3 PW 12 O 40 supported MCM-41, commercially available heteropolyacid (H 3 PW 12 O 40 · n H 2 O) and zeolites (HM, Hβ and ZSM-5). Zeolites showed less activity for EG, PEN but comparable activity to MET. The requirement of Bronsted acid sites for the reaction was clearly established by running the reaction in the absence of catalyst.
55 citations
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TL;DR: In this paper, the structural characteristics and performance of vanadia catalysts (0.7-8 W.% V) supported on mesoporous (MCM-41, HMS, MCF, SBA-15), microporous (silicalite) and non-porous (SiO 2 ) silicas in oxidative dehydrogenation of propane were investigated.
55 citations