Showing papers on "Metamorphism published in 2016"

The giant Jiaodong gold province: The key to a unified model for orogenic gold deposits?

Abstract: Although the term orogenic gold deposit has been widely accepted for all gold-only lode-gold deposits, with the exception of Carlin-type deposits and rare intrusion-related gold systems, there has been continuing debate on their genesis. Early syngenetic models and hydrothermal models dominated by meteoric fluids are now clearly unacceptable. Magmatic-hydrothermal models fail to explain the genesis of orogenic gold deposits because of the lack of consistent spatially – associated granitic intrusions and inconsistent temporal relationships. The most plausible, and widely accepted, models involve metamorphic fluids, but the source of these fluids is hotly debated. Sources within deeper segments of the supracrustal successions hosting the deposits, the underlying continental crust, and subducted oceanic lithosphere and its overlying sediment wedge all have their proponents. The orogenic gold deposits of the giant Jiaodong gold province of China, in the delaminated North China Craton, contain ca. 120 Ma gold deposits in Precambrian crust that was metamorphosed over 2000 million years prior to gold mineralization. The only realistic source of fluid and gold is a subducted oceanic slab with its overlying sulfide-rich sedimentary package, or the associated mantle wedge. This could be viewed as an exception to a general metamorphic model where orogenic gold has been derived during greenschist- to amphibolite-facies metamorphism of supracrustal rocks: basaltic rocks in the Precambrian and sedimentary rocks in the Phanerozoic. Alternatively, if a holistic view is taken, Jiaodong can be considered the key orogenic gold province for a unified model in which gold is derived from late-orogenic metamorphic devolatilization of stalled subduction slabs and oceanic sediments throughout Earth history. The latter model satisfies all geological, geochronological, isotopic and geochemical constraints but the precise mechanisms of auriferous fluid release, like many other subduction-related processes, are model-driven and remain uncertain.

High-grade metamorphism and partial melting of basic and intermediate rocks

Abstract: Rocks of basic and intermediate bulk composition occur in orogenic terranes from all geological time periods and are thought to represent significant petrological components of the middle and lower continental crust. However, the former lack of appropriate thermodynamic models for silicate melt, amphibole and clinopyroxene that can be applied to such lithologies at high temperature has inhibited effective phase equilibrium modelling of their petrological evolution during amphibolite- and granulite facies metamorphism. In this work, we present phase diagrams calculated in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) compositional system for a range of natural basic and intermediate bulk compositions for conditions of 2–12 kbar and 600–1050 ∘C using newly parameterized activity–composition relationships detailed in a companion paper by Green et al. in this issue. Particular attention is given to mid-ocean ridge basalt (MORB) and diorite protolith bulk compositions. Calculated subsolidus mineral assemblages in all basic and intermediate rock types are modally dominated by hornblende and plagioclase, with variable proportions of epidote, clinopyroxene, garnet, biotite, muscovite, quartz, titanite or ilmenite present at different pressures. The H2O-saturated (wet) solidus has a negative P−T slope and occurs between ∼620–690 ∘C at mid- to lower-crustal pressures of 5–10 kbar. The lowest-T melts generated close to the wet solidus are calculated to have granitic major-element oxide compositions. Melting at higher temperature is attributed primarily to multivariate hydrate-breakdown reactions involving biotite and/or hornblende. Partial melt compositions calculated at 800–1050 ∘C for MORB show good correlation with analysed compositions of experimental glasses produced via hydrate-breakdown melting of natural and synthetic basic protoliths, with Niggli norms indicating that they would crystallize to trondhjemite or tonalite. Diorite is shown to be significantly more fertile than MORB and is calculated to produce high-T melts (>800 ∘C) of granodioritic composition. Subsolidus and suprasolidus mineral assemblages show no significant variation between different members of the basalt family, although the P−T conditions at which orthopyroxene stabilizes, thus defining the prograde amphibolite–granulite transition, is strongly dependent on bulk-rock oxidation state and water content. The petrological effects of open- and closed-system processes on the mineral assemblages produced during prograde metamorphism and preserved during retrograde metamorphism are also examined via a case-study analysis of a natural Archean amphibolite from the Lewisian Complex, northwest Scotland.

Tectonic evolution and paleogeography of the Kırşehir Block and the Central Anatolian Ophiolites, Turkey

Abstract: In Central and Western Anatolia two continent-derived massifs simultaneously underthrusted an oceanic lithosphere in the Cretaceous and ended up with very contrasting metamorphic grades: high pressure, low temperature in the Tavsanli zone and the low pressure, high temperature in the Kirsehir Block. To assess why, we reconstruct the Cretaceous paleogeography and plate configuration of Central Anatolia using structural, metamorphic, and geochronological constraints and Africa-Europe plate reconstructions. We review and provide new 40Ar/39Ar and U/Pb ages from Central Anatolian metamorphic and magmatic rocks and ophiolites and show new paleomagnetic data on the paleo-ridge orientation in a Central Anatolian Ophiolite. Intraoceanic subduction that formed within the Neotethys around 100–90 Ma along connected N-S and E-W striking segments was followed by overriding oceanic plate extension. Already during suprasubduction zone ocean spreading, continental subduction started. We show that the complex geology of central and southern Turkey can at first order be explained by a foreland-propagating thrusting of upper crustal nappes derived from a downgoing, dominantly continental lithosphere: the Kirsehir Block and Tavsanli zone accreted around 85 Ma, the Afyon zone around 65 Ma, and Taurides accretion continued until after the middle Eocene. We find no argument for Late Cretaceous subduction initiation within a conceptual “Inner Tauride Ocean” between the Kirsehir Block and the Afyon zone as widely inferred. We propose that the major contrast in metamorphic grade between the Kirsehir Block and the Tavsanli zone primarily results from a major contrast in subduction obliquity and the associated burial rates, higher temperature being reached upon higher subduction obliquity.

Dating prograde fluid pulses during subduction by in situ U–Pb and oxygen isotope analysis

Abstract: The Dora-Maira whiteschists derive from metasomatically altered granites that experienced ultrahigh-pressure metamorphism at ~750 °C and 40 kbar during the Alpine orogeny. In order to investigate the P–T–time–fluid evolution of the whiteschists, we obtained U–Pb ages from zircon and monazite and combined those with trace element composition and oxygen isotopes of the accessory minerals and coexisting garnet. Zircon cores are the only remnants of the granitic protolith and still preserve a Permian age, magmatic trace element compositions and δ18O of ~10 ‰. Thermodynamic modelling of Si-rich and Si-poor whiteschist compositions shows that there are two main fluid pulses during prograde subduction between 20 and 40 kbar. In Si-poor samples, the breakdown of chlorite to garnet + fluid occurs at ~22 kbar. A first zircon rim directly overgrowing the cores has inclusions of prograde phlogopite and HREE-enriched patterns indicating zircon growth at the onset of garnet formation. A second main fluid pulse is documented close to peak metamorphic conditions in both Si-rich and Si-poor whiteschist when talc + kyanite react to garnet + coesite + fluid. A second metamorphic overgrowth on zircon with HREE depletion was observed in the Si-poor whiteschists, whereas a single metamorphic overgrowth capturing phengite and talc inclusions was observed in the Si-rich whiteschists. Garnet rims, zircon rims and monazite are in chemical and isotopic equilibrium for oxygen, demonstrating that they all formed at peak metamorphism at 35 Ma as constrained by the age of monazite (34.7 ± 0.4 Ma) and zircon rims (35.1 ± 0.8 Ma). The prograde zircon rim in Si-poor whiteschists has an age that is within error indistinguishable from the age of peak metamorphic conditions, consistent with a minimum rate of subduction of 2 cm/year for the Dora-Maira unit. Oxygen isotope values for zircon rims, monazite and garnet are equal within error at 6.4 ± 0.4 ‰, which is in line with closed-system equilibrium fractionation during prograde to peak temperatures. The resulting equilibrium ∆18Ozircon-monazite at 700 ± 20 °C is 0.1 ± 0.7 ‰. The in situ oxygen isotope data argue against an externally derived input of fluids into the whiteschists. Instead, fluid-assisted zircon and monazite recrystallisation can be linked to internal dehydration reactions during prograde subduction. We propose that the major metasomatic event affecting the granite protolith was related to hydrothermal seafloor alteration post-dating Jurassic rifting, well before the onset of Alpine subduction.

Neoproterozoic to early Paleozoic tectonic evolution of the Zavkhan terrane of Mongolia: Implications for continental growth in the Central Asian orogenic belt

Abstract: The Zavkhan terrane is a Proterozoic cratonic fragment in southwestern Mongolia that forms the core of the Central Asian orogenic belt. We provide new geologic and U-Pb zircon geochronologic constraints on the Neoproterozoic and early Paleozoic tectonic evolution of the terrane. Orthogneisses dated as ca. 1967 and ca. 839 Ma form the basement and are intruded and overlain by ca. 811–787 Ma arc-volcanic and volcaniclastic rocks that lack a gneissic fabric, suggestive of a mid-Neoproterozoic metamorphic event. Rifting and formation of the Zavkhan ribbon continent occurred from ca. 770–717 Ma and was followed by passive margin sedimentation between 717 and 580 Ma. During the latest Ediacaran to Cambrian, the southern margin of the Zavkhan terrane was reactivated with the obduction of the Lake terrane, slab break-off and reversal, and ca. 509–507 Ma magmatism. Metamorphosed Proterozoic and Cambrian units are cut by undeformed ca. 496 Ma gabbro, providing a tight constraint on the age of Cambrian metamorphism. Late Ordovician to Silurian rifting is marked by bimodal magmatism and deposition in narrow fault-bound basins. Our data indicate that the Zavkhan terrane traveled alone in the Neoproterozoic, collided with the Lake terrane in the late Ediacaran to Cambrian, accreted an unknown crustal block during Cambrian Epoch 2–Epoch 3, and then rifted away in the Ordovician. We suggest the majority of continental growth in Mongolia occurred through the trapping and oroclinal bending of ribbon continents rather than long-lived accretion on the margin of a major craton.

Paleoproterozoic evolution of the Guiana Shield in Suriname: A revised model

Abstract: The Proterozoic basement of Suriname consists of a greenstone–tonalite–trondhjemite–granodiorite belt in the northeast of the country, two high-grade belts in the northwest and southwest, respectively, and a large granitoid–felsic volcanic terrain in the central part of the country, punctuated by numerous gabbroic intrusions. The basement is overlain by the subhorizontal Proterozoic Roraima sandstone formation and transected by two Proterozoic and one Jurassic dolerite dyke swarms. Late Proterozoic mylonitisation affected large parts of the basement. Almost 50 new U–Pb and Pb–Pb zircon ages and geochemical data have been obtained in Suriname, and much new data are also available from the neighbouring countries. This has led to a considerable revision of the geological evolution of the basement. The main orogenic event is the Trans-Amazonian Orogeny, resulting from southwards subduction and later collision between the Guiana Shield and the West African Craton. The first phase, between 2.18 and 2.09 Ga, shows ocean floor magmatism, volcanic arc development, sedimentation, metamorphism, anatexis and plutonism in the Marowijne Greenstone Belt and the adjacent older granites and gneisses. The second phase encompasses the evolution of the Bakhuis Granulite Belt and Coeroeni Gneiss Belt through rift-type basin formation, volcanism, sedimentation and, between 2.07 and 2.05 Ga, high-grade metamorphism. The third phase, between 1.99 and 1.95 Ga, is characterised by renewed high-grade metamorphism in the Bakhuis and Coeroeni belts along an anticlockwise cooling path, and ignimbritic volcanism and extensive and varied intrusive magmatism in the western half of the country. An alternative scenario is also discussed, implying an origin of the Coeroeni Gneiss Belt as an active continental margin, recording northwards subduction and finally collision between a magmatic arc in the south and an older northern continent. The Grenvillian collision between Laurentia and Amazonia around 1.2–1.0 Ga caused widespread mylonitisation and mica age resetting in the basement.