Showing papers on "Metamorphism published in 2022"

Archean eclogite-facies oceanic crust indicates modern-style plate tectonics

Abstract: Significance The onset time of plate tectonics is highly debated in the Earth sciences. A key indicator of modern-style plate tectonics, with deep subduction of oceanic plates, is the presence of eclogite (oceanic crust metamorphosed at high-pressure and low-temperature) in orogenic belts. Since no orogenic eclogites older than 2.1 billion y are currently documented, many scientists argue that modern plate tectonics started only 2.1 billion y ago (Ga). We document an Archean orogenic eclogite, providing robust evidence that subduction of oceanic crust reached to at least 65 to 70 km in depth at circa 2.5 Ga. This extends the known age of subduction-related eclogite-facies metamorphism back 400 My, showing that modern-style plate tectonics operated by the close of the Archean.

OUP accepted manuscript

Abstract: Abstract In collision-type orogens, where high-pressure and ultrahigh-pressure (HP–UHP) metamorphism usually occurs, deeply subducted continental slabs with eclogitized mafic rocks often undergo recrystallization/overprinting with various geothermal gradients after the peak conditions at lower-to-middle-crustal levels. During the crustal stabilization, the transition from eclogite-to granulite-facies is common. We conducted metamorphic petrology and zircon geochronology on (1) bimineralic and (2) partially granulitized eclogites from the Neoproterozoic Ufipa Terrane (Southwestern Tanzania). Microtextural relationships and mineral chemistry define three metamorphic stages: eclogite metamorphism (M1), HP granulite-facies overprinting (M2), and amphibolite-facies retrogression (M3). The bimineralic eclogite has a basaltic composition and lacks M2 minerals. In contrast, the kyanite eclogite is characterized by a gabbro-dioritic whole-rock composition and contains inherited magmatic zircon. Although the matrix is highly granulitized, garnet and kyanite contain eclogite-facies mineral inclusions. Phase equilibria modeling revealed P–T conditions of 2.1–2.6 GPa and 650–860°C for the M1 stage and 1.4–1.6 GPa and 750–940°C for the M2 stage. Zircon with eclogite-facies mineral inclusions from the bimineralic eclogite lacks Eu anomaly in the REE patterns and yielded the M1 eclogite metamorphic age of 588 ± 3 Ma. Zircon overgrowths surrounding the inherited Paleoproterozoic magmatic cores in kyanite eclogite yielded 562 ± 3 Ma. A weak negative Eu anomaly in the REE patterns and the absence of eclogitic mineral inclusions suggest the zircon growths at the M2 HP granulite-facies metamorphic stage. These new data indicate an eclogite-to granulite-facies transition time of 26 ± 4 million years (Myr), suggesting a rate of HP rock exhumation toward a lower crustal level of 0.7–1.5 mm/year. Furthermore, the density evolution model indicates that buoyant host orthogneiss with low-density gabbro-dioritic eclogite plays an important role in carrying high-density basaltic eclogite. Our 2D thermomechanical modeling also suggests that a slab break-off with a lower angle subduction of <20° triggers the exhumation of the HP slab sliver with 20–30 Myr eclogite-to granulite transition time of large HP–UHP terranes in major collision zones.

Paleozoic post-collisional magmatism and high-temperature granulite-facies metamorphism coupling with lithospheric delamination of the East Kunlun Orogenic Belt, NW China

Abstract: Lithosphere extension and upwelling of asthenosphere at post-collisional stage of an orogenic cycle generally induce diverse magmatism and/or associated high-temperature metamorphism. Nevertheless, the intimate coexistence of post-collisional magmatic activity and high-temperature metamorphism is rare. In this contribution, a lithological assemblage composing of diverse magmatic rocks deriving from distinct magma sources and coeval high-temperature metamorphism was identified in eastern Kunlun. Petrography, ages, mineral chemistry and whole-rock geochemistry demonstrated that those intimately coexistent diverse rocks were genetically related to post-collisional extension. The garnet-bearing mafic granulites in Jinshuikou area interior of the East Kunlun Orogenic Belt are mainly composed of garnet, orthopyroxene, and plagioclase, with peak metamorphic P–T conditions of ~ 701–756 °C and 5.6–7.0 kbar, representing a granulite-facies metamorphism at 409.7 ± 1.7 Ma. The diverse contemporaneous magmatic rocks including hornblendites, gabbros and granites yield zircon U–Pb ages of 408.6 ± 2.5 Ma, 413.4 ± 4.6 Ma, and 387–407 Ma, respectively. The hornblendites show N-MORB-like REE patterns with (La/Sm)N values of 0.85–0.94. They have positive zircon eHf(t) values of 0.1–4.9 and whole-rock eNd(t) values of 3.9–4.7 but relatively high (87Sr/86Sr)i values of 0.7081 to 0.7088. These features demonstrate that the hornblendites derived from a depleted asthenospheric mantle source with minor continental crustal materials in source. As for the gabbros, they exhibit arc-like elemental signatures, low zircon eHf(t) values (−4.3 to 2.5) and variable whole-rock eNd(t) values (−4.9 to 1.2) as well as high (87Sr/86Sr)i values (0.7068 to 0.7126), arguing for that they were originated from partial melting of heterogeneous lithospheric mantle anteriorly metasomatized by subducted-sediment released melts. Geochemistry of the granites defines their strongly peraluminous S-type signatures. Zircons from the granites yield a large range of eHf(t) values ranging from −30.8 to −5.1, while the whole-rock samples yield consistent (87Sr/86Sr)i values (0.7301 to 0.7342) and negative eNd(t) values (−10.1 to −12.4). These features indicate that the S-type granites could be generated by reworking of an ancient crust. Taken together, the penecontemporaneous magmatism and metamorphic event, demonstrated the early-middle Devonian transition from crustal thickening to extensional collapse. The post-collisional mantle-derived magmas serve as an essential driving force for the high-temperature granulite-facies metamorphism and anataxis of the crust associated with formation of S-type granite. This study not only constructs a more detail Proto-Tethys evolution process of the eastern Kunlun, but also sheds new light on better understanding the intimate relationship between magmatism and metamorphism during post-collisional extensional collapse.

Critical metal enrichment in crustal melts: The role of metamorphic mica

Abstract: Metals such as Li, Be, V, Co, Nb, In, Cs, Sn, Ta, and W are considered resources that are critical for modern economies. They can be significantly enriched in granites and pegmatites, but the mechanisms of enrichment remain poorly understood. Many metal-enriched granitic magmas form through mica dehydration reactions during high-grade metamorphism. The preferential incorporation of these metals into micas provides a mechanism for concentration and mobilization during crustal melting. Comprehensive data sets of these elements and their partitioning in metamorphic micas across different metamorphic grades are currently lacking. We present the first extensive in situ laser ablation–inductively coupled plasma–mass spectrometry element data set collected from metasediment-hosted muscovite and biotite from three different metamorphic cross sections traversing sub-greenschist- (~400 °C) to granulite-facies conditions (>900 °C). Within the same sample, Li, V, Co, Cs, and Ta concentrations are higher in biotite, whereas Be, In, Sn, and W concentrations are higher in muscovite. Subsolidus micas record only nonsystematic compositional variations between samples. Suprasolidus biotites show systematic depletion in Li, Be, Sn, and Cs and enrichment in V and Co with increasing temperature in the highest-grade (muscovite-absent) samples. Indium and W reach peak concentrations in biotite at 750 °C and 850 °C, respectively. Muscovites record systematic enrichment in In and W and depletion in Be, Sn, and Cs with increasing metamorphic grade. These distinctive trends appear to be independent of tectonic setting (i.e., continental collision and crustal thinning). Our data set highlights the importance of higher-temperature melting (>750 °C), in particular, biotite breakdown reactions, for the release of Li, Be, Sn, Cs, and W into crustal melts.

A window into an older orogenic cycle: <i>P–T</i> conditions and timing of the pre‐Alpine history of the Dora‐Maira Massif (Western Alps)

Abstract: Deciphering the pre-orogenic evolution of subducted continental basement is challenging due to pervasive reworking of crust during subduction and exhumation. Survival of such polycyclic basement may occur locally in low strain domains bounded by intensely overprinted rocks. The Palaeozoic history of basement involved in Alpine continental subduction is investigated in the northern Dora-Maira Massif where a kilometre-scale domain of low strain preserves a pre-Alpine amphibolite-facies foliation in garnet-biotite orthogneiss and garnet-staurolite micaschist. By contrast, a first generation garnet is the only pre-Alpine relict in pervasively reworked domains surrounding the low-strain domain. Thermodynamic modelling based on garnet isopleths in micaschist constrains the pre-Alpine pressure–temperature (P–T) evolution from 4 to 5 kbar and ~500°C to 6–7 kbar and ~650°C, which is consistent with Barrovian metamorphism up to the staurolite zone. In this micaschist, monazite included in garnet rims provide an age of 324 ± 6 Ma (95% confidence interval; c.i.). On the basis of textural and chemical data, this is interpreted as recording peak Barrovian metamorphic conditions. Low Th/U metamorphic zircon overgrowths and crystals yield an age of 304 ± 2 Ma (95% confidence interval). On the basis of the trace element concentrations and rare earth element (REE) patterns measured in garnet and metamorphic zircon, the latter is tentatively interpreted as having grown during early exhumation or cooling, involving garnet consumption and fluid infiltration. The reconstructed Variscan Barrovian metamorphism of the northern Dora-Maira basement is consistent with that documented in the External Crystalline Massifs and in the Austroalpine domain of the Alps. The Palaeozoic basement of the Dora-Maira Massif likely represents upper crustal material, later involved in Alpine continental subduction under high- to ultra-high-pressure conditions.

Protracted Subduction of the European Hyperextended Margin Revealed by Rutile U‐Pb Geochronology Across the Dora‐Maira Massif (Western Alps)

Abstract: The Dora-Maira massif is an archetypal nappe stack of subducted and exhumed upper crust. Slices of continental crust experienced metamorphism at upper blueschist to ultrahigh-pressure (UHP) eclogite-facies conditions. While the timing of peak metamorphism in the UHP unit has been extensively studied, little is known about the other units. In order to constrain the timing and conditions of high-pressure metamorphism, U-Pb-trace element analyses of rutile and titanite were carried out across the nappe stack. The data reveal Alpine peak metamorphic ages younging downwards in the stack, from ∼40 to ∼33 Ma. Greenschist-facies retrogression of the whole massif occurred at ∼32–31 Ma, after high-pressure metamorphism of the lowermost unit (Sanfront-Pinerolo Unit). Tectonic implications include (a) continuous and fast exhumation of subducted continental crust, (b) long-lived subduction from ∼60 to ∼33 Ma of the distal European margin, reconstructed to be a hyperextended margin spread over ∼130 km for the Dora-Maira massif alone, and (c) the initiation of continental collision synchronous with the end of high-pressure metamorphism.

Paleozoic post-collisional magmatism and high-temperature granulite-facies metamorphism coupling with lithospheric delamination of the East Kunlun Orogenic Belt, NW China

Abstract: Lithosphere extension and upwelling of asthenosphere at post-collisional stage of an orogenic cycle generally induce diverse magmatism and/or associated high-temperature metamorphism. Nevertheless, the intimate coexistence of post-collisional magmatic activity and high-temperature metamorphism is rare. In this contribution, a lithological assemblage composing of diverse magmatic rocks deriving from distinct magma sources and coeval high-temperature metamorphism was identified in eastern Kunlun. Petrography, ages, mineral chemistry and whole-rock geochemistry demonstrated that those intimately coexistent diverse rocks were genetically related to post-collisional extension. The garnet-bearing mafic granulites in Jinshuikou area interior of the East Kunlun Orogenic Belt are mainly composed of garnet, orthopyroxene, and plagioclase, with peak metamorphic P–T conditions of ~ 701–756 °C and 5.6–7.0 kbar, representing a granulite-facies metamorphism at 409.7 ± 1.7 Ma. The diverse contemporaneous magmatic rocks including hornblendites, gabbros and granites yield zircon U–Pb ages of 408.6 ± 2.5 Ma, 413.4 ± 4.6 Ma, and 387–407 Ma, respectively. The hornblendites show N-MORB-like REE patterns with (La/Sm)N values of 0.85–0.94. They have positive zircon εHf(t) values of 0.1–4.9 and whole-rock εNd(t) values of 3.9–4.7 but relatively high (87Sr/86Sr)i values of 0.7081 to 0.7088. These features demonstrate that the hornblendites derived from a depleted asthenospheric mantle source with minor continental crustal materials in source. As for the gabbros, they exhibit arc-like elemental signatures, low zircon εHf(t) values (−4.3 to 2.5) and variable whole-rock εNd(t) values (−4.9 to 1.2) as well as high (87Sr/86Sr)i values (0.7068 to 0.7126), arguing for that they were originated from partial melting of heterogeneous lithospheric mantle anteriorly metasomatized by subducted-sediment released melts. Geochemistry of the granites defines their strongly peraluminous S-type signatures. Zircons from the granites yield a large range of εHf(t) values ranging from −30.8 to −5.1, while the whole-rock samples yield consistent (87Sr/86Sr)i values (0.7301 to 0.7342) and negative εNd(t) values (−10.1 to −12.4). These features indicate that the S-type granites could be generated by reworking of an ancient crust. Taken together, the penecontemporaneous magmatism and metamorphic event, demonstrated the early-middle Devonian transition from crustal thickening to extensional collapse. The post-collisional mantle-derived magmas serve as an essential driving force for the high-temperature granulite-facies metamorphism and anataxis of the crust associated with formation of S-type granite. This study not only constructs a more detail Proto-Tethys evolution process of the eastern Kunlun, but also sheds new light on better understanding the intimate relationship between magmatism and metamorphism during post-collisional extensional collapse.

Linking metamorphism and plate boundaries over the past 2 billion years

Abstract: Since the Jurassic, there has been a clear spatiotemporal correlation between different types of metamorphism and active convergent plate margins. However, the extent to which this relationship extends into the past is poorly understood. We compared paleogeographic reconstructions and inferred plate kinematics with the age and thermobaric ratio (temperature/pressure [T/P]) of metamorphism over the past 2 b.y. The null hypothesis—that there is no spatiotemporal link between inferred plate margins and metamorphism—can be rejected. Low-T/P metamorphism is almost exclusively located near plate margins, whereas intermediate- and high-T/P metamorphism skews toward increasingly greater distances from these margins, consistent with three different tectonic settings: the subduction zone, the mountain belt, and the orogenic hinterland, respectively. However, paleogeographic reconstructions suggest that so-called “paired metamorphic belts” are rare and that high- and low-T/P localities more commonly occur along strike from each other. The observation that bimodal metamorphism is largely a function of distance from the trench and that end-member T/P types rarely occur in the same place can be explained if the style of orogenesis has evolved from hotter to colder, consistent with the abrupt emergence of low-T/P metamorphism in the Cryogenian. The widespread development of high-T/P rocks in orogenic hinterlands in the Proterozoic was followed by the production and efficient exhumation of low-T/P rocks in subduction channels in the Phanerozoic.

Evidence from HP/UHP metasediments for recycling of isotopically heterogeneous potassium into the mantle

Abstract: Abstract Potassium isotopes may provide a novel approach for fingerprinting recycled sediments in the mantle due to the significant differences in K abundance and isotopic ratio between subducting sediment and the mantle. However, the behavior of K isotopes in sediments during subduction zone metamorphism is still unknown. Here we investigate K isotopic composition of a set of well-characterized high- to ultrahigh-pressure metasediments from the Schistes Lustrés nappe (western Alps), which represents marine sediments subducted down to ~90 km depth in a cold subduction zone, and their protoliths from the Lavagna nappe (Apennines, Italy). The metasediments display δ41KSRM 3141a values from –0.76‰ to –0.48‰, which are on average lower than the mantle value (–0.43‰) but similar to those of non-metamorphic equivalents (–0.79‰ to –0.49‰). No systemic variation of δ41K with metamorphic grade is observed, suggesting negligible K isotope fractionation in these sediments during prograde metamorphism. This is in accord with the limited loss of K during the entire metamorphic history as evidenced by the constancy of K/Rb and K/Cs ratios between metamorphic and non-metamorphic sediments and the absence of correlations of δ41K with K/Rb and K/Cs. The heterogeneous δ41K values of metasediments are most likely inherited from their protoliths, which experienced different degrees of chemical weathering depending on their provenances. Our results demonstrate that the variable and light K isotopic signatures in subducting sediments could be preserved to depths of at least 90 km along a cold geotherm gradient, indicating that the introduction of sediments into the mantle could produce K isotope heterogeneity in the source regions of mantle-derived lavas.

Dynamic pressure variations in the lower crust caused by localized fluid-induced weakening

Abstract: Abstract Metamorphism of dry, lower crust within orogens is often localized in shear zones composed of mechanically weaker rocks 1–4 . Several field-based studies suggest shear zone development is preceded by brittle faults which provide the fluid pathways required for metamorphism and weakening 4–12 . However, a unifying model which couples long-term geological deformation to fluid migration and metamorphic reactions does not exist. Here, we present a visco-elasto-plastic model where the most pertinent features observed in transformed lower crust emerge from basic mechanical principles during the deformation of a coherent rock volume with associated fluid introduction. These include a strikingly dynamic and heterogeneous pressure distribution in the reacting and deforming rock volumes. Lower crustal pressure variations may reach 1 GPa at the same depth. This will have first order effects on the pattern of fluid migration in the lower crust, and may explain the apparent discrepancies between the relevant tectonic settings and petrologically-inferred burial depths.

Geologic field evidence for non-lithostatic overpressure recorded in the North American Cordillera hinterland, northeast Nevada

Abstract: There is a long-standing discrepancy for numerous North American Cordillera metamorphic core complexes between geobarometric pressures recorded in the exhumed rocks and their apparent burial depths based on palinspastic reconstructions from geologic field data. In particular, metamorphic core complexes in eastern Nevada are comprised of well-documented ~12–15 km thick Neoproterozoic–Paleozoic stratigraphy of Laurentia's western passive margin, which allows for critical characterization of field relationships. In this contribution we focus on the Ruby Mountain–East Humboldt Range–Wood Hills–Pequop Mountains (REWP) metamorphic core complex of northeast Nevada to explore reported peak pressure estimates versus geologic field relationships that appear to prohibit deep burial. Relatively high pressure estimates of 6–8 kbar (23–30 km depth, if lithostatic) from the lower section of the Neoproterozoic–Paleozoic passive margin sequence require burial and or repetition of the passive margin sequence by 2–3× stratigraphic depths. Our observations from the least migmatized and/or mylonitized parts of this complex, including field observations, a transect of peak-temperature (Tp) estimates, and critical evaluation of proposed thickening/burial mechanisms cannot account for such deep burial. From Neoproterozoic–Cambrian (Ꞓ) rocks part of a continuous stratigraphic section that transitions ~8 km upsection to unmetamorphosed Permian strata that were not buried, we obtained new quartz-in-garnet barometry via Raman analysis that suggest pressures of ~7 kbar (~26 km). A Tp traverse starting at the same basal Ꞓ rocks reveals a smooth but hot geothermal gradient of ≥40 °C/km that is inconsistent with deep burial. This observation is clearly at odds with thermal gradients implied by high P-T estimates that are all ≤25 °C/km. Remarkably similar discrepancies between pressure estimates and field observations have been discussed for the northern Snake Range metamorphic core complex, ~200 km to the southeast. We argue that a possible reconciliation of long-established field observations versus pressures estimated from a variety of barometry techniques is that the rocks experienced non-lithostatic tectonic overpressure. We illustrate how proposed mechanisms to structurally bury the rocks, as have been invoked to justify published high pressure estimates, are entirely atypical of the Cordillera hinterland and unlike structures interpreted from other analogous orogenic plateau hinterlands. Proposed overpressure mechanisms are relevant in the REWP, including impacts from deviatoric/differential stress considerations, tectonic mode switching, and the autoclave effect driven by dehydration melting. Simple mechanical arguments demonstrate how this overpressure could have been achieved. This study highlights that detailed field and structural restorations of the least strained rocks in an orogen are critical to evaluate the tectonic history of more deformed rocks.

Strengths and limitations of in situ U–Pb titanite petrochronology in polymetamorphic rocks: An example from western Maine, USA

Abstract: Titanite is a potentially powerful U-Pb petrochronometer that may record metamorphism, metasomatism, and deformation. Titanite may also incorporate significant inherited Pb, which may lead to inaccurate and geologically ambiguous U-Pb dates if a proper correction is not or cannot be applied. Here we present laser ablation inductively coupled mass spectrometry (LA-ICP-MS)-derived titanite U-Pb dates and trace element concentrations for two banded calc-silicate gneisses from south-central Maine, USA (SSP18-1A & -1B). Single spot common Pb-corrected dates range from 400 to 280 Ma with ±12–20 Ma propagated 2SE. Titanite grains in sample SSP18-1B exhibit regular core-to-rim variations in texture, composition, and date. We identify four titanite populations: 1) 397 ± 5 Ma (95% CL) low Y + HREE cores and mottled grains, 2) 370 ± 7 Ma high Y + REE mantles and cores, 3) 342 ± 6 Ma cores with high Y + REE and no Eu anomaly, and 4) 295 ± 6 Ma LREE-depleted rims. We interpret the increase in titanite Y + HREE between ca. 397 and ca. 370 Ma to constrain the timing of diopside fracturing and recrystallization and amphibole breakdown. Apparent Zr-in-titanite temperatures (803 ± 36°C at 0.5 ± 0.2 GPa) and increased XDi suggest a thermal maximum at ca. 370 Ma. Population 3 domains dated to ca. 342 Ma exhibit no Eu anomaly and are observed only in compositional bands dominated by diopside (>80 vol%), suggesting limited equilibrium between titanite and plagioclase. Finally, low LREE and high U/Th in Population 4 titanite date the formation of hydrous phases, such as allanite, during high XH2O fluid infiltration at ca. 295 Ma. In contrast to the well-defined date-composition-texture relationships observed for titanite from SSP18-1B, titanite grains from sample SSP18-1A exhibit complex zoning patterns and little correlation between texture, composition, and date. We hypothesize that the incorporation of variable amounts of radiogenic Pb from dissolved titanite into recrystallized domains resulted in mixed ages spanning 380–330 Ma. Although titanite may reliably record multiple phases of metamorphism, these data highlight the importance of considering U-Pb data along with chemical and textural data to screen for inherited radiogenic Pb.

⁴⁰ Ar/ ³⁹ Ar Age Constraints on H <i>P</i> /L <i>T</i> Metamorphism in Extensively Overprinted Units: The Example of the Alpujárride Subduction Complex (Betic Cordillera, Spain)

Abstract: Widespread overprinting of early high-pressure/low-temperature (HP/LT) subduction stages due to subsequent collisional or late-orogenic tectono-metamorphic events is a common feature affecting the interpretation of geochronologic data from HP/LT orogens. The Betic-Rif orogen is exemplary in this connection as a great majority of published radiometric ages are found to cluster around 20 Ma. This clustering is commonly interpreted as reflecting a short, yet complex, succession of tectono-metamorphic events spanning only over a few Myr, including back-arc extension and overthrusting of the Internal Zones on the External Zones. An alternative explanation consists in the poor preservation of a much earlier HP/LT metamorphic event, presumably Eocene, coeval with subduction and crustal thickening in the Internal Zones, and particularly the Alpujárride Complex. However, this age is vividly debated due to widespread resetting by the Early Miocene HT/LP overprint. In this study, we provide new 40Ar/39Ar evidence from white micas selected along an E-W section of the Internal Betics, from the central to the eastern Alpujárride Complex. Our new data show (a) that exceptionally well-preserved HP/LT parageneses in this unit retain a well-defined Eocene age around 38 Ma, and (b) that widespread 20 Ma ages recorded all along the section correspond to a regional stage of exhumation, coeval with a major change in the kinematics of back-arc extension. Our study provides conclusive evidence that 40Ar/39Ar dating of carefully targeted HP/LT associations can overcome the problem of extensive late-orogenic overprinting, testifying for an Eocene HP event around 38 Ma in the Betic-Rif orogen.